Article
Chemistry, Multidisciplinary
Dayan L. Buitrago-Rincon, Veronique Sadtler, Ronald A. Mercado, Thibault Roques-Carmes, Philippe Marchal, Samuel F. Munoz-Navarro, Maria Sandoval, Julio A. Pedraza-Avella, Cecile Lemaitre
Summary: The effect of silica nanoparticles (NP-SiO2) in xanthan gum (XG) solutions was investigated in this study. The addition of nanoparticles showed a slight effect on the viscosity of the fluids, which became more remarkable over time. Interfacial tension tests measured in water-mineral oil systems did not find any effect on the interfacial properties with the addition of polymer or nanoparticles. Three core flooding experiments were conducted using sandstone core plugs and mineral oil, and the nanofluid formulation recovered about 13% of the residual oil, almost double that of the original XG solution.
Article
Energy & Fuels
Claudia K. B. de Vasconcelos, Felipe S. Medeiros, Bruna R. S. Diniz, Marcelo M. Viana, Vinicius Caliman, Glaura G. Silva
Summary: The study investigated the use of graphene oxide and aminated graphene oxide to prepare nanofluids, with aminated graphene oxide showing better performance and greater viscosity enhancement in high salinity conditions.
Article
Chemistry, Physical
Zsofia Vargane Arok, Szilard Saringer, Dora Takacs, Coline Bretz, Adam Juhasz, Istvan Szilagyi
Summary: The study investigates the structural and rheological properties of a partially hydrolyzed polyacrylamide (FLOPAAM 3630S) in a wide range of salinity relevant to existing oil reservoir conditions. It is found that macromolecular solutions are present at low polymer concentrations and/or elevated salt levels, while gelation occurs at high FLOPAAM 3630S doses at low salinity. The driving force behind this transformation is determined to be hydrophobic intermolecular interactions. These findings provide new insights for the design of efficient enhanced oil recovery processes in oil reservoirs with varying salt levels.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Energy & Fuels
Si-Jia Miao, Jing Zhou, Gui-Na Qi, Jin-Feng Liu, Shi-Zhong Yang, Hongze Gang, Bo-Zhong Mu
Summary: In this study, a thermally stable and salt tolerant biopolymer (HS-EPS) was obtained from the broth of Sphingomonas sp. HS. The HS-EPS showed good viscosity stability, and in combination with a biobased surfactant, a new alkali-free surfactant-polymer binary system was developed. This system exhibited low interfacial tension with crude oil and demonstrated good adsorption resistance, dilution resistance, and aging stability.
Article
Energy & Fuels
Akinleye O. Sowunmi, Vincent E. Efeovbokhan, Oyinkepreye D. Orodu, Babalola A. Oni
Summary: The study compared the EOR performance of Gum Arabic (GA) and Xanthan Gum (XG) solutions, showing similar oil recovery for 1.0 wt% GA and 0.1 wt% XG polymeric solutions. GA exhibited Newtonian viscosity at high shear rates. The impact of nano-polymeric solutions on oil recovery was found to be higher than that of polymeric solutions.
JOURNAL OF PETROLEUM EXPLORATION AND PRODUCTION TECHNOLOGY
(2022)
Article
Energy & Fuels
Tagwa A. Musa, Ahmed F. Ibrahim, Hisham A. Nasr-El-Din, Anas. M. Hassan
Summary: The study confirmed the potential of guar gum as a natural polymer for EOR applications in sandstone reservoirs, showing good stability and viscosity under high-temperature and high-salinity conditions. Additionally, flooding experiments demonstrated a 16% increase in recovery factor.
JOURNAL OF PETROLEUM EXPLORATION AND PRODUCTION TECHNOLOGY
(2021)
Article
Energy & Fuels
Tahoura Ahsani, Yousef Tamsilian, Alireza Rezaei
Summary: The adsorption of hydrolyzed polyacrylamide on carbonate surface was investigated by molecular dynamic simulation and experimental procedure, showing that polymer adsorption decreased the water contact angle, resulting in a moderately oilwet state and good agreement with experimental results. This opens up opportunities for further molecular dynamic investigations of different polymers as wettability modifiers during EOR processes.
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING
(2021)
Article
Environmental Sciences
Shatha Al-Kindi, Saif Al-Bahry, Yahya Al-Wahaibi, Usman Taura, Sanket Joshi
Summary: Polyacrylamide is widely used in oil fields to enhance oil recovery, but it also produces a large quantity of toxic wastewater. The challenge is to remove or degrade polyacrylamide in an environmentally safe manner. Biodegradation with the aid of microbes is considered an efficient and environmentally friendly solution.
