Ethenolysis: A Green Catalytic Tool to Cleave Carbon-Carbon Double Bonds

Olefin Metathesis at the Dawn of Implementation in Pharmaceutical and Specialty-Chemicals Manufacturing

(2016) Carolyn S. Higman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Exploring the reactivity of a ruthenium complex in the metathesis of biorenewable feedstocks to generate value-added chemicals

(2016) Kathryn A. Alexander et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Sterically Driven Olefin Metathesis: The Impact of Alkylidene Substitution on Catalyst Activity

(2016) Justin A. M. Lummiss et al.   ORGANOMETALLICS

N-Trifluoromethyl NHC Ligands Provide Selective Ruthenium Metathesis Catalysts

(2016) Pascal S. Engl et al.   ORGANOMETALLICS

Valorisation of vegetable oils via metathesis reactions on solid catalysts: Cross-metathesis of methyl oleate with 1-hexene

(2015) J. Zelin et al.   APPLIED CATALYSIS A-GENERAL

Effect of Dispersion of the Active Phase on the Activity and Coke Formation over WO3/SiO2 Catalysts in the Metathesis of Ethylene and 2-Butene

(2015) Narongrat Poovarawan et al.   CATALYSIS LETTERS

Neutral and Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: Reactivity in Selected Olefin Metathesis Reactions and Immobilization on Silica

(2015) Suman Sen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stereocontrolled One-Step Synthesis of Difunctionalised Cispentacin Derivatives through Ring-Opening Metathesis of Norbornene β-Amino Acids

(2015) Loránd Kiss et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Comparison of Reactivity in the Cross Metathesis of Allyl Acetate-Derivatives with Oleochemical Compounds

(2015) Arno Behr et al.   JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY

Stereoselective synthesis of macrocyclic peptides via a dual olefin metathesis and ethenolysis approach

(2015) Shane L. Mangold et al.   Chemical Science

Investigation of the Enhancing Effect of Solid Cocatalysts on Propene Formation in Ethene/trans-2-Butene Metathesis over MoOx/SiO2–Al2O3

(2015) Vera Goelden et al.   ACS Catalysis

Decomposition of a Phosphine-Free Metathesis Catalyst by Amines and Other Bronsted Bases: Metallacyclobutane Deprotonation as a Major Deactivation Pathway

(2015) Benjamin J. Ireland et al.   ACS Catalysis

Cross-Metathesis of Microbial Oils for the Production of Advanced Biofuels and Chemicals

(2015) Rhodri W. Jenkins et al.   ACS Sustainable Chemistry & Engineering

Continuous Flow Metathesis for Direct Valorization of Food Waste: An Example of Cocoa Butter Triglyceride

(2015) Christiane Schotten et al.   ACS Sustainable Chemistry & Engineering

Cyclic Alkyl Amino Carbene (CAAC) Ruthenium Complexes as Remarkably Active Catalysts for Ethenolysis

(2014) Vanessa M. Marx et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

WO3-based catalysts prepared by non-hydrolytic sol-gel for the production of propene by cross-metathesis of ethene and 2-butene

(2014) Surasa Maksasithorn et al.   APPLIED CATALYSIS A-GENERAL

Metathesis of cardanol over Ru catalysts supported on mesoporous molecular sieve SBA-15

(2014) Tushar Shinde et al.   APPLIED CATALYSIS A-GENERAL

Ionic-tagged catalytic systems applied to the ethenolysis of methyl oleate

(2014) Guilherme L.P. Aydos et al.   CATALYSIS COMMUNICATIONS

Amine-Mediated Degradation in Olefin Metathesis Reactions that Employ the Second-Generation Grubbs Catalyst

(2014) Justin A. M. Lummiss et al.   ChemCatChem

The effect of supported MoOXstructures on the reaction pathways of propene formation in the metathesis of ethylene and 2-butene

(2014) T. Hahn et al.   CHEMICAL COMMUNICATIONS

Cross-Metathesis of Biosourced Fatty Acid Derivatives: A Step Further Toward Improved Reactivity

(2014) Paul Vignon et al.   ChemSusChem

Cross-metathesis of fatty acid methyl esters with acrolein: An entry to a variety of bifunctional compounds

(2014) Hélène Bonin et al.   EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY

Ruthenium catalyzed ethenolysis of renewable oleonitrile

(2014) Johan Bidange et al.   EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY

Metathesis reactions of rapeseed oil-derived fatty acid methyl esters induced by monometallic and homobimetallic ruthenium complexes

(2014) Bengi Özgün Öztürk et al.   EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY

Selective ethenolysis and oestrogenicity of compounds from cashew nut shell liquid

