Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 12, Issue 2, Pages 198-202Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201601492
Keywords
boron; fluorescence; mechanochromism; gels; Pi interactions
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Funding
- National Natural Science Foundation of China [21472111]
- China Three Gorges University [KJ2014H006]
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Triphenylamine-functionalized boron 2-(2'-pyridyl)imidazole complex bearing no alkyl chains or H-bond unit was found to be able to gelate a series of solvents, and the balanced intermolecular pi-pi interactions play an important role in its supramolecular self-assembly. The gelator molecule is piezochromic, and the dried gel responded to pressure more sensitively than regular crystalline powder.
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