Recent Advances in Photoredox Methods for Ketone Synthesis

Visible-Light-Mediated Synthesis of β-Chloro Ketones from Aryl Cyclopropanes

(2019) Daniel Petzold et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Promoted Oxo-difluoroalkylation of Alkenes with DMSO as the Oxidant

(2019) Zi-Hao Xia et al.   JOURNAL OF ORGANIC CHEMISTRY

Photoredox‐Catalyzed Oxydifluoroalkylation of Styrenes for Access to Difluorinated Ketones with DMSO as an Oxidant

(2019) Lixin Li et al.   ADVANCED SYNTHESIS & CATALYSIS

Visible Light-Mediated [2 + 2] Cycloaddition Reactions of 1,4-Quinones and Terminal Alkynes

(2019) Shaista Sultan et al.   JOURNAL OF ORGANIC CHEMISTRY

Photoredox-Mediated Generation of gem-Difunctionalized Ketones: Synthesis of α,α-Aminothioketones

(2019) Neha Chalotra et al.   ORGANIC LETTERS

Photoredox-Catalyzed Remote Difunctionalizations of Alkenes To Synthesize Fluoroalkyl Ketones with Dimethyl Sulfoxide as the Oxidant

(2019) Lixin Li et al.   ORGANIC LETTERS

Synthesis of Reversed C -Acyl Glycosides through Ni/Photoredox Dual Catalysis

(2018) Shorouk O. Badir et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Acyl Radicals from Terminal Alkynes: Photoredox-Catalyzed Acylation of Heteroarenes

(2018) Shaista Sultan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Photoinduced Generation of Acyl Radicals from Simple Aldehydes, Access to 3-Acyl-4-arylcoumarin Derivatives, and Evaluation of Their Antiandrogenic Activities

(2018) Kazuki Kawaai et al.   JOURNAL OF ORGANIC CHEMISTRY

Visible-Light-Induced Decarboxylation Coupling/Intramolecular Cyclization: A One-Pot Synthesis for 4-Aryl-2-quinolinone Derivatives

(2018) Chenglong Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Multicomponent Oxidative Trifluoromethylation of Alkynes with Photoredox Catalysis: Synthesis of α-Trifluoromethyl Ketones

(2018) Yashwardhan R. Malpani et al.   ORGANIC LETTERS

Expeditious and Chemoselective Synthesis of α-Aryl and α-Alkyl Selenomethylketones via Homologation Chemistry

(2018) Raffaele Senatore et al.   ORGANIC LETTERS

Visible-Light-Mediated Synthesis of Ketones by the Oxidative Alkylation of Styrenes

(2018) Adrian Tlahuext-Aca et al.   ORGANIC LETTERS

Photoredox-Catalyzed Decarboxylative Alkylation of Silyl Enol Ethers To Synthesize Functionalized Aryl Alkyl Ketones

(2018) Weiguang Kong et al.   ORGANIC LETTERS

Palladium-Catalyzed Synthesis of Diaryl Ketones from Aldehydes and (Hetero)Aryl Halides via C–H Bond Activation

(2018) Takayuki Wakaki et al.   ACS Catalysis

Kumada Arylation of Secondary Amides Enabled by Chromium Catalysis for Unsymmetric Ketone Synthesis under Mild Conditions

(2018) Changpeng Chen et al.   ACS Catalysis

A general deoxygenation approach for synthesis of ketones from aromatic carboxylic acids and alkenes

(2018) Muliang Zhang et al.   Nature Communications

Carbon-carbon and Carbon-heteroatom Bond Formation Reactions using Unsaturated Carbon Compounds

(2018) Shaista Sultan et al.   CHEMICAL RECORD

Photoredox Generated Vinyl Radicals: Synthesis of Bisindoles and β-Carbolines

(2018) Neha Chalotra et al.   JOURNAL OF ORGANIC CHEMISTRY

Metal-free synthesis of ketones by visible-light induced aerobic oxidative radical addition of aryl hydrazines to alkenes

(2017) Ya Ding et al.   GREEN CHEMISTRY

Photoinduced Gold-Catalyzed Domino C(sp) Arylation/Oxyarylation of TMS-Terminated Alkynols with Arenediazonium Salts

(2017) Benito Alcaide et al.   JOURNAL OF ORGANIC CHEMISTRY

Synergistic Photoredox/Nickel Coupling of Acyl Chlorides with Secondary Alkyltrifluoroborates: Dialkyl Ketone Synthesis

(2017) Javad Amani et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct Aldehyde C–H Arylation and Alkylation via the Combination of Nickel, Hydrogen Atom Transfer, and Photoredox Catalysis

