Journal
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
Volume 75, Issue 4, Pages 379-382Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1515/znb-2019-0225
Keywords
crystal structure; fluorescence; N,O-functional ligand; Zn(II)
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Funding
- Natural Science Foundation for Universities in Jiangsu Province [16KJB150005]
- Huaiyin Institute of Technology [15HGZ006, 491713325]
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The hydrothermal reaction of Zn(II) nitrate hydrate with 5-(pyridin-4-yl)isophthalic acid (H2L) yields the complex [Zn-2(L)(2)(H2O)(2)]center dot 2(H2O) (1), which has been characterized by single crystal X-ray diffraction, IR spectroscopic, elemental, and thermogravimetric analyses. Complex 1 exhibits a 3-nodal (3,6)-connected 2D net structure with (4.6(2))(2)(4(2).6(10).8(3))(6(3))(4) topology. Its luminescence property was investigated, but the results show that the coordination to the zinc atom has no significant effect on the emission of the ligand.
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