Rh-Catalyzed Chemo- and Enantioselective Hydrogenation of Allylic Hydrazones

An Iridium(I) N-Heterocyclic Carbene Complex Catalyzes Asymmetric Intramolecular Allylic Amination Reactions

(2016) Ke-Yin Ye et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective synthesis of β-substituted chiral allylic amines via Rh-catalyzed asymmetric hydrogenation

(2016) Qingli Wang et al.   CHEMICAL COMMUNICATIONS

Asymmetric Hydrogenation of Nonaromatic Cyclic Substrates

(2016) Zhenfeng Zhang et al.   CHEMICAL REVIEWS

Iridium-Catalyzed Asymmetric Hydrogenation of Unfunctionalized Exocyclic C=C Bonds

(2016) Jingzhao Xia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ru-Catalyzed Asymmetric Hydrogenative/Transfer Hydrogenative Desymmetrization of Meso-Epoxy Diketones

(2016) Yuping Hong et al.   ORGANIC LETTERS

Rh-Catalyzed One-Pot Sequential Asymmetric Hydrogenation of α-Dehydroamino Ketones for the Synthesis of Chiral Cyclic trans-β-Amino Alcohols

(2016) Qiupeng Hu et al.   ORGANIC LETTERS

Asymmetric Hydrogenation of α-Substituted Acrylic Acids Catalyzed by a Ruthenocenyl Phosphino-oxazoline–Ruthenium Complex

(2016) Jing Li et al.   ORGANIC LETTERS

Recent Developments in Asymmetric Allylic Amination Reactions

(2016) P. Evans et al.   SYNTHESIS-STUTTGART

Asymmetric synthesis of allylic amines via hydroamination of allenes with benzophenone imine

(2016) Kun Xu et al.   Chemical Science

Asymmetric Hydrogenation of β-Secondary Amino Ketones Catalyzed by a Ruthenocenyl Phosphino-oxazoline-ruthenium Complex (RuPHOX-Ru): the Synthesis of γ-Secondary Amino Alcohols

(2015) Jianxia Wang et al.   ADVANCED SYNTHESIS & CATALYSIS

Kinetic resolution of primary allylic amines via palladium-catalyzed asymmetric allylic alkylation of malononitriles

(2015) Yong Wang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rh-Catalyzed Asymmetric Hydrogenation of Cyclic α-Dehydroamino Ketones

(2015) Zhenfeng Zhang et al.   ORGANIC LETTERS

Mechanism of the Asymmetric Hydrogenation of Exocyclic α,β-Unsaturated Carbonyl Compounds with an Iridium/BiphPhox Catalyst: NMR and DFT Studies

(2014) Yuanyuan Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Asymmetric Dearomatization of Pyridines and Pyrazines by Iridium-Catalyzed Allylic Amination Reactions

(2014) Ze-Peng Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperative Catalysis by Palladium and a Chiral Phosphoric Acid: Enantioselective Amination of Racemic Allylic Alcohols

(2014) Debasis Banerjee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

ZnCl2-Promoted Asymmetric Hydrogenation of β-Secondary-Amino Ketones Catalyzed by a P-Chiral Rh-Bisphosphine Complex

(2014) Qiupeng Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Regio- and Enantioselective Synthesis of N-Substituted 2-Pyridones: Iridium-Catalyzed Intermolecular Asymmetric Allylic Amination

(2014) Xiao Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed aerobic oxidative coupling of enantioenriched primary allylic amines with sulfonyl hydrazides leading to optically active allylic sulfones

(2014) Ting-Ting Wang et al.   CHEMICAL COMMUNICATIONS

Highly Enantioselective Synthesis of Chiral Cyclic Allylic Amines via Rh-Catalyzed Asymmetric Hydrogenation

(2014) Ming Zhou et al.   ORGANIC LETTERS

Catalytic stereospecific allylation of protected hydrazines with enantioenriched primary allylic amines

(2014) Yong Wang et al.   Organic Chemistry Frontiers

Iridium-Catalyzed Asymmetric Hydrogenation of α-Alkylidene Succinimides

(2013) Yuanyuan Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Asymmetric Hydrogenation of α-Acyloxy-1-arylethanones

