Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 3, Pages 564-566Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc07793a
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Funding
- DOE EERE [DE-EE0002978]
- Target Project of WPI-AIMR, Tohoku University [4]
- Collaborative Research Centre on Energy Materials, Tohoku University
- JSPS KAKENHI [25220911]
- Advanced Low Carbon Technology Research and Development Program (ALCA) from the Japan Science and Technology Agency (JST)
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A new crystalline phase derived from a 90LiBH(4):10P(2)S(5) mixture displays high lithium-ionic conductivity of log(sigma/S cm(-1)) = -3.0 at 300 K. It is stable up to 473 K and has both a wide potential window of 0-5 V and favorable mechanical properties for battery assembly. Its incorporation into a bulk-type all-solid-state TiS2/InLi battery enabled repeated battery operation at 300 K.
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