Article
Energy & Fuels
Peyman Koreh, Mostafa Lashkarbolooki, Majid Peyravi, Mohsen Jahanshahi
Summary: This study investigated the performance of different types of surfactants on the surface activity, emulsion size, and surface charge of five oil samples. The effects of various parameters on the interfacial tension of crude oil/surfactant solutions were comprehensively analyzed. The results showed that the properties of the surfactants, crude oil type, and ionic strength influenced the interfacial tension, surface charge, and microemulsion size, but not in a straightforward manner. Among the surfactants considered, the cationic surfactant showed the lowest dependency on the crude oil type, while the non-ionic surfactant showed the highest dependency. CTAB cationic surfactant exhibited the most efficient performance with a microemulsion size of 102 nm and surface charge near the isoelectric point.
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING
(2022)
Article
Energy & Fuels
Saba Mazinani, Hamed Farhadi, Mobeen Fatemi
Summary: Wettability alteration is a key mechanism for enhanced oil recovery during low salinity water flooding, but the role of oil type in this process is still not well understood. This study investigated the contact angle, interfacial tension, and zeta potentials for various rock/brine/crude oil systems. The results showed that the contact angle behavior varied with oil type and salinity, and a comprehensive model was successfully used to predict the contact angle. The study also revealed that interfacial tension and electric double-layer forces play important roles in controlling wettability behavior in different rock substrates.
Article
Energy & Fuels
Eugene N. Ngouangna, Mohd Zaidi Jaafar, M. N. A. M. Norddin, Augustine Agi, Abdul Rahim Risal, Stanley C. Mamah, Jeffrey O. Oseh
Summary: The novel concept of using nanoparticles to enhance oil recovery and reduce trapped oil in hydrocarbon reservoirs is being explored. This study investigates the use of hydroxyapatite nanoparticles for reducing interfacial tension and altering wettability under different salinity and temperature conditions. The results show that HAP nanoparticles are effective in improving these properties in both low and high salinity environments.
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING
(2022)
Article
Energy & Fuels
Jordy Sarmas-Farfan, Bryan X. Medina-Rodriguez, Vladimir Alvarado
Summary: The chemical composition of the aqueous phase is important in water-based enhanced-oil recovery processes. The ionic profile of the aqueous phase affects the snap-off response of a crude oil-brine system. Solutions with higher ionic strength form more rigid interfaces, while solutions with polyvalent anions in the low-salinity regime produce more viscoelastic interfaces at faster rates. There is an excellent correlation between the relative stability of the interfacial film predicted in liquid bridge tests and the ratio of interfacial tension and interfacial elastic modulus.
Article
Chemistry, Physical
Arastoo Abdi, Behnam Ranjbar, Yousef Kazemzadeh, Ali Niazi, Masoud Riazi
Summary: This study investigates the fluid-fluid interaction between low salinity water and microbial enhanced oil recovery (MEOR) and demonstrates that the injection of GeoBacillus stearothermophilus bacteria can reduce interfacial tension in both acidic and basic oil. The presence of different salts, especially CaCl2, affects the performance of biosurfactants. Furthermore, the combination of low salinity water and bacteria results in lower interfacial tension compared to using them individually.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2022)
Article
Chemistry, Multidisciplinary
Guangsheng Cao, Qingchao Cheng, Ying Liu, Ruixuan Bu, Ning Zhang, Peilun Wang
Summary: This paper focuses on the mechanism of surfactant production enhancement in the reservoir during the exploitation of tight reservoirs. It provides a detailed description of the factors affecting the stripping of crude oil by different surfactants, as well as the two spontaneous imbibition mechanisms of the surfactant. The results show that the particle size of emulsion, the interfacial tension between the surfactant and oil, and the wettability change all play important roles in the efficiency of oil stripping and the imbibition process. The study also utilizes X-ray computed tomography to determine the surfactant imbibition distance of different permeability types of cores. These findings contribute to a better understanding of enhanced oil recovery by surfactants and have significant implications for the exploitation of tight reservoirs.