(2014) Jennifer Julis et al.   GREEN CHEMISTRY

Synthesis of tsetse fly attractants from a cashew nut shell extract by isomerising metathesis

(2014) S. Baader et al.   GREEN CHEMISTRY

Efficient Synthesis of α,ω-Divinyl-Functionalized Polyolefins

(2014) Vishal B. Patil et al.   MACROMOLECULAR CHEMISTRY AND PHYSICS

Acrylates via Metathesis of Crotonates

(2014) Dirk Schweitzer et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Donor-Induced Decomposition of the Grubbs Catalysts: An Intercepted Intermediate

(2014) Justin A. M. Lummiss et al.   ORGANOMETALLICS

Influence of the preparation procedure on the properties of supported molybdenum catalysts for ethylene and trans-butene-2 metathesis to propylene

(2014) A. V. Gordeev et al.   PETROLEUM CHEMISTRY

An expeditious approach to highly functionalized angularly fused 5–5–n ring systems through ring opening–ring closing metathesis of norbornene derivatives

(2014) Ritabrata Datta et al.   TETRAHEDRON LETTERS

Terminal conjugated dienes via a ruthenium-catalyzed cross-metathesis/elimination sequence: application to renewable resources

(2014) Hallouma Bilel et al.   Catalysis Science & Technology

Cross-metathesis of methyl 10-undecenoate with dimethyl maleate: an efficient protocol with nearly quantitative yields

(2014) A. Behr et al.   RSC Advances

Cross-metathesis approach to produce precursors of nylon 12 and nylon 13 from microalgae

(2014) Godwin Ameh Abel et al.   RSC Advances

Isomerization During Olefin Metathesis: An Assessment of Potential Catalyst Culprits

(2013) Carolyn S. Higman et al.   ChemCatChem

Ruthenium-catalyzed olefin metathesis accelerated by the steric effect of the backbone substituent in cyclic (alkyl)(amino) carbenes

(2013) Jun Zhang et al.   CHEMICAL COMMUNICATIONS

Isomerizing Ethenolysis as an Efficient Strategy for Styrene Synthesis

(2013) Sabrina Baader et al.   CHEMISTRY-A EUROPEAN JOURNAL

Long-chain polyesters and polyamides from biochemically derived fatty acids

(2013) Nicolai Kolb et al.   EUROPEAN POLYMER JOURNAL

Study of ethylene/2-butene cross-metathesis over W-H/Al2O3 for propylene production: Effect of the temperature and reactant ratios on the productivity and deactivation

(2013) Etienne Mazoyer et al.   JOURNAL OF CATALYSIS

Influence of preparation method on the catalytic performances of Re2O7/SiO2-Al2O3 catalysts in the metathesis of ethylene and 2-pentene

(2013) Weena Phongsawat et al.   JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY

Z-Selective Ethenolysis with a Ruthenium Metathesis Catalyst: Experiment and Theory

(2013) Hiroshi Miyazaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Methylidene Complexes that Contain a 2,6-Dimesitylphenylimido Ligand and Ethenolysis of 2,3-Dicarbomethoxynorbornadiene

(2013) Laura C. H. Gerber et al.   ORGANOMETALLICS

Metathetic degradation of trans-1,4-polyisoprene with ruthenium catalysts

(2013) Samira Ouardad et al.   POLYMER DEGRADATION AND STABILITY

The regioselective outcome of ring rearrangement metathesis transformations performed on bicyclo[2.2.2]oct-2-ene derivatives

(2013) Patricia E. Standen et al.   TETRAHEDRON LETTERS

Concise Syntheses of Insect Pheromones UsingZ-Selective Cross Metathesis

(2012) Myles B. Herbert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Effect of SiO2–Al2O3 Composition on the Catalytic Performance of the Re2O7/SiO2–Al2O3 Catalysts in the Metathesis of Ethylene and 2-Pentene for Propylene Production

(2012) Weena Phongsawat et al.   CATALYSIS LETTERS

Renewable linear alpha olefins by selective ethenolysis of decarboxylated unsaturated fatty acids

(2012) Frits van der Klis et al.   EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY

Simultaneous production of biobased styrene and acrylates using ethenolysis

(2012) Jurjen Spekreijse et al.   GREEN CHEMISTRY

On the ethenolysis of end-of-life tire granulates

(2012) Stefanie Wolf et al.   GREEN CHEMISTRY

Role of support nature (γ-Al2O3 and SiO2-Al2O3) on the performances of rhenium oxide catalysts in the metathesis of ethylene and 2-pentene

(2012) Weena Phongsawat et al.   Journal of Natural Gas Chemistry

Stereoselective Access to Z and E Macrocycles by Ruthenium-Catalyzed Z-Selective Ring-Closing Metathesis and Ethenolysis