ENVIRONMENTAL MONITORING AND ASSESSMENT
(2022)
Article
Energy & Fuels
Zhihua Wang, Yunfei Xu, Yifan Gan, Xue Han, Wenbo Liu, Hua Xin
Summary: This study investigates the behavior of HPAM molecules at the crude oil-water interface. The results show that HPAM molecules aggregate in different forms, and the inorganic cations have an impact on the aggregation. The stability of the interfacial film is correlated with the gyration radius of the HPAM molecules, and the effect of hydrolysis degree on stability is within a certain range.
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING
(2022)
Article
Environmental Sciences
Bethania Felix Miranda Ramos, Paulo Fernando de Almeida, Fabio Alexandre Chinalia
Summary: The present work aimed to economically utilize the produced water from the oil and gas industry by producing bioactives such as xanthan gum and ramnolipid. This research showed a method to optimize the culture conditions for Xanthomonas campestris and Pseudomonas aeruginosa using a factorial design and surface response analysis. After optimization, xanthan and ramnolipid production reached 8.69 g/L and 4.80 g/L, respectively.
ENVIRONMENTAL TECHNOLOGY
(2022)
Article
Energy & Fuels
M. Elmuzafar Ahmed, Abdullah S. Sultan, Abdulkarim Al-Sofi, Hasan S. Al-Hashim
Summary: This article evaluates the feasibility of using surfactant polymer (SP) in high saline and high-temperature reservoirs and identifies the optimal chemical combination, slug size, and injection sequence to achieve maximum oil recovery.
JOURNAL OF PETROLEUM EXPLORATION AND PRODUCTION TECHNOLOGY
(2023)
Article
Polymer Science
Iskander Sh Gussenov, Nurbatyr Mukhametgazy, Alexey Shakhvorostov, Sarkyt E. Kudaibergenov
Summary: This paper presents the viscosifying and oil recovery efficiencies of a novel high-molecular-weight ternary polyampholyte (TPA) in high-salinity brines. The results show that TPA has high and stable viscosity in high salinity conditions, indicating its potential for improved oil displacement capability.
Article
Engineering, Chemical
Subhadeep Chakraborty, Sonai Dutta, Rahul Chatterjee, Jagannath Chanda, Sagar Pal, Abhijit Bandyopadhyay
Summary: A decorated semi-synthetic flocculant derived from Xanthan gum has been synthesized and found to efficiently unsettle stable kaolin suspension at low concentration (0.25wt.%). The copolymer with the maximum extent of branching (70.5%) exhibited the fastest settling time and the lowest turbidity, especially at pH 7 and the isoelectric point.
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2023)
Article
Engineering, Chemical
Xu Han, Changqing Li, Feng Pan, Yuxi Li, Yujun Feng
Summary: Compared with P-HPAM, E-HPAM showed shorter dissolution time, higher viscosity retention, lower interfacial tension, and higher oil recovery factor in a simulated Daqing Oilfield reservoir.
CANADIAN JOURNAL OF CHEMICAL ENGINEERING
(2022)
Article
Energy & Fuels
Jinesh Machale, Suresh Kumar Yatirajula, Vinod Kumar Saxena
Summary: “The present study highlights the potential application of a polymer blend of polyacrylamide and xanthan gum in enhanced oil recovery. The study demonstrates that the polymer blend exhibits higher tolerance to salinity, temperature, alkali, and surfactant compared to parent polymers, making it a promising option for enhanced oil recovery.”
PETROLEUM SCIENCE AND TECHNOLOGY
(2022)
Article
Engineering, Chemical
Alison J. Scott, Alexander Penlidis
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2020)
Article
Engineering, Chemical
Alison J. Scott, Noushin Majdabadifarahani, Katherine M. E. Stewart, Thomas A. Duever, Alexander Penlidis
MACROMOLECULAR REACTION ENGINEERING
(2020)
Article
Polymer Science
Katherine M. E. Stewart, Alison J. Scott, Alexander Penlidis
POLYMERS FOR ADVANCED TECHNOLOGIES
(2020)
Article
Engineering, Chemical
Alison J. Scott, Alexander Penlidis
Summary: As process engineering has matured, the focus of research has shifted towards polymer product design, with the goal of producing polymers with specific application properties. By employing a systematic design framework and iterative steps, it is possible to optimize production conditions for tailored polymer materials.
