Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 53, Pages 8305-8308Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc02962k
Keywords
-
Categories
Funding
- NSF [CHE-1213880, CHE-1465075]
- NSF ND-EPSCoR [EPS-0814442]
- NDSU
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1465075, 1213880] Funding Source: National Science Foundation
Ask authors/readers for more resources
Atropisomeric maleimides were synthesized and subjected to atropselective [5+2]-photocycloaddition under direct irradiation to yield azepinone products with high enantio- (ee > 98%) and diastereoselectivity (dr > 98%). While the ee was dictated by the axial chirality, the dr was influenced by the substituent on the maleimide ring. Interestingly, by tuning the electronics of the substituent, the dr of the product can be reversed.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available