Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 142, Issue 13, Pages 5980-5984Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.0c01592
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- European Research Council [ERC AdG 692775]
- Israel Planning and Budgeting Committee (PBC)
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Oxidation by water with H-2 liberation is highly desirable, as it can serve as an environmentally friendly way for the oxidation of organic compounds. Herein, we report the oxidation of alkenes with water as the oxidant by using a catalyst combination of a dearomatized acridine-based PNP-Ru complex and indium(III) triflate. Compared to traditional Wacker-type oxidation, this transformation avoids the use of added chemical oxidants and liberates hydrogen gas as the only byproduct.
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