Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 50, Pages 7846-7849Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc03932d
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Funding
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0011979]
- National Science Foundation [CHE-1465068]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1465068] Funding Source: National Science Foundation
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Two water-soluble anionic cyclometalated Ir(III) complexes, Ir(ppy)(2)BPS [1] and Ir(F-mppy)(2)BPS [2] have been synthesized and display clear evidence of self-assembly in water. Concentration-induced aggregation enhances the excited-state properties of both complexes, blue-shifting the photoluminescence emission energies as well as increasing the corresponding excited state lifetimes and quantum yields up to a factor of 5.
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