Article
Chemistry, Multidisciplinary
M. Elmuzafar Ahmed, Abdullah S. Sultan, Mohamed Mahmoud, Kamaljit Singh, Muhammad Shahzad Kamal, Shirish Patil, Mazen Kanj
Summary: The study investigated the dynamic interfacial tension (IFT) between oil and VES solution using a porous glass micromodel, showing that IFT increases with shear rate and then reaches a plateau. The findings indicate that the IFT of high concentration VES can be reliably estimated during multiphase flow without the need for separate experiments and waiting for equilibrium to be reached.
Article
Engineering, Environmental
Charbel Abou Khalil, Nathalie Fortin, Roger C. Prince, Charles W. Greer, Kenneth Lee, Michel C. Boufadel
Summary: The salinity of upper seashores can surpass seawater due to evaporation, potentially inhibiting the biodegradation of oil spills. Under high salt concentrations, the activity of hydrocarbon-degrading bacteria was significantly inhibited, especially for alkanes. This study suggests that occasional irrigation of oiled supratidal zones could support remediation processes by promoting biodegradation.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Business, Finance
Zhuo Huang, Fang Liang, Tianyi Wang, Chao Li
Summary: This paper examines the time-varying conditional higher moments of daily returns on WTI crude oil futures using the GJR-GARCH model with Gram-Charlier expansion. The empirical results show significant time variations in conditional skewness and kurtosis, and suggest the advantage of models with dynamic higher moments in out-of-sample VaR forecasting.
FINANCE RESEARCH LETTERS
(2021)
Article
Chemistry, Multidisciplinary
Hang Dong, Runze Ma, Jian Zhao, Nan Guo, Zhihua Wang
Summary: The motion behaviors, rheological properties, and mechanical properties of a wax crystal mesoscale force chain network in gelation of waxy crude oil were studied experimentally and numerically. The relationship between the structure of the force chain network and the motion behaviors of the wax crystals and its rheological properties was analyzed. Results showed that as the temperature decreased, the motion velocity of wax crystals decreased, average coordination number increased, and viscosity of waxy crude oil increased. A complex and stable force chain network was observed during gelation.
Article
Energy & Fuels
Mohammad Fattahi Mehraban, Seyed Amir Farzaneh, Mehran Sohrabi
Summary: This study identified the functional compounds in crude oil that contribute to the low salinity water effect during water injection. Acidic compounds with aliphatic nature and asphaltene molecules were found to promote the formation of water-in-oil microdispersion at the interface, crucial for designing waterflood operations in oil reservoirs.
Article
Chemistry, Multidisciplinary
Tianhao Wu, Abbas Firoozabadi
Summary: The study indicates that a demulsifier surfactant enhances spontaneous emulsification near the oil-water interface, while a viscosifier polymer inhibits emulsification in the bulk oil phase but has a less pronounced effect on spontaneous emulsification near the interface.
Article
Energy & Fuels
Li Yisong, Raoof Gholami, Mehdi Safari, Ali Rahimi, Wee Siaw Khur
Summary: The study extracts and characterizes a natural surfactant with high thermal stability, demonstrating its synergistic effects with low salinity water, effectively reducing interfacial tension and altering sandstone surface wettability to enhance hydrocarbon production efficiency.
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING
(2022)
Article
Energy & Fuels
Ramtin Hamidian, Mostafa Lashkarbolooki
Summary: The study explored the surface-free energies on carbonate surfaces in contact with different aqueous solutions and crude oil, focusing on parameters such as interfacial tension (IFT), contact angle, works of cohesion (WC) and adhesion (WA), and spreading coefficient (SC). MgSO4 showed the greatest IFT reduction, MgCl2 and KCl had the shortest and longest adsorption times, respectively. Na2SO4 was able to change wettability from strongly oil-wet to strongly water-wet, while other salts could alter contact angle.
ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS
(2021)
Article
Energy & Fuels
Estrella Rogel, Kyle Hench, Francesca Cibotti, Eric Forbes, Les Jackowski
Summary: This study investigated the effect of blending crude oils on fouling propensity and found that the compatibility of crude oils significantly influences fouling. The results showed that higher fouling propensities were observed as the blends approached the threshold of incompatibility. The stability of the blends increased after fouling testing, indicating a decrease in the solubility of asphaltenes. These changes in the fluid and deposits' characteristics are associated with thermal degradation. However, further analysis is required to understand the underlying complex behavior.
