4.7 Article

A top-down strategy to synthesize wurtzite Cu2ZnSnS4 nanocrystals by green chemistry

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 63, Pages 9821-9824

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc04197c

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Funding

  1. National Natural Science Foundation of China (NSFC) [21301044]
  2. Fundamental Research Funds for the Central Universities [2014HGCH0013, JZ2014HGCH0164, JZ2016HGTB0725]
  3. Natural Science Foundation of Anhui Province of China [1408085MB31]

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Green synthesis of metastable wurtzite Cu2ZnSnS4 nanocrystals through a top-down synthetic strategy is presented. Formation mechanisms associated with Kirkendall and etching effects are illustrated in detail. The nanocrystals exhibit remarkable photoluminescence properties at room temperature.

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