Article
Chemistry, Inorganic & Nuclear
Qing-Lin Cao, Ruo-Tong Wang, Jing-Yu Duan, Gui-Ying Dong
Summary: Two stable Cd(II) coordination polymers were successfully constructed under hydrothermal conditions, showing high sensitivity and selectivity for the detection of Fe3+ and TC. These materials are promising dual-functional fluorescent sensors based on MOFs, with excellent thermal and chemical stability.
JOURNAL OF SOLID STATE CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Xu-Peng Zhang, Yan-Qin Zhao, Lianshe Fu, Guang-Hua Cui
Summary: A novel ternary coordination polymer with an unusual 3D network structure was synthesized and characterized. The polymer showed excellent thermal and pH stability in the pH range of 3-12. It also exhibited promising potential as a probe for detecting tetracycline and Cr2O72- with good recyclability and low detection limits. Furthermore, the possible luminescence mechanism was analyzed in detail.
INORGANIC CHEMISTRY COMMUNICATIONS
(2023)
Article
Crystallography
Huarui Wang, Jianhua Qin
Summary: Three Cd(II) coordination complexes with unique structures and topologies have been successfully synthesized and characterized. The structural and dimensional diversity of these complexes highlights the important roles of the flexible ligand and aromatic polycarboxylates in constructing the frameworks. Furthermore, the different photoluminescence behaviors of the complexes in the solid state have been studied.
Article
Chemistry, Inorganic & Nuclear
Ya Liu, Ruo-Tong Wang, Lianshe Fu, Gui-Ying Dong
Summary: Detecting antibiotics and heavy metal ions in water system is crucial for environmental protection. Two new ternary coordination polymers (CPs) were prepared and found to exhibit excellent properties as dual-functional fluorescent sensors with high sensitivity, selectivity, and low detection limit for different substances.
JOURNAL OF SOLID STATE CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Zong-Ying Li, Hong-Xia Zhang, Tian-Sheng He, Hong-Xin Jiang, Xiao-Wei Liu, Li-Na Zhu, Xiao-Zeng Li, De-Ming Kong
Summary: A water-stable Cd (II) luminescent coordination polymer (1) was obtained through assembly of a new ligand with CdCl2. This polymer can serve as a luminescent probe for the organoarsenic compound Roxarsine (ROX) with high selectivity and sensitivity. It can also detect some inorganic harmful ions with excellent versatility.
INORGANICA CHIMICA ACTA
(2023)
Article
Chemistry, Multidisciplinary
Ningning Gao, Yunyun Zhang, Jing Huang, Yan Wang
Summary: In this study, a high-performance fluorescent material, [Cd(2-bpmh)(BDC)H2O](n) (2-bpmh=1,4-bis(2-pyridyl)-2,3-diaza-1,3-butadiene, H2BDC=terephthalic acid), was successfully synthesized for the detection of toxic pollutants in water through solvothermal reaction. Single crystal X-ray analysis revealed that the material forms a one-dimensional chain structure and further assembles into a three-dimensional structure through hydrogen bonding interactions. The luminescence sensing research demonstrated that the material not only exhibited excellent luminescence quenching efficiency, but also selectively recognized Cr2O72-, CrO42-, and Fe3+ ions in water.
Article
Chemistry, Multidisciplinary
Liangjuan Liu, Yungen Ran, Jianlong Du, Zhichao Wang, Mei Liu, Yajuan Mu
Summary: A luminescent Cd(ii) coordination polymer, CP-1, was constructed through the mixed-ligand method and exhibited high sensing towards Zn2+, Fe3+ and Cr2O72- ions. CP-1 displayed fluorescence enhancement for Zn2+ ions and fluorescence quenching for Fe3+ and Cr2O72- ions, making it a rare multi-responsive sensor material for efficient detection.
Article
Chemistry, Physical
Kun Lyu, Ying-Li Wei, Yue-Hua Li, Guang-Hua Cui
Summary: Two nickel(II) coordination polymers were synthesized and characterized, showing remarkable photocatalytic activities for degradation of methylene blue and serving as dual-responsive luminescent chemosensors for selective detection of benzaldehyde and Fe3+ in aqueous systems.
JOURNAL OF MOLECULAR STRUCTURE
(2021)
Article
Biochemistry & Molecular Biology
Anirban Karmakar, Anup Paul, Maria Fatima C. da Silva, Armando J. L. Pombeiro
Summary: Two new 1D Cd(II) coordination polymers were synthesized and used as catalysts for the solvent-free Strecker-type cyanation reaction of different acetals. One of the catalysts showed higher activity, and both catalysts were found to be recyclable.
