Journal
CHEMISTRY LETTERS
Volume 45, Issue 8, Pages 866-868Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.160410
Keywords
Dinuclear iridium complex; Stereoselective semi-hydrogenation; Alkyne
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Semi-hydrogenation of alkynes was catalyzed by halide-bridged dinuclear iridium complexes, yielding (E)-alkenes with high selectivity. Mechanistic studies conducted with mono hydride dinuclear species, dihydride mononuclear species, and trihydride dinuclear species led us to propose a mechanism involving dual cycles.
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