4.6 Article

Highly Fluorescent Non-Conventional Boron-Difluoride-Based Organogel with Gelation-Assisted Piezochromism

Journal

CHEMISTRY-AN ASIAN JOURNAL
Volume 12, Issue 2, Pages 198-202

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201601492

Keywords

boron; fluorescence; mechanochromism; gels; Pi interactions

Funding

  1. National Natural Science Foundation of China [21472111]
  2. China Three Gorges University [KJ2014H006]

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Triphenylamine-functionalized boron 2-(2'-pyridyl)imidazole complex bearing no alkyl chains or H-bond unit was found to be able to gelate a series of solvents, and the balanced intermolecular pi-pi interactions play an important role in its supramolecular self-assembly. The gelator molecule is piezochromic, and the dried gel responded to pressure more sensitively than regular crystalline powder.

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