Journal
MATERIALS CHEMISTRY AND PHYSICS
Volume 245, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2019.122576
Keywords
ZIF-8; Nanocrystals; Controllable synthesis; Colloidal stability; Biomedicine
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Funding
- China Postdoctoral Science Foundation [2018M633524, 017M613127, 2019T120924]
- National Natural Science Foundation of China [81701769, 51861145307]
- Natural Science Basic Research Plan in Shaanxi Province of China [2018JM7031]
- Shaanxi Provincial Postdoctoral Science Foundation of China [2017BSHEDZZ96]
- Fundamental Research Funds for the Central Universities of China [xjj2017144]
- Research Support Program for Young Teachers in Xi'an Jiaotong University of China [YX1K092, YX1K075]
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ZIF-8, one kind of representative of metal-organic frameworks, has received much attention in various applications, due to its exceptional properties. Herein we reported the facially- controllable synthesis and post-modification of ZIF-8 nanocrystals with good colloidal stability. The research results demonstrated that the size of ZIF-8 nanocrystals synthesized in water using ZnI2 as zinc source could be controlled by adjusting the molar ratio of ligand (Hmim) to metal ion (Zn2+). Additionally, the zinc salts and solvents played an important role in controlling the size and morphology of ZIF-8 nanocrystals. Furthermore, the ZIF-8 nanocrystals modified with PAA showed good colloidal stability in PBS.
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