(2012) Vanessa M. Marx et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metathesis Transformations of Natural Products: Cross-Metathesis of Natural Rubber and Mandarin Oil by Ru-Alkylidene Catalysts

(2012) Araceli Martínez et al.   MOLECULES

The stereochemical outcome of allyl magnesium and indium additions to 5-substituted norbornen-7-ones and its application to cis fused carbocycle formation via ring rearrangement metathesis

(2012) Patricia E. Standen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Reactions of Grubbs Catalysts with Excess Methoxide: Formation of Novel Methoxyhydride Complexes

(2012) Nicholas J. Beach et al.   ORGANOMETALLICS

A Highly Efficient Olefin Metathesis Process for the Synthesis of Terminal Alkenes from Fatty Acid Esters

(2012) Andrew Nickel et al.   TOPICS IN CATALYSIS

Robust and Selective Metathesis Catalysts for Oleochemical Applications

(2012) Renat Kadyrov et al.   TOPICS IN CATALYSIS

Targeting an Achilles heel in olefin metathesis: A strategy for high-yield synthesis of second-generation Grubbs methylidene catalysts

(2012) Justin A. M. Lummiss et al.   Catalysis Science & Technology

Ethenolysis of ricinoleic acid methyl ester – an efficient way to the oleochemical key substance methyl dec-9-enoate

(2012) A. Behr et al.   RSC Advances

Ring Size-Selective Ring-Closing Olefin Metathesis: Taking Advantage of the Deleterious Effect of Ethylene Gas

(2011) Kazuhiro Yoshida et al.   ADVANCED SYNTHESIS & CATALYSIS

Ethene-Induced Temporary Inhibition of Grubbs Metathesis Catalysts

(2011) Judith Scholz et al.   ADVANCED SYNTHESIS & CATALYSIS

The cross-metathesis of methyl oleate withcis-2-butene-1,4-diyl diacetate and the influence of protecting groups

(2011) Arno Behr et al.   Beilstein Journal of Organic Chemistry

Ene–yne cross-metathesis with ruthenium carbene catalysts

(2011) Cédric Fischmeister et al.   Beilstein Journal of Organic Chemistry

Ring-Rearrangement Metathesis of Nitroso Diels-Alder Cycloadducts

(2011) Guillaume Vincent  et al.   CHEMISTRY-A EUROPEAN JOURNAL

Lowering the boiling point curve of biodiesel by cross-metathesis

(2011) Rowena E. Montenegro et al.   EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY

On the ethenolysis of natural rubber and squalene

(2011) Stefanie Wolf et al.   GREEN CHEMISTRY

Ruthenium–alkylidene catalysed cross-metathesis of fatty acid derivatives with acrylonitrile and methyl acrylate: a key step toward long-chain bifunctional and amino acid compounds

(2011) X. Miao et al.   GREEN CHEMISTRY

Ring-Rearrangement Metathesis of 1-Substituted 7-Azanorbornenes as an Entry to 1-Azaspiro[4.5]decane systems

(2011) Javier Carreras et al.   JOURNAL OF ORGANIC CHEMISTRY

Alkene Metathesis Approach to β-Unsubstituted Anti-Allylic Alcohols and Their Use in Ene–Yne Metathesis

(2011) Joseph R. Clark et al.   JOURNAL OF ORGANIC CHEMISTRY

Isolation of Pure DisubstitutedEOlefins through Mo-CatalyzedZ-Selective Ethenolysis of Stereoisomeric Mixtures

(2011) Smaranda C. Marinescu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Probing the Origin of Degenerate Metathesis Selectivity via Characterization and Dynamics of Ruthenacyclobutanes Containing Variable NHCs

(2011) Benjamin K. Keitz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Improved Ruthenium Catalysts for Z-Selective Olefin Metathesis

(2011) Benjamin K. Keitz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Ruthenium Metathesis Catalysts for Ethenolysis

(2011) Renee M. Thomas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Characterization and Dynamics of Substituted Ruthenacyclobutanes Relevant to the Olefin Cross-Metathesis Reaction

(2011) Anna G. Wenzel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Co-metathesis of ethylene and olefinic compounds in ionic liquids

(2011) Alexander A. Greish et al.   MENDELEEV COMMUNICATIONS

Low Pressure Ethenolysis of Renewable Methyl Oleate in a Microchemical System

(2011) Chan Pil Park et al.   ORGANIC LETTERS

An efficient stereoselective route to the construction of tricyclic core structure towards the synthesis of the sesquiterpenes of the seco-prezizaane family

(2011) Ram Naresh Yadav et al.   TETRAHEDRON LETTERS

Acyclic dienemetathesis: a versatile tool for the construction of defined polymer architectures

