Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 22, Issue 51, Pages 18349-18353Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201604103
Keywords
anion-binding; hydrogen bonds; organocatalysis; self-assembly; silanol
Categories
Funding
- National Science Foundation [CHE-0847358, CHE-1363375]
- UC Davis Borge Fellowship
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1363375] Funding Source: National Science Foundation
Ask authors/readers for more resources
A series of new 1,3-disiloxanediols has been synthesized, including naphthyl-substituted and unsymmetrical siloxanes, and demonstrated as a new class of anion-binding catalysts. In the absence of anions, diffusion-ordered spectroscopy (DOSY) displays self-association of 1,3-disiloxanediols through hydrogen-bonding interactions. Binding constants determined for 1,3-disiloxanediol catalysts indicate strong hydrogen-bonding and anion-binding abilities with unsymmetrical siloxanes displaying different hydrogen-bonding abilities for each silanol group.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available