Article
Chemistry, Inorganic & Nuclear
Ce Liu, Guang-Hua Cui
Summary: A 1D zigzag chain Cd(II) coordination polymer (CP), [Cd(L)2(tcpa)]n (1), has been synthesized and characterized, which shows promising fluorescence properties for detecting chlortetracycline with a low detection limit of 2.3 x 10-8 mol/L. The CP can be reused five times and the fluorescent sensing mechanism has been discussed.
INORGANIC CHEMISTRY COMMUNICATIONS
(2023)
Article
Polymer Science
Venkatesan Lakshmanan, Yi-Ting Lai, Xiang-Kai Yang, Manivannan Govindaraj, Chia-Her Lin, Jhy-Der Chen
Summary: The reaction of divalent metal salts with ligands in various solvents resulted in the formation of structurally characterized complexes with interpenetrating frameworks. These complexes exhibited high porosity, CO2 adsorption capabilities, and stability in aqueous environments. Complexes 1 and 2 showed high selectivity towards mesitylene molecules and Fe3+ ions, with low detection limits and good reusability for up to five cycles.
Article
Chemistry, Inorganic & Nuclear
Shan-Shan He, Ting Jiang, Wei-Wei Fu, Hong Chen, Shuang Li, Pan Zhou, Jing-Run Shen, Yang Liu, Man-Sheng Chen
Summary: In this study, six novel coordination polymers were synthesized based on a rigid tridentate ligand. The structures of the polymers were characterized using various techniques. The results indicate that the structural topology of the coordination polymers is modulated by the versatility of the ligands.
Article
Chemistry, Multidisciplinary
Xiao-Ling He, Fu-Hui Huang, Chun-Ming Zhang, Zhen Dong, Bin-Quan Wang
Summary: Two new Zn(II)/Cd(II) coordination polymers were synthesized and evaluated for their therapeutic and protective activities against laryngeal carcinoma. The compounds showed inhibitory activity against the viability of laryngeal carcinoma cells and the underlying mechanism was explored.
Article
Chemistry, Multidisciplinary
Daniel Ejarque, Teresa Calvet, Merce Font-Bardia, Josefina Pons
Summary: This study systematically investigated the synthesis of fluorescent coordination complexes using Cd(II) ion and various pyridine ligands. The results showed that the fluorescence enhancement effect and the electronegativity of Cd(II) ion helped to prevent fluorescence quenching.
Article
Chemistry, Applied
Zhao-Hao Li, Li-Ping Xue, Shuo Li, Ping-Fang Zang
Summary: Two new photochromic coordination polymers have been synthesized through the regulation of metal-ligand ratios.
Article
Chemistry, Inorganic & Nuclear
Caleb J. Bennett, Helen E. A. Brand, Alexander K. L. Yuen, Maria K. Nicholas, Brendan J. Kennedy
Summary: The temperature dependence of the crystal structure of Potassium Hexaiodoplatinate(IV) between 80 and 500 K is studied. Different crystal structures are observed at different temperatures, including monoclinic, tetragonal, and cubic structures. Accurate determination of the structures of K2PtI6 is important for further theoretical and practical research.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Zhuo Zeng, Jiangfu Zheng, Xiaoming Li, Changzheng Fan, Rongying Zeng, Wenqing Tang
Summary: An efficient method for phosphate removal from wastewater is urgently needed due to the environmental issue caused by excessive phosphorus. In this study, calcium aluminum layered double hydroxides (CaAl-LDHs) and six amino acid intercalated calcium aluminum layered double hydroxides (CaAl-amino acid-LDHs) were prepared and compared for their phosphate adsorption performance. L-Aspartic acid intercalated calcium aluminum layered double hydroxides (CaAl-Asp-LDHs) exhibited the highest phosphate adsorption capacity and faster removal rate compared to CaAl-LDHs. The phosphate adsorption mechanism on CaAl-Asp-LDHs involved electrostatic attraction, hydrogen bonds, complexation, and ion exchange. This environmentally friendly material shows promising potential for efficient phosphate removal from aquatic environments.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Rouzbeh Aghaei Hakkak, Thomas Schleid
Summary: The novel guanidinium hydro-closo-borates with [BnHn]2- (n = 10 and 12) anions were successfully synthesized via direct reaction. The crystal structures exhibit hydrogen bonding interactions and have the potential to facilitate H2 generation.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Liqiang Ma, Pengpeng Wei, Jingfang Li, Liye Liang, Guangming Li
Summary: A novel catalyst, H4PVMo2W9O40@rht-MOF-1, was developed using a one-pot hydrothermal method. It exhibited high efficiency and reusability in esterification reactions.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Liudmila A. Gorelova, Valentiva A. Yukhno, Maria G. Krzhizhanovskaya, Oleg S. Vereshchagin
Summary: Two new Ga-Ge disordered feldspar-related compounds were successfully synthesized using melt crystallization methods. Their stability and thermal expansion properties were studied under high-temperature conditions. The results showed that both compounds are stable within the studied temperature range and exhibit anisotropic thermal expansion.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Seifeddine Bdey, Nesrine Boussadoune, Francois Allard, Jacques Huot, Gabriel Antonius, Noura Fakhar Bourguiba, Pedro Nunez