CANADIAN JOURNAL OF CHEMICAL ENGINEERING
(2021)
Article
Engineering, Chemical
Ali Seyedi, Mohammad Najafi, Gregory T. Russell, Yousef Mohammadi, Eduardo Vivaldo-Lima, Alexander Penlidis
Review
Engineering, Chemical
Miguel angel Vega-Hernandez, Gema Susana Cano-Diaz, Eduardo Vivaldo-Lima, Alberto Rosas-Aburto, Martin G. Hernandez-Luna, Alfredo Martinez, Joaquin Palacios-Alquisira, Yousef Mohammadi, Alexander Penlidis
Summary: This critical review focuses on the synthesis, characterization, and modeling of polymer grafting, pointing out that there is room for further research in this area despite existing understanding and efforts.
Article
Engineering, Chemical
Katherine M. E. Stewart, Majed Al-Ghamdi, Mahmoud Khater, Eihab M. Abdel-Rahman, Alexander Penlidis
Summary: This paper critically reviews recent advancements in aqueous sensors for heavy metals, focusing on the challenges and advantages of using MEMS sensors in water environments and choosing appropriate polymeric sensing materials. Additionally, general considerations and recommendations for developing MEMS chemical sensors are provided, centering around the chemical nature of the analyte and sensor application environment. By following these recommendations, time and cost can be saved by designing a suitable sensor and sensing material for the target application.
CANADIAN JOURNAL OF CHEMICAL ENGINEERING
(2022)
Article
Polymer Science
Yousef Mohammadi, Mohammad Reza Saeb, Alexander Penlidis, Esmaiel Jabbari, Florian J. Stadler, Philippe Zinck, Eduardo Vivaldo-Lima
Summary: Recent advances in macromolecular reaction engineering have allowed for the synthesis of sequence-controlled polymers, particularly through the development of olefin block copolymers. The use of an intelligent tool combining simulation and artificial neural network modeling has enabled the prediction of properties of OBCs and exploration of their microstructural characteristics.
MACROMOLECULAR THEORY AND SIMULATIONS
(2021)
Editorial Material
Engineering, Chemical
Eduardo Vivaldo-Lima, Yousef Mohammadi, Alexander Penlidis
Article
Chemistry, Analytical
Mohamed Arabi, Majed Alghamdi, Khalid Kabel, Ahmed Labena, Walaa S. Gado, Bhoomi Mavani, Alison J. Scott, Alexander Penlidis, Mustafa Yavuz, Eihab Abdel-Rahman
Summary: This study reports on the deployment of MEMS static bifurcation sensors for the detection of volatile organic compounds, specifically hydrogen sulfide and formaldehyde. The sensitivity and selectivity of two detector polymers, polyaniline (PANI) and poly (2,5-dimethyl aniline) (P25DMA), were investigated. A semi-automatic method was developed to functionalize individual sensors and arrays with the detector polymers. The results show that the sensor array can selectively detect 1 ppm of formaldehyde in the presence of benzene.
Article
Engineering, Chemical
Bhoomi Het Mavani, Alexander Penlidis
Summary: The study evaluated the sensitivity of polyaniline and its derivative poly (2,5-dimethyl aniline) towards formaldehyde, with polyaniline showing higher sensitivity. Doping polyaniline with different weight percentages of indium oxide was found to enhance sensitivity towards formaldehyde, with 1.25 wt% In2O3 yielding the highest sensitivity. Additionally, different weight percentages of In2O3 resulted in reversed trends for sensitivity and selectivity, with all sensing materials being stable.
MACROMOLECULAR REACTION ENGINEERING
(2022)
Article
Polymer Science
Chandra Mouli R. Madhuranthakam, Sudharsan Pandiyan, Alexander Penlidis
Summary: Packaging material plays a crucial role in maintaining or changing the shelf life of products. This study focuses on developing a new polymer composite for packaging. The composite consists mainly of nonacosan-10-ol and polyethylene, aiming to address the challenge of controlling oxygen diffusion rates during the storage of perishable goods. Molecular dynamics simulations are conducted to assess the impact of different weight percentages of nonacosan-10-ol on polyethylene in terms of mechanical and gas transport properties. The optimal composition of the proposed additive is suggested based on minimal oxygen diffusion rate, high elastic modulus, and good thermal stability.