(2010) Hatice Mutlu et al.   CHEMICAL SOCIETY REVIEWS

Improving Sustainability in Ene-Yne Cross-Metathesis for Transformation of Unsaturated Fatty Esters

(2010) Virginie Le Ravalec et al.   ChemSusChem

Cross metathesis of butene-2 and ethene to propene over Mo/MCM-22-Al2O3 catalysts with different Al2O3 contents

(2010) Shenglin Liu et al.   Journal of Natural Gas Chemistry

Hydrogenolysis versus Methanolysis of First- and Second-Generation Grubbs Catalysts: Rates, Speciation, and Implications for Tandem Catalysis†

(2010) Nicholas J. Beach et al.   ORGANOMETALLICS

Formation of a Ruthenium(II) Dicyclohexyl(η2-cyclohex-3-enyl)phosphine Hydride Complex from an Alkylidene Precursor

(2010) Wai-Man Cheung et al.   ORGANOMETALLICS

Metathesis of renewable products: degradation of natural rubber via cross-metathesis with β-pinene using Ru-alkylidene catalysts

(2010) Selena Gutiérrez et al.   POLYMER BULLETIN

Stability of Second Generation Grubbs’ Alkylidenes to Primary Amines: Formation of Novel Ruthenium-Amine Complexes

(2009) Gerald O. Wilson et al.   ADVANCED SYNTHESIS & CATALYSIS

First Transformation of Unsaturated Fatty Esters Involving Enyne Cross-Metathesis

(2009) Virginie Le Ravalec et al.   ADVANCED SYNTHESIS & CATALYSIS

Grubbs’ Ruthenium-Carbenes Beyond the Metathesis Reaction: Less Conventional Non-Metathetic Utility

(2009) Benito Alcaide et al.   CHEMICAL REVIEWS

Diethyl carbonate as a solvent for ruthenium catalysed C–H bond functionalisation

(2009) Percia Arockiam et al.   GREEN CHEMISTRY

Effect of Phase Behavior on the Ethenolysis of Ethyl Oleate in Compressed CO2

(2009) Jiyuan Song et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Use of a Renewable and Degradable Monomer to Study the Temperature-Dependent Olefin Isomerization during ADMET Polymerizations

(2009) Patrice A. Fokou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ethenolysis Reactions Catalyzed by Imido Alkylidene Monoaryloxide Monopyrrolide (MAP) Complexes of Molybdenum

(2009) Smaranda C. Marinescu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ring-Rearrangement Metathesis of Cyclopropenes: Synthesis of Heterocycles

(2009) Frédéric Miege et al.   ORGANIC LETTERS

Determination of absolute configuration of C14−C23 fragment in symbiodinolide

(2009) Chunguang Han et al.   TETRAHEDRON LETTERS

Total Synthesis of Aburatubolactam A

(2008) James A. Henderson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cross-metathesis reactions of allyl chloride with fatty acid methyl esters: Efficient synthesis of α,ω-difunctional chemical intermediates from renewable raw materials

(2008) Tina Jacobs et al.   APPLIED CATALYSIS A-GENERAL

The preparation of active WO3 catalysts for metathesis between ethene and 2-butene under moist atmosphere

(2008) H LIU et al.   CATALYSIS COMMUNICATIONS

Dimethyl Carbonate: An Eco-Friendly Solvent in Ruthenium-Catalyzed Olefin Metathesis Transformations

(2008) Xiaowei Miao et al.   ChemSusChem

Ruthenium Olefin Metathesis Catalysts for the Ethenolysis of Renewable Feedstocks

(2008) Yann Schrodi et al.   CLEAN-Soil Air Water

Generation and Spectroscopic Characterization of Ruthenacyclobutane and Ruthenium Olefin Carbene Intermediates Relevant to Ring Closing Metathesis Catalysis

(2008) Edwin F. van der Eide et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

ESI-MS Study on First-Generation Ruthenium Olefin Metathesis Catalysts in Solution: Direct Detection of the Catalytically Active 14-Electron Ruthenium Intermediate

(2008) Haoyang Wang et al.   ORGANOMETALLICS

Kinetic Selectivity of Olefin Metathesis Catalysts Bearing Cyclic (Alkyl)(Amino)Carbenes

(2008) Donde R. Anderson et al.   ORGANOMETALLICS

GC-MS Analysis of β-Carotene Ethenolysis Products and their Synthesis as Potentially Active Vitamin A Analogues

(2008) I. Jermacz et al.   TOXICOLOGY MECHANISMS AND METHODS

Ethenolysis of Methyl Oleate in Room-Temperature Ionic Liquids

(2007) Cyril Thurier et al.   ChemSusChem