Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 69, Pages 10574-10577Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc05095f
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Funding
- NIH-NIDCR [U01 DE023774]
- NIH-COBRE [1P30 GM110758]
- Office of Integrative Activities
- Office Of The Director [1301765] Funding Source: National Science Foundation
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A visible-light (470 nm wavelength) sensitive Type II photoinitiator system is developed for bulk Cu(I)-catalyzed azide-alkyne cycloaddition (CuAAC) reactions in crosslinked networks. The accelerated photopolymerization eliminates UV-mediated azide decomposition allowing for the formation of defect-free glassy networks which exhibit a narrow glass transition temperature.
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