Article
Engineering, Chemical
Mostafa Lashkarbolooki, Roohollah Parvizi, Shahab Ayatollahi, Ebrahim Ghaseminejad Raeeni
CHINESE JOURNAL OF CHEMICAL ENGINEERING
(2020)
Article
Chemistry, Physical
Ramtin Hamidian, Mostafa Lashkarbolooki, Hossein Amani
JOURNAL OF MOLECULAR LIQUIDS
(2020)
Article
Physics, Multidisciplinary
Mostafa Lashkarbolooki, Ali Zeinolabedini Hezave, Masoud Riazi, Shahab Ayatollahi
EUROPEAN PHYSICAL JOURNAL PLUS
(2020)
Article
Chemistry, Physical
Hamed Amouei Ojaki, Mostafa Lashkarbolooki, Kamyar Movagharnejad
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2020)
Article
Engineering, Chemical
Mahboubeh Pishnamazi, Samyar Zabihi, Sahar Jamshidian, Mostafa Lashkarbolooki, Fatemeh Borousan, Azam Marjani
Summary: In this study, the solubility of etoricoxib in supercritical CO2 was measured using a gravimetric method over a wide range of pressures and temperatures. Different solubility values were obtained depending on the applied pressure and temperature. It was found that pressure directly influenced the solubility of etoricoxib at all temperatures, while the effect of temperature depended on the crossover point in the solubility curve. Before reaching the crossover point, solubility decreased with increasing temperature, while after the crossover point, a direct relationship between solubility and temperature was observed.
CHEMICAL ENGINEERING & TECHNOLOGY
(2021)
Article
Energy & Fuels
Ramtin Hamidian, Mostafa Lashkarbolooki
Summary: The study explored the surface-free energies on carbonate surfaces in contact with different aqueous solutions and crude oil, focusing on parameters such as interfacial tension (IFT), contact angle, works of cohesion (WC) and adhesion (WA), and spreading coefficient (SC). MgSO4 showed the greatest IFT reduction, MgCl2 and KCl had the shortest and longest adsorption times, respectively. Na2SO4 was able to change wettability from strongly oil-wet to strongly water-wet, while other salts could alter contact angle.
ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS
(2021)
Article
Thermodynamics
Samyar Zabihi, Saber Hosseini, Mahboubeh Pishnamazi, Mostafa Lashkarbolooki, Fatemeh Borousan, Azam Marjani, Rasool Pelalak, Saeed Shirazian
Summary: The solubility of the active pharmaceutical ingredient, tenoxicam, was determined under supercritical conditions in CO2, showing a direct influence of pressure on solubility and a negative effect of temperature at low pressures. The Mendez-Santiago-Teja (MST) model had the best performance in correlating the solubility data, indicating a linear trend which can be utilized for data extrapolation.
JOURNAL OF CHEMICAL AND ENGINEERING DATA
(2021)
Article
Engineering, Chemical
Mehdi Razavifar, Aliya Mukhametdinova, Ehsan Nikooee, Alexander Burukhin, Amin Rezaei, Alexey Cheremisin, Masoud Riazi
Summary: This study evaluates the porous structure of a carbonate rock sample using various techniques, with μCT providing porosity data closer to gas porosimetry compared to MIP. NMR technique yielded lower porosity values but higher than the prediction by MIP.
