4.3 Article

Sodium carbonate treatment of fibres to improve mechanical and water absorption characteristics of short bamboo natural fibres reinforced polyester composite

Journal

PLASTICS RUBBER AND COMPOSITES
Volume 49, Issue 10, Pages 425-433

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1080/14658011.2020.1768336

Keywords

Surface modification; bamboo natural fibres; polyester matrix; mechanical properties; thermo-gravimetric analysis

Funding

  1. Pakistan Science Foundation [PSF/Res/KPK-GIKI/Eng. (170)]
  2. Ghulam Ishaq Khan Institute's Graduate Assistantship Scheme [GA-1]
  3. Ghulam Ishaq Khan Institute of Engineering Sciences and Technology Topi-Pakistan

Ask authors/readers for more resources

The effect of sodium carbonate (Na2CO3) treatment of short bamboo fibres on mechanical properties and water absorption character of polyester composite is investigated. Treatment time and Na2CO3 concentration were optimised to 6 h and 5 wt-% respectively. Microscopy of the treated fibres showed a significant change in surface texture whereas; FTIR suggested the removal of amorphous compounds from the fibres that resulted in enhanced interfacial bonding between fibres and the polyester matrix. Removal of amorphous compounds was also confirmed by TGA where material loss for untreated fibres was 15% higher than the treated fibres. Composites were prepared using 10, 20 and 30 wt-% of treated and untreated fibres. Good interfacial bonding, achieved by the fibre treatment, enhanced the strength (similar to 24 MPa),( decreased the impact energy (from similar to 36x10(-3) KJ/m(2) to similar to 33x10(-3) KJ/m(2)) and improved the water absorption resistance (similar to 2%) in case of 20 wt-% fibres composite.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.3
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Materials Science, Composites

Improved mechanical and water absorption properties of epoxy-bamboo long natural fibres composites by eco-friendly Na2CO3 treatment

Muhammad Ramzan Abdul Karim, Danish Tahir, Khurram Imran Khan, Azhar Hussain, Ehsan Ul Haq, Muhammad Sohail Malik

Summary: Epoxy-bamboo long natural fibres composites were prepared by hand lay-up method to study the influence of fibre's treatment on their characteristics. SEM showed increased surface roughness due to the removal of amorphous compounds from the treated fibre as confirmed by the disappearance of certain peaks in FTIR spectroscopy. Resultantly, similar to 52% increase in crystallinity was observed by XRD analysis. TGA results also showed the effectiveness of the treatment as mass loss for treated fibres was similar to 15% lesser than the untreated fibres. Moreover, thermogravimetric analysis of composites showed highest mass loss in untreated fibres composites and lowest in neat epoxy. The DSC-DTA curves indicated an early start of initiation temperature in treated fibre composite. Tension tests showed similar to 12% and similar to 16% increase in tensile strength and modulus respectively for treated fibres composite due to increased interfacial strength caused by fibre treatment. Treatment also resulted in decreased impact energy and water absorption level.

PLASTICS RUBBER AND COMPOSITES (2023)

Review Materials Science, Ceramics

Hexagonal boron nitride-based composites: an overview of processing approaches and mechanical properties

Muhammad Ramzan Abdul Karim, Muhammad Awais Khan, Atteeq Uz Zaman, Azhar Hussain

Summary: Hexagonal boron nitride (h-BN)-based composites have versatile and significantly improved properties, making them highly valuable in various industries. This review article critically examines the crystal structure and enhanced properties of h-BN, as well as the fabrication methods, mechanical properties, and applications of h-BN-based ceramics and composites with different materials. The results show that hot pressing enhances mechanical properties through the incorporation of BN, while pressureless sintering leads to poor mechanical properties due to porosity and poor bonding between h-BN grains. These findings provide valuable insights for the development and application of h-BN-based materials.

