Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 59, Pages 9283-9286Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc04735a
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Funding
- NIH [NIGMS R01-GM073072]
- Northwestern University
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM073072] Funding Source: NIH RePORTER
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A convergent, transition-metal-free synthesis of 2-aryl-azaindoles has been developed. The interception of a reactive aza-ortho-azaquinone methide intermediate by an acyl anion equivalent generated through carbene catalysis provides high yields, a wide substrate scope, and the synthesis of previously inaccessible azaindoles.
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