Article
Materials Science, Characterization & Testing
Qiang Tian, Jiayi Sun, Mark Julian Henderson, Xuegang Huang, Na Li, Jeremie Courtois, Laszlo Almasy
Summary: Relaxation mechanisms of shake gels, composed of silica nanoparticles and poly(ethylene oxide), were investigated using small-angle X-ray scattering and dynamic light scattering methods. Results showed that the gel network quickly relaxes within the first 10-20 minutes after shake-induced gelation, and then slowly reaches a quiescent structure after 1 hour.
Article
Polymer Science
Abigail K. Grosskopf, Joseph L. Mann, Julie Baillet, Hector Lopez Hernandez, Anton A. A. Autzen, Anthony C. Yu, Eric A. Appel
Summary: Designing high water content nanocomposite hydrogel materials with desired functional properties is a significant challenge. The dynamic cross-linking interactions within the polymer network can be controlled by modulating the chemical composition of the materials, leading to high extensibility and yielding of stress fluids.
Article
Chemistry, Analytical
Dan Chicea, Cristian Leca, Sorin Olaru, Liana Maria Chicea
Summary: Dynamic Light Scattering is a technique used to evaluate particle size and distribution by processing scattered light intensity. Details on experimental conditions, setup, and data processing for particle light scattering in air are provided, showing possibility of designing an advanced sensor for particles in air through extreme simplification.
Article
Chemistry, Physical
Qiyan Yin, Lei Wang, Jingtao Jiang, Chenghao Dai, Gengsheng Weng, Jie He
Summary: In this study, a new synthetic strategy is reported for the fabrication of shape-transformative Eu3+-containing interpenetrating polymer films. These films can autonomously adopt various three-dimensional shapes in response to high humidity. The shape transformation is reversible and can be controlled by adjusting the ink concentration and humidity.
CHEMISTRY OF MATERIALS
(2022)
Article
Biochemistry & Molecular Biology
Lumin Yang, Xiaoduo Zhao, Yunsong Kong, Renjie Li, Tao Li, Rui Wang, Zhengfeng Ma, Yong-min Liang, Shuanhong Ma, Feng Zhou
Summary: In this study, a novel macromolecular/microsphere-based injectable hydrogel (CMC-ODex NPs) was developed for dual functionalities of drug release and lubrication. The hydrogel exhibited viscosity-thinning phenomenon and gel-sol transition feature, resulting in low friction coefficient at the sliding interface of articular cartilages. The encapsulated anti-inflammatory drug (dexamethasone, DXM) in the hydrogel showed sustainable drug release, leading to good and stable anti-inflammatory effect.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Physics, Applied
A. H. Asadova, E. A. Masimov
Summary: The thermal hysteresis and stability of agarose-water gelling systems were found to be dependent on the concentration of agarose, with higher concentrations leading to higher gelation temperature and strength. Additionally, an increase in the concentration of polymer solvent resulted in gel melting at higher temperatures. The enthalpy was determined to be 150.0127 KC/mol, and during the gelation process, phase separation occurred with an increase in the value of Δt = t(melting) - t(gelation).
MODERN PHYSICS LETTERS B
(2021)
Article
Materials Science, Multidisciplinary
Yuxuan Mao, Peng Li, Jiewei Yin, Yanjie Bai, Huan Zhou, Xiao Lin, Huilin Yang, Lei Yang
Summary: A series of ionically crosslinked starch hydrogels with high tissue adhesiveness and multifunctionality have been developed, showing great potential for a wide range of applications. The hydrogel demonstrated good hemostatic effects in wound treatment and exhibited safe and effective characteristics in experiments.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2021)
Article
Chemistry, Physical
Yekun Zhang, Rui Tian, Shishu Yang, Xiaomin Guo, Hang Li
Summary: In this study, a method for determining the Hamaker constant of humus using dynamic light scattering (DLS) technique was established. The relationship between the Hamaker constant of the mixture colloid and humic acid content was determined, leading to the calculation of the Hamaker constant of humic acid. The validity of the obtained Hamaker constant was confirmed through comparison with experimentally determined values.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2021)
Article
Materials Science, Multidisciplinary
Mutian Hua, Cheolgyu Kim, Yingjie Du, Dong Wu, Ruobing Bai, Ximin He
Summary: Self-oscillating systems are powerful tools for converting static energy inputs into repetitive motions without external control. The challenge lies in avoiding thermodynamic equilibrium and steady states in sustaining the motion of oscillating materials. While living organisms exhibit elegant strategies in self-oscillations, synthetic systems often rely on specific chemical reactions and microstructures for maintaining far-from-equilibrium motion.
Article
Polymer Science
Ratan Pal Singh
Summary: This study investigates the inverse-gelation process of methylcellulose in an aqueous medium using dynamic light scattering. The results show that methylcellulose can form an entangled network at specific temperatures. Computational studies also reveal that the entanglement of cellulose molecules is affected by molecular orientation and hydrogen bonding.
JOURNAL OF POLYMER RESEARCH
(2022)
Article
Polymer Science
Zhaoyu Guo, Zhuwei Yao, Feifei Pan, Weiyu Cao
Summary: The study found that water can be used as a gel accelerator for PAN/DMSO solution, affecting the size and distribution of PAN coils through rheological testing. Dynamic light scattering testing showed that the gel accelerator can increase the average size of PAN coils and alter the mobility of PAN chains during the cooling process.
Article
Polymer Science
Irina Popescu, Marieta Constantin, Maria Bercea, Bogdan-Paul Cosman, Dana Mihaela Suflet, Gheorghe Fundueanu
Summary: This study synthesized a complex of carboxymethyl pullulan (CMP) and poloxamer (PL) and studied their miscibility in dilute aqueous solution using capillary viscometry. The thermogelation of concentrated PL solutions with the presence of CMP was monitored by various methods, and the micellization and gelation of PL were also studied. The results showed that CMP concentration has a peculiar influence on the rheological parameters of the gels, and the gels have a reversible healing process at 37 degrees C.
Article
Chemistry, Multidisciplinary
Juri Kim, Yun-Seok Choi, Geonhyeong Park, Mingeun Kim, Jin Suk Myung, Woo Jin Choi, Soon Mo Park, Dong Ki Yoon
Summary: This article introduces a method for fabricating anisotropic DNA hydrogels and demonstrates the potential of directionally controlled DNA hydrogels as smart materials.
Article
Biochemistry & Molecular Biology
Yuwei Zhou, Meiru Li, Weicheng Gao, Xueping Li, Lixia Long, Xin Hou, Jin Zhao, Sidi Li, Xubo Yuan
Summary: A microstructure-united heterogeneous injectable hydrogel (MH) was constructed, which exhibited high compressive and tensile performance simultaneously. By mixing two types of sodium alginate doped hydrogels with different microstructures, MH with micro-pores or nano-pores can be formed. MH showed high mechanical performance and provided stable and sustained hemostasis in dynamic mechanical environments.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Chemistry, Physical
Anastasia A. Belyaeva, Ilya V. V. Tretyakov, Alexey V. Kireynov, Yuliya A. Nashchekina, Vitaliy I. Solodilov, Evgenia G. Korzhikova-Vlakh, Sofia M. Morozova
Summary: The colloidal system based on a mixture of PNIPAM and CNC was studied, showing different states and properties at different temperatures. By controlling the ratio between PNIPAM and CNC, the system's state and properties can be adjusted, making these hydrogels promising materials for bioapplications such as extrusion printing.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)