Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 42, Pages 6903-6906Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc02384c
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Funding
- Natural Science Foundation of China [21572149]
- Young National Natural Science Foundation of China [21402133]
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The first bidentate directing group assisted highly selective meta arylation of beta-arylethylamine derivatives via palladium/norbornene catalysis is reported, and the range of aryl iodides for the oxalyl amide assisted meta-selective arylation reactions is broadest yet reported. This meta arylation also proceeds well with thiophene derivatives, giving the corresponding products in satisfactory yields. And three-step functionalization of arylethyloxalamide with three different functional groups is successfully performed.
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