4.3 Article

Role of Texture and Acidity of SAPO-34 in Methanol to Olefins Conversion

Journal

PETROLEUM CHEMISTRY
Volume 60, Issue 4, Pages 471-478

Publisher

MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0965544120040167

Keywords

SAPO-34; silicoaluminophosphate; TEAOH; mesoporous materials; methanol to olefins; MTO

Funding

  1. Ministry of Science and Higher Education of the Russian Federation [AAAA-A17-117041710077-4]

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The effect of the amount of the molecular template tetraethylammonium hydroxide (TEAOH) in the precursor mixture on the physicochemical properties of SAPO-34 crystals has been examined, and the catalysts obtained have been tested in methanol conversion to lower olefins (MTO). The analysis of the textural and acidic properties of SAPO-34, which determine the high catalytic performances of catalysts in MTO, has been carried out. An effective catalyst possesses a high acidity and a developed surface with a large specific mesopore volume.

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