JOURNAL OF THE KOREAN CERAMIC SOCIETY (2023)

Article Materials Science, Multidisciplinary

Synthesis and electrochemical energy storage performance evaluation of PANI functionalized CNTs/Ni-Zn (PO4)2 nanocomposites

Waseem Shehzad, Muhammad Ramzan Abdul Karim

Summary: In this study, nanocomposites of binary transition metal phosphate [Ni0.75Zn0.25 (PO4)(2)] with PANI-CNTs were prepared and characterized for potential use in electrochemical energy storage. The highest-performing electrode, NZP60, exhibited a specific capacity of 1143 Cg(-1) and an exceptional energy density of 89.2 Wh kg(-1) in an asymmetric supercapacitor device. The cyclic performance (99.86% after 5000 cycles) and rate performance (25% increase after stability test) were excellent, indicating the high potential of Ni-Zn binary metal phosphate/PANI-CNTs nanocomposites in energy storage applications.

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING (2023)

Article Chemistry, Multidisciplinary

Comparative study of enhanced catalytic properties of clay-derived SiO2 catalysts for biodiesel production from waste chicken fat

Iqra Riaz, Obaid Ali Qamar, Farrukh Jamil, Murid Hussain, Abrar Inayat, Lisandra Rocha-Meneses, Parveen Akhter, Sara Musaddiq, Muhammad Ramzan Abdul Karim, YoungKwon Park

Summary: The use of clay derived SiO2 catalyst impregnated with SrO, Bi2O3, CuO and CaO is an effective and efficient method for biodiesel production from waste chicken fat (WCF). By optimizing the reaction parameters, including methanol to oil ratio, catalyst loading, reaction temperature and time, a maximum biodiesel yield of 98.9% can be achieved.

KOREAN JOURNAL OF CHEMICAL ENGINEERING (2023)

Article Engineering, Chemical

Novel MoS2-sputtered NiCoMg MOFs for high-performance hybrid supercapacitor applications

Muhammad Fawad Khan, Mohsin Ali Marwat, Abdullah, Syed Shaheen Shah, Muhammad Ramzan Abdul Karim, Md. Abdul Aziz, Zia Ud Din, Saad Ali, Kanwar Muhammad Adam

Summary: In this study, three types of electrode materials were prepared, and the capacitance of the electrode materials was improved by MoS2 sputtering technology. A cactus-like microstructure of S-NiCoMg electrode was successfully prepared. The S-NiCoMg electrode exhibited a specific capacitance of 2000 F/g, which was higher than the other two electrodes. It also showed excellent specific capacitance, energy density, and power density, indicating its potential as electrode materials for supercapacitors.

SEPARATION AND PURIFICATION TECHNOLOGY (2023)

Article Mechanics

Load-bearing characteristics of 3D auxetic structures made with carbon fiber reinforced polymer composite

Ehsan Etemadi, Minglonghai Zhang, Keda Li, Mohammad Bashtani, Danish Tahir, Mabel Mei Po Ho, Hong Hu

Summary: This paper presents a study on 3D novel hybrid auxetic structures made with carbon fiber reinforced polymer (CFRP) laminate composite. The mechanical characteristics of the designed structures, such as Young's modulus, shear modulus, and Poisson's ratio, are evaluated through theoretical analysis and finite element simulation. The results show that the structures have negative Poisson's ratio values in all ranges of design geometry parameters. The optimized geometry parameters are achieved through a multi-objective optimization method based on maximizing stiffness and minimizing relative density responses. Additionally, the mechanical behaviors of the assembled 3D structures are studied through quasi-static compressive tests to measure the negative Poisson's ratio values using strain gauges and a video extensometer. The proposed structures exhibit superior stiffness and high elongation percentage, making them a strong candidate for the next generation of load-bearing auxetic structures.

