Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 79, Pages 11760-11763Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc05777b
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Funding
- European Marie Curie Actions under ECOSTORE grant [607040]
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We report for the first time the formation of a metal amide-hydride solid solution. The dissolution of KH into KNH2 leads to an anionic substitution, which decreases the interaction among NH2- ions. The rotational properties of the high temperature polymorphs of KNH2 are thereby retained down to room temperature.
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