TRANSPORT IN POROUS MEDIA
(2021)
Article
Chemistry, Physical
Mohammad Barari, Mostafa Lashkarbolooki, Reza Abedini
Summary: The investigation focused on new families of ionic liquid (IL) based surfactants for enhanced oil recovery. Imidazolium based ILs with different alkyl chain lengths were synthesized and their effects on interfacial tension, emulsification, and wettability alteration were examined. Results showed different responses to NaCl and Na2SO4 salts based on the alkyl chain length of the ILs.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Energy & Fuels
Karol Zapata, Daniel Lopez, Richard D. Zabala, Italo Bahamon, Masoud Riazi, Camilo A. Franco, Farid B. Cortes
Summary: This study aims to develop novel acid nanocapsules with tailored breaking reservoir temperatures for controlled release of acids to dissolve fine particles. Thermolabile nanocapsules were synthesized and characterized, and a nanofluid was formulated for acid dissolution tests. Results showed that the nanocapsules exhibited controlled release properties, increased acid lifetime, and reduced corrosion.
Article
Energy & Fuels
Vadim Fetisov, Adam M. M. Gonopolsky, Maria Yu. Zemenkova, Schipachev Andrey, Hadi Davardoost, Amir H. H. Mohammadi, Masoud Riazi
Summary: This study determines the costs of using CO2 capture technologies in the refining and petrochemical sectors. Depending on the process and method used, CO2 emissions costs of EUR 30 to 40 per ton of CO2 can be avoided. Advanced low-temperature CO2 capture technologies may not provide significant benefits compared to conventional technologies. An analysis estimated a reduction potential of about 0.5-1 Gt/yr for the oil and gas industries using short- and long-term technologies. The integration of CO2 capture into the oil production process helps reduce costs and emissions.
Article
Polymer Science
Aliasghar Parsaie, Masoud Riazi, Abdolreza Kazemi Abadshapoori, Mohammad Mohammadi-Khanaposhtani, Yousef Tamsilian
Summary: This study focused on the effects of sponge density and magnesium stearate loadings on the separation performance of superhydrophobic magnesium stearate coated-polyurethane. The results showed that the surface of the sponge became rougher after being coated with magnesium stearate, while the sponge density had no significant impact on the water contact angle and oil absorption rate. The absorption capacity of the modified sponges for various oils and solvents was also tested and showed promising results.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Multidisciplinary Sciences
Vadim Fetisov, Yury V. Ilyushin, Gennadii G. Vasiliev, Igor A. Leonovich, Johannes Mueller, Masoud Riazi, Amir H. Mohammadi
Summary: This article presents the results of a numerical experiment and analysis of temperature fields in a gas pipeline using cooling elements. The analysis revealed several principles for temperature field formation, highlighting the importance of maintaining a relative temperature for gas pumping. The experiment aimed to determine the optimal distance for installing cooling elements to achieve optimal gas pumping, considering the synthesis of control laws and assessment of control error. The developed technique allows for the evaluation of the regulation error of the control system.
SCIENTIFIC REPORTS
(2023)
Article
Energy & Fuels
Ali Khalilnezhad, Hosein Rezvani, Alireza Talebi, Parastoo Ganji, Tina Puntervold, Masoud Riazi
Summary: The purpose of this research is to investigate the use of aluminananoparticles in low-salinity brine for enhanced oil recovery in carbonate oil reservoirs. Analyses including oil/water interfacial tension, zeta potential, and rock wettability were performed to select the optimized dispersions for spontaneous imbibition tests. The results showed that the addition of alumina nanoparticles in low-salinity brine can significantly reduce the oil/water interfacial tension, improve the wettability of the rock, and enhance oil production.
Review
Energy & Fuels
Amin Sharifi, Rohaldin Miri, Masoud Riazi
Summary: The surfactant EOR is considered a promising approach for enhancing oil recovery due to the changing energy supply and demand and the non-renewable nature of world oil reservoirs. However, surfactants face challenges such as high adsorption, low stability, and poor performance in harsh conditions like high temperature, high salinity, and dense carbonate rocks. There is currently no established procedure or framework for systematically selecting the best surfactant for EOR in dense carbonates.
Article
Engineering, Chemical
Andrea Coletto, Pietro Poesio
Summary: Experiments and simulations were conducted to study the air volume fraction and hold-up in a bubble channel reactor. A new signal processing method was proposed to avoid the loss of bubble residence time. The results were in agreement with previous studies and a bubble-scale model was developed to explain the relationship between hold-up and air superficial velocity.
CHEMICAL ENGINEERING RESEARCH & DESIGN
(2024)