4.7 Article

Stepwise fabrication of donor/acceptor thin films with a charge-transfer molecular wire motif

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 97, Pages 13983-13986

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc08310b

Keywords

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology of Japan [16H02269, 15K13652, 2601, 15H00983]
  2. E-IMR project
  3. Asahi Glass Foundation
  4. Mitsubishi Foundation
  5. Iketani Science and Technology Foundation
  6. Support Program for Interdisciplinary Research
  7. inter-university cooperative research program of the Cooperative Research and Development Center for Advanced Materials, Institute for Materials Research, Tohoku University [15G0416]
  8. Grants-in-Aid for Scientific Research [15K13652, 26410064, 15H03791, 26102007, 15H00983, 16H02269] Funding Source: KAKEN

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Novel thin films composed of a donor (D)/acceptor (A) charge-transfer chain compound were fabricated by a layer-by-layer technique using complexation of a paddlewheel-type diruthenium(II, II) complex with an N, N'-dicyanoquinonediimine derivative on an ITO substrate with a pyridine-substituted phosphonate anchor. The stepwise growth of an electron-transfer D+A(-)-chain thin film was confirmed.

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