4.6 Article

Batch-Fabricated WSe2-on-Sapphire Field-Effect Transistors Grown by Chemical Vapor Deposition

Journal

IEEE TRANSACTIONS ON ELECTRON DEVICES
Volume 67, Issue 4, Pages 1839-1844

Publisher

IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC
DOI: 10.1109/TED.2020.2974450

Keywords

Chemical vapor deposition (CVD); field-effect transistor (FET); polyethylene oxide; cesium perchlorate (PEO: CsClO4); tungsten diselenide; WSe2

Funding

  1. Center for Low Energy Systems Technology (LEAST)
  2. Microelectronics Advanced Research Corporation (MARCO)
  3. Defense Advanced Research Projects Agency (DARPA)

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Stepper-based batch fabrication of top-gated field-effect transistors (FETs) is demonstrated on few-layer WSe2-on-sapphire grown by chemical vapor deposition. This article reports the electrical characterization of 94 transistors with three different transistor structures. ON-/ OFF-current ratios exceeding 10(5) at room temperature with noise-floor-limited gate current and contact-limited ON-current density of 15 nA/ $\mu \text{m}$ was achieved for FETs using a structure in which the gate overlaps the source and drain contacts. Two transistors with open channel access regions are used to allow ion doping through polyethylene oxide: cesium perchlorate (PEO: CsClO4) to induce electron and hole conductivity and allow characterization of the intrinsic FET characteristics. In these geometries, the ON-current increased by four orders of magnitude with ON-/ OFF-current ratio greater than 10(6) at ${V}_{\text {DS}} = -0.05$ V, compared to gate overlapped FETs. An analytic 2-D FET model was used to model the full current-voltage characteristics. This allowed the field-effect mobility to be extracted revealing the gate and drain field dependence for the first time. The fit of the measured characteristics from subthreshold to saturation is made with only four fitting parameters, revealing a field-dependent electron mobility ranging from 1 to 2.6 cm(2)/Vs.

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