Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 39, Pages 6549-6552Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc02063a
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Funding
- National Research Foundation of Korea (NRF) - Korea government (MSIP) [2015R1A2A2A01008130]
- National Research Foundation of Korea [2015R1A2A2A01008130] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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The esters of 1,2-azido alcohols were transformed into alpha-amido ketones without external oxidants through the Ru-catalyzed formation of N-H imines with the liberation of N-2 followed by intramolecular migration of the acyl moiety. A wide range of alpha-amido ketones were obtained, and one-pot transformation into the corresponding oxazoles (or a thiazole) was demonstrated.
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