Summary: The structure of a novel arsenate compound Na3Al3(AsO4)4 has been determined using X-ray diffraction. The crystal exhibits a monoclinic space group with suitable pathways for Na+ ion migration. The accuracy of the structural model was confirmed using various validation tools and density functional theory calculations.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Amit Kumar Atri, Ujwal Manhas, Sumit Singh, Irfan Qadir, Shikha Sharma, Preteek Sharma, Devinder Singh
Summary: This study synthesizes new oxygen deficient triple layered Ruddlesden-Popper (RP) phases via sol-gel method and investigates the effects of Cr3+ doping on their structural, optical, magnetic, and photocatalytic properties. The experimental results demonstrate that Cr3+ doping alters the interactions and leads to excellent photocatalytic performance in some phases.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Dat Le Thanh, Amandine Guiet, Emmanuelle Suard, Romain Berthelot
Summary: In this study, FeNb11O29 powder samples were prepared using a microwave-assisted solid-state synthesis method for the first time. The samples obtained rapidly from submicrometric oxide precursors showed enhanced cycling performance, possibly due to the easier ionic diffusion occurring in the smaller particles.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Raimund Ziegler, Felix R. S. Purtscher, Thomas S. Hofer, Gunter Heymann, Hubert Huppertz
Summary: We have successfully synthesized a new tellurium borate crystal under high-pressure and high-temperature conditions. The crystal structure and theoretical calculations have been thoroughly discussed.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Subhendu Jana, Eric A. Gabilondo, Paul A. Maggard
Summary: This study reports the synthesis and characterization of two previously unknown multinary selenides, Ba8Hf2Se11(Se-2) and Ba9Hf3Se14(Se-2), which display unique structures and optoelectronic properties competitive with existing perovskite-type chalcogenides.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Fei Ruan, Chonggui Lei, Fenglong Zhang, Jinxiao Bao, Fen Zhou, Min Xie, Pengfei Xu, Jianquan Gao
Summary: Studying the diffusion properties of hydrogen is important for designing new proton conductors. In the past, the chemical diffusion coefficient of hydrogen in proton conductors was usually obtained through a manual calculation method, resulting in difficulty in controlling the calculation accuracy. To address this issue, a mathematical algorithm and C language computer program were developed to calculate the chemical diffusion coefficient based on Fick's second law and Romberg numerical integral. The algorithm showed high precision and powerful computing function, and has the potential to replace the manual calculation method in calculating the chemical diffusion coefficient for hydrogen in proton conductors.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Deepika Shanubhogue, Suraj Mangavati, Ashok Rao, Ru-Ting Tsao, Yung-Kang Kuo
Summary: In this study, the effect of Y doping at the Sn-site on the structural, electrical, and low-temperature thermoelectric properties of the Cu2SnSe3 system is investigated. Y-doped compounds Cu2Sn1-xYxSe3 show reduced electrical resistivity, enhanced power factor, and decreased thermal conductivity, resulting in higher ZT values.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Wei Hong, Min Qing, Xun He, Lei Wang, Yu Pu, Qiyu Li, Zhimin He, Qin Dong, Rong Li, Xinglong Gou
Summary: This study developed a simple method to prepare SnS2 nanosheets and assembled them with MXene to form SnS2/MXene. The composite material exhibited abundant active sites, superior electron/ion transfer kinetics, and a unique 2D interlayer structure, resulting in high specific capacity, outstanding rate capability, and excellent cycling stability, with potential applications in LIBs.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Heng-Yu Ruan, Xue-Qian Wu, Tian-Yu Zhang, Yi Yuan, Le Wang, Ya-Pan Wu, Qing-Wen Han, Ruan Chi, Dong-Sheng Li
Summary: Two isostructural metalorganic frameworks (MOFs), CTGU-36-Co and CTGU-36-Ni, were synthesized, and CTGU-36-Ni demonstrated high activity as a molecular electrocatalyst for the methanol oxidation reaction.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Rachid Fakhreddine, Ali Ouasri, Abderrahim Aatiq
Summary: This paper reports the synthesis, structure, and spectroscopic studies of three novel metal orthophosphate salts. The structures of these compounds were refined using X-ray powder diffraction data. The infrared and Raman analysis revealed their symmetries and the UV-visible investigation determined their optical properties.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)