Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 10, Pages 2145-2148Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc09146b
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Funding
- National Natural Sciences Foundation of China [21172125]
- Specialized Research Fund for the Doctoral Program of Higher Education [20130031110013]
- MOE Innovation Team [IRT13022]
- 111'' Project of Ministry of Education of China [B06005]
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A novel Cu(II)-catalyzed aerobic oxidative esterification of simple ketones for the synthesis of esters has been developed with wide functional group tolerance. This process is assumed to go through a tandem sequence consisting of alpha-oxygenation/esterification/ nucleophilic addition/C-C bond cleavage and carbon dioxide is released as the only byproduct.
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