Journal
TETRAHEDRON LETTERS
Volume 61, Issue 26, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2020.152035
Keywords
Selectfluor; N-Heterocycles; Diaryl diselenide; Selanylation reaction; C-H functionalization
Categories
Funding
- Fundacao de Amparo a Pesquisa do Estado do Rio Grande do Sul (FAPERGS) [ARD 16/2551-0000358-0, PRONEM 16/2551-0000240-1]
- Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq)
- Financiadora de Estudos e Projetos (FINEP)
- Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior - Brasil (CAPES) [001]
- CNPq [142366/2017-0, 308015/2019-3]
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The direct selanylation of a diverse array of (hetero)arenes, including imidazo[2, 1-b]thiazole, imidazo [1, 2-a]pyridine, 1H-indole, 1H-pyrazole, isoxazole and naphthalen-2-ol is presented. The reactions are mediated by Selectfluor, as a stable, easy to handle and commercially available oxidant. The methodology features simple, mild and safe reaction conditions to produce non-symmetrical diorganyl selenides in moderate to excellent yields. The reactions were conducted at room temperature in air using NaHCO3 in acetonitrile. (C) 2020 Elsevier Ltd. All rights reserved.
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