Journal
CHEMISTRY LETTERS
Volume 45, Issue 12, Pages 1437-1439Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.160766
Keywords
Hydrogen storage; Electrocatalytic hydrogenation; PEM reactor
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Funding
- Council for Science, Technology and Innovation (CSTI), Cross-ministerial Strategic Innovation Promotion Program (SIP), energy carrier (Funding agency: JST)
- JSPS KAKENHI [JP15H05847]
- Grants-in-Aid for Scientific Research [15K13691, 15H03843, 15H05847] Funding Source: KAKEN
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The electrocatalytic hydrogenation of o-xylene in a proton-exchange membrane (PEM) reactor with various cathode catalysts was carried out as a study of a model reaction for hydrogen storage. o-Xylene introduced in a PEM reactor underwent electrocatalytic hydrogenation to provide cis-1,2-dimethylcyclohexane as the main stereoisomer with moderate to good current efficiencies. The reaction proceeded in accordance with the Langmuir-Hinshelwood mechanism.
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