COMPOSITE STRUCTURES (2023)

Article Materials Science, Multidisciplinary

Improved energy storage performance of sonochemically synthesized Ni-Co-Zn ternary metal phosphate composites by incorporating PANI functionalized CNTs

Waseem Shehzad, Muhammad Ramzan Abdul Karim

Summary: The multi-walled carbon nanotubes were functionalized with polyaniline through chemical grafting, followed by the addition of ternary transition metal phosphate. The resulting nanocomposites exhibited excellent electrochemical performance in energy storage devices, with a specific capacity of 1438 Cg-1 and an energy density of 104 Whkg � 1. The hierarchical structure of the composite played a crucial role in achieving these desirable properties.

DIAMOND AND RELATED MATERIALS (2023)

Article Chemistry, Physical

Ti3SiC2-coupled NiCoMn LDH nanocomposites as positive electrode for high performance supercapacitors

Saad Ali, Mohsin Ali Marwat, Muhammad Fawad Khan, Kanwar Muhammad Adam, Zia Ud Din, Muhammad Ramzan Abdul Karim, Sohail Khan

Summary: In this study, nickel-cobalt-manganese layered double hydroxides (LDH) and its composites with Ti3SiC2 MAXenes were synthesized using the probe sonication method. It was found that the LDH/M6 electrode had a higher specific capacitance compared to the other electrodes, demonstrating the effectiveness of using Ti3SiC2 MAXenes nanosheets. The LDH/M6 electrode also showed excellent stability with 93% capacity retention after 4000 cycles, suggesting its potential application in high-performance supercapacitors.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Engineering, Chemical

Analysis of mechanical and water absorption properties of hybrid composites reinforced with micron-size bamboo fibers and ceramic particles

Danish Tahir, Muhammad Ramzan Abdul Karim, Hong Hu

Summary: By adding filler, the density and tensile strength of bamboo and its hybrid composites increased, while the impact strength decreased and hardness increased. The addition of filler also improved the water resistance of the composites.

INTERNATIONAL POLYMER PROCESSING (2023)

Article Electrochemistry

Exploring the electrochemical utilization of PANI/CNT-integrated Ni-Mn phosphates for advanced supercapacitor applications

Zaheer Abbas, Muhammad Ramzan Abdul Karim, Waseem Shehzad, Nemah Abu Shama, Jai Kumar, Sirajuddin, Selcan Karakus, Razium Ali Soomro, Ayman Nafady

Summary: This study demonstrates the utilization of polyaniline/multiwalled carbon nanotubes as a conductive scaffold for the formation of nickel manganese phosphate heterostructures, resulting in the development of an efficient hybrid super-capacitor. The optimized composite, PCNT-NMP-40, exhibits outstanding energy density and power density as a positive electrode in a two-electrode cell configuration.

ELECTROCHIMICA ACTA (2023)

Article Energy & Fuels

Design and development of NbTiVZr porous high entropy alloys for energy applications

Ayesha Siddique, Talha Abid, M. Aftab Akram, Talha Bin Yaqub, M. Ramzan Abdul Karim, Filipe Fernandes, Rizwan Khan, Khurram Yaqoob

Summary: Porous NbTiVZr refractory high entropy alloys have been successfully developed by adding yttrium to the base alloy and subsequently removing it through an electrochemical process. The resulting alloys exhibit excellent electrochemical performance, making them potential candidates for supercapacitor electrodes.

JOURNAL OF ENERGY STORAGE (2023)

Article Multidisciplinary Sciences

A Low-Cost Novel Talc-Based Opaque Glaze for Ceramic Floor Tiles

Khuram Imran Khan, Murtaza Khan, Azhar Hussain, Muhammad Ramzan Abdul Karim, Saad Ullah Khan, Sajjad Hussain, Hammad Amjad Khan

Summary: This research investigates the use of talc as a replacement for zirconium silicate in ceramic floor tile glaze to reduce costs. The experiment shows that complete replacement of zirconium silicate with talc can achieve better opacity in the glaze. There are no significant changes observed in the resistance of the fired sample tiles to chemical attack. Economic analysis reveals that the use of talc can reduce the cost of opacifier by 82%.

ARABIAN JOURNAL FOR SCIENCE AND ENGINEERING (2023)

No Data Available