4.7 Article

Pd-on-Si catalysts prepared via galvanic displacement for the selective hydrogenation of para-chloronitrobenzene

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 14, Pages 3026-3029

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc07474f

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Funding

  1. National Science foundation of China [21073013]

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The direct redox reaction (galvanic displacement) between Pd2+ and substrate Si was used to deposit Pd on Si, and the Pd-Si catalysts enabled a chemoselective hydrogenation of para-chloronitrobenzene with the selectivity for para-chloroaniline higher than 99.9% at complete conversion of para-chloronitrobenzene.

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