Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 55, Pages 8514-8517Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc03471c
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Funding
- Office of Basic Energy Sciences, U.S. Department of Energy [DE-FG02-01ER15186]
- Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Science, ICT & Future Planning [2015R1C1A1A02037578]
- Robert A. Welch Foundation [F-1738]
- National Research Foundation of Korea [2015R1C1A1A02037578] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- U.S. Department of Energy (DOE) [DE-FG02-01ER15186] Funding Source: U.S. Department of Energy (DOE)
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A 3-dimensional networked molecular cage, NMC-1, has been synthesized. This macrocycle-based framework was prepared from a solvothermal reaction involving a flexible organic building block, calix[4] pyrrole dibenzoic acid (H2L), and Pr(NO3)(3)center dot 6H(2)O. A unique feature of NMC-1 is that it retains free calix[4]pyrrole molecules in the framework pores. Treatment with a fluoride anion source serves to destroy the network and allows release of the organic guest. The net result is a 'molecular ship' in a 'breakable bottle'.
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