(2017) Xiaheng Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible Light Copper Photoredox-Catalyzed Aerobic Oxidative Coupling of Phenols and Terminal Alkynes: Regioselective Synthesis of Functionalized Ketones via C≡C Triple Bond Cleavage

(2017) Arunachalam Sagadevan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Suzuki–Miyaura Coupling of Aryl Esters

(2017) Taoufik Ben Halima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A general approach to intermolecular carbonylation of arene C–H bonds to ketones through catalytic aroyl triflate formation

(2017) R. Garrison Kinney et al.   Nature Chemistry

Synergistic Visible-Light Photoredox/Nickel-Catalyzed Synthesis of Aliphatic Ketones via N–C Cleavage of Imides

(2017) Javad Amani et al.   ORGANIC LETTERS

General Method for the Suzuki–Miyaura Cross-Coupling of Primary Amide-Derived Electrophiles Enabled by [Pd(NHC)(cin)Cl] at Room Temperature

(2017) Peng Lei et al.   ORGANIC LETTERS

Direct Conversion of Carboxylic Acids to Alkyl Ketones

(2017) Javad Amani et al.   ORGANIC LETTERS

Photoredox-Catalyzed Diamidation and Oxidative Amidation of Alkenes: Solvent-Enabled Synthesis of 1,2-Diamides and α-Amino Ketones

(2017) Qixue Qin et al.   ORGANIC LETTERS

Synthesis of Fused Pyran Derivatives via Visible-Light-Induced Cascade Cyclization of 1,7-Enynes with Acyl Chlorides

(2017) Chen-Guang Li et al.   ORGANIC LETTERS

Acyl Radicals from Acylsilanes: Photoredox-Catalyzed Synthesis of Unsymmetrical Ketones

(2017) Luca Capaldo et al.   ACS Catalysis

Visible-light photoredox catalyzed hydroacylation of electron-deficient alkenes: carboxylic anhydride as an acyl radical source

(2017) Shupeng Dong et al.   Organic Chemistry Frontiers

Synthesis of Highly Functionalized Diaryl Ketones by Palladium-Catalyzed Carbonylative Cross-Coupling Reaction Between Triarylbismuthines and Aryl(Heteroaryl) Iodides

(2017) Julien Dansereau et al.   ChemistrySelect

Direct Acylation of C(sp3 )−H Bonds Enabled by Nickel and Photoredox Catalysis

(2016) Candice L. Joe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible light-promoted C–H functionalization of ethers and electron-deficient arenes

(2016) Shekaraiah Devari et al.   CHEMICAL COMMUNICATIONS

Organic Photoredox Catalysis

(2016) Nathan A. Romero et al.   CHEMICAL REVIEWS

Cooperative photoredox catalysis

(2016) Xianjun Lang et al.   CHEMICAL SOCIETY REVIEWS

Merging Visible-Light Photocatalysis and Palladium Catalysis for C−H Acylation of Azo- and Azoxybenzenes with α-Keto Acids

(2016) Ning Xu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Visible-Light-Mediated Photocatalytic Difunctionalization of Olefins by Radical Acylarylation and Tandem Acylation/Semipinacol Rearrangement

(2016) Giulia Bergonzini et al.   CHEMISTRY-A EUROPEAN JOURNAL

Acylation of indoles via photoredox catalysis: a route to 3-acylindoles

(2016) Lijun Gu et al.   GREEN CHEMISTRY

Photoredox Catalysis in Organic Chemistry

(2016) Megan H. Shaw et al.   JOURNAL OF ORGANIC CHEMISTRY

Visible Light Photoredox Cross-Coupling of Acyl Chlorides with Potassium Alkoxymethyltrifluoroborates: Synthesis of α-Alkoxyketones

(2016) Javad Amani et al.   ORGANIC LETTERS

Unified Approach to (Thio)chromenones via One-Pot Friedel–Crafts Acylation/Cyclization: Distinctive Mechanistic Pathways of β-Chlorovinyl Ketones

(2016) Hun Young Kim et al.   ORGANIC LETTERS

Carbonylative coupling of aryl tosylates/triflates with arylboronic acids under CO atmosphere

(2016) Cheng Yi Hao et al.   RSC Advances

Dual Hypervalent Iodine(III) Reagents and Photoredox Catalysis Enable Decarboxylative Ynonylation under Mild Conditions

(2015) Hanchu Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones by the Decarboxylative Arylation of α-Oxo Acids

(2015) Lingling Chu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Acyl Radicals from Aromatic Carboxylic Acids by Means of Visible-Light Photoredox Catalysis

