Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 15, Pages 3187-3190Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc09688j
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Funding
- National Science Council
- Ministry of Education, Taiwan
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Gold-catalyzed [2+2+2]-cycloadditions of two discrete ynamides and one nitrile afford 2,4-diaminopyridine derivatives that are not readily prepared from typical low-valent-metal catalysts. Our mechanistic analysis reveals that the reaction chemoselectivity is controlled by the types of sulfonamides of ynamides.
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