(2013) Jianzhong Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Chiral Aliphatic Amines through Asymmetric Hydrogenation

(2013) Tang-Lin Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Non-enzymatic acylative kinetic resolution of primary allylic amines

(2013) Amandine Kolleth et al.   CHEMICAL COMMUNICATIONS

Progress on the Catalytic Asymmetric Hydrogenation of Imines

(2013) Dong Wang et al.   CHINESE JOURNAL OF ORGANIC CHEMISTRY

Spiroketal-Based Diphosphine Ligands in Pd-Catalyzed Asymmetric Allylic Amination of Morita–Baylis–Hillman Adducts: Exceptionally High Efficiency and New Mechanism

(2013) Xiaoming Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Rh-Catalyzed Alkenylation of Imines: Synthesis of Chiral Allylic Amines via Asymmetric Addition of Potassium Alkenyltrifluoroborates to N-Tosyl Imines

(2013) Balraj Gopula et al.   ORGANIC LETTERS

New Progress and Prospects of Transition Metal-Catalyzed Asymmetric Hydrogenation

(2012) Jianhua Xie et al.   ACTA CHIMICA SINICA

Asymmetric Hydrogenation of N-Arylimines Catalyzed by the Xyl-Skewphos/DPEN-Ruthenium(II) Complex

(2012) Noriyoshi Arai et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective Rhodium-Catalyzed Synthesis of Branched Allylic Amines by Intermolecular Hydroamination of Terminal Allenes

(2012) Michael L. Cooke et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Allylic Amination of Unactivated Terminal Olefins via an Ene Reaction/[2,3]-Rearrangement

(2012) Hongli Bao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Substitution of Primary Allylic Amines with Sulfinate Salts

(2012) Xue-Song Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Allylic Amines as Key Building Blocks in the Synthesis of (E)-Alkene Peptide Isosteres

(2012) Erin M. Skoda et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Cooperative Transition-Metal and Chiral Brønsted Acid Catalysis: Enantioselective Hydrogenation of Imines To Form Amines

(2011) Shaolin Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Hydrogenation of Heteroarenes and Arenes

(2011) Duo-Sheng Wang et al.   CHEMICAL REVIEWS

C–N Bond Cleavage of Allylic Amines via Hydrogen Bond Activation with Alcohol Solvents in Pd-Catalyzed Allylic Alkylation of Carbonyl Compounds

(2011) Xiaohu Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rigid P-Chiral Phosphine Ligands with tert-Butylmethylphosphino Groups for Rhodium-Catalyzed Asymmetric Hydrogenation of Functionalized Alkenes

(2011) Tsuneo Imamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly effective chiral phosphorus amidite–olefin ligands for palladium-catalyzed asymmetric allylic substitutions

(2011) Zhaoqun Liu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A Dual-Catalysis/Anion-Binding Approach to the Kinetic Resolution of Allylic Amines

(2011) Eric G. Klauber et al.   ORGANIC LETTERS

Iridium-Catalyzed Highly Enantioselective Hydrogenation of Exocyclic α,β-Unsaturated Carbonyl Compounds

(2010) Fengtao Tian et al.   ADVANCED SYNTHESIS & CATALYSIS

Transition Metal-Catalyzed Enantioselective Hydrogenation of Enamines and Imines

(2010) Jian-Hua Xie et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Dynamic Kinetic Asymmetric Transformations of Vinyl Aziridines with Nitrogen Heterocycles: Rapid Access to Biologically Active Pyrroles and Indoles

(2010) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiopure 1,2-Bis(tert-butylmethylphosphino)benzene as a Highly Efficient Ligand in Rhodium-Catalyzed Asymmetric Hydrogenation

(2010) Ken Tamura et al.   ORGANIC LETTERS

Enantioselective, Iridium-Catalyzed Monoallylation of Ammonia

(2009) Mark J. Pouy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stable Preformed Chiral Palladium Catalysts for the One-Pot Asymmetric Reductive Amination of Ketones

(2008) Laura Rubio-Pérez et al.   ORGANIC LETTERS

Asymmetric addition of phenylzinc reagents to C-alkynyl nitrones. Enantiomeric enhancement by a product-like additive

(2008) Weilin Wei et al.   TETRAHEDRON-ASYMMETRY