(2015) Giulia Bergonzini et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–H functionalization of terminal alkynes towards stereospecific synthesis of (E) or (Z) 2-methylthio-1,4-ene-diones

(2015) Shekaraiah Devari et al.   CHEMICAL COMMUNICATIONS

Transition-metal-free, ambient-pressure carbonylative cross-coupling reactions of aryl halides with potassium aryltrifluoroborates

(2015) Fengli Jin et al.   CHEMICAL COMMUNICATIONS

Room-Temperature Decarboxylative Couplings of α-Oxocarboxylates with Aryl Halides by Merging Photoredox with Palladium Catalysis

(2015) Wan-Min Cheng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nickel-catalysed Suzuki–Miyaura coupling of amides

(2015) Nicholas A. Weires et al.   Nature Chemistry

Decarboxylative 1,4-Addition of α-Oxocarboxylic Acids with Michael Acceptors Enabled by Photoredox Catalysis

(2015) Guang-Zu Wang et al.   ORGANIC LETTERS

Merging Photoredox with Palladium Catalysis: Decarboxylative ortho-Acylation of Acetanilides with α-Oxocarboxylic Acids under Mild Reaction Conditions

(2015) Chao Zhou et al.   ORGANIC LETTERS

Visible-Light-Promoted Photoredox Syntheses of α,β-Epoxy Ketones from Styrenes and Benzaldehydes under Alkaline Conditions

(2015) Jing Li et al.   ORGANIC LETTERS

Metal-Free CH Bond Activation of Branched Aldehydes with a Hypervalent Iodine(III) Catalyst under Visible-Light Photolysis: Successful Trapping with Electron-Deficient Olefins

(2014) Shin A. Moteki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A general metal free approach to α-ketoamides via oxidative amidation–diketonization of terminal alkynes

(2014) Ramesh Deshidi et al.   CHEMICAL COMMUNICATIONS

Metal-Catalyzed Reductive Coupling Reactions of Organic Halides with Carbonyl-Type Compounds

(2014) Toni Moragas et al.   CHEMISTRY-A EUROPEAN JOURNAL

Silver-catalyzed decarboxylative acylation of arylglyoxylic acids with arylboronic acids

(2014) Kai Cheng et al.   RSC Advances

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

Organocatalytic C–H Bond Arylation of Aldehydes to Bis-heteroaryl Ketones

(2013) Qiao Yan Toh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent developments in palladium catalysed carbonylation reactions

(2013) Sandip T. Gadge et al.   RSC Advances

Benzophenone Photosensitized DNA Damage

(2012) M. Consuelo Cuquerella et al.   ACCOUNTS OF CHEMICAL RESEARCH

Synthesis of Heterocycles via Palladium-Catalyzed Carbonylations

(2012) Xiao-Feng Wu et al.   CHEMICAL REVIEWS

Chemoselective synthesis of ketones and ketimines by addition of organometallic reagents to secondary amides

(2012) William S. Bechara et al.   Nature Chemistry

Synthesis of aromatic poly(ether ketone)s bearing optically active macrocycles through Suzuki coupling polymerization

(2012) Katsuya Maeyama et al.   POLYMER JOURNAL

Large-Scale Applications of Transition Metal-Catalyzed Couplings for the Synthesis of Pharmaceuticals

(2011) Javier Magano et al.   CHEMICAL REVIEWS

Palladium-catalyzed carbonylative coupling reactions between Ar–X and carbon nucleophiles

(2011) Xiao-Feng Wu et al.   CHEMICAL SOCIETY REVIEWS

Rh-Catalyzed Carbonylation of Arylzinc Compounds Yielding Symmetrical Diaryl Ketones by the Assistance of Oxidizing Agents

(2011) Kana Kobayashi et al.   JOURNAL OF ORGANIC CHEMISTRY

Discovery of an  -Amino C-H Arylation Reaction Using the Strategy of Accelerated Serendipity

(2011) A. McNally et al.   SCIENCE

Visible light photoredox catalysis: applications in organic synthesis

(2010) Jagan M. R. Narayanam et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Carbonylation Reactions of Aryl Halides and Related Compounds

(2009) Anne Brennführer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Design, Synthesis, and Structure−Activity Relationships of Benzophenone-Based Tetraamides as Novel Antibacterial Agents

(2009) Sunil K. Vooturi et al.   JOURNAL OF MEDICINAL CHEMISTRY

Merging Photoredox Catalysis with Organocatalysis: The Direct Asymmetric Alkylation of Aldehydes

(2008) D. A. Nicewicz et al.   SCIENCE