Article
Chemistry, Physical
Min Zhou, Li Cheng, Zhifeng Chen, Liru Chen, Yongjun Ma
Summary: In this study, CdSe QDs@MoS2 nanocomposites were prepared and their photocatalytic performance in degrading ceftriaxone sodium under visible light irradiation was investigated. The results showed that the MCQ-35 catalyst could significantly enhance the degradation rate and TOC removal ratio of ceftriaxone sodium. Furthermore, active species capture experiments confirmed the generation of specific active species and their contributions in the photocatalytic process.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Inorganic & Nuclear
Di Liu, Liping Chen, Wenbin Chen, Mengtao Qin, Siqi Wei
Summary: Well-dispersed Pt quantum dots were successfully deposited onto a PDI supramolecular nanorods surface, forming Pt QDs/PDI composites with excellent photocatalytic properties in the degradation of phenol. The enhanced photocatalytic performance can be attributed to the efficient trapping and transporting of electrons by Pt QDs, which also act as active sites during the photocatalytic reaction, leading to high stability and utilization in water environmental purification.
DALTON TRANSACTIONS
(2021)
Article
Engineering, Electrical & Electronic
Zheng Zhang, Changsheng Feng, Caiyun Jiang, Yuping Wang
Summary: This study successfully prepared Ag@AgCl/TiO2 nanotubes and characterized their crystal structure and properties through various experiments. The results showed that 40%Ag@AgCl/TNTs has a higher removal rate of o-NBA under visible light, indicating its superior photocatalytic performance.
JOURNAL OF ELECTRONIC MATERIALS
(2021)
Article
Materials Science, Multidisciplinary
Zheng Zhang, Yuyang Kang, Li-Chang Yin, Ping Niu, Chao Zhen, Runze Chen, Xiangdong Kang, Fayu Wu, Gang Liu
Summary: Constructing type II heterostructures by utilizing porous g-C3N4 as substrate for CdSe quantum dots effectively enhances the photocatalytic hydrogen production activity, offering a feasible strategy for boosting visible light driven water splitting performance.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2021)
Article
Engineering, Environmental
Gongduan Fan, Rongsheng Ning, Zhongsen Yan, Jing Luo, Banghao Du, Jiajun Zhan, Lingshan Liu, Jin Zhang
Summary: Antibiotic contamination is a growing concern, leading to increased scrutiny on solutions like the AgAgCl/WO3/g-C3N4 (AWC) nanocomposites for trimethoprim degradation. Experimental results showed high efficiency with 99.9% of TMP degraded within 60 min using AWC at 0.5 g/L concentration. The proposed double photoelectron-transfer mechanism and identification of degradation pathways through theoretical calculations and experiments further support AWC as a promising photocatalyst for removing TMP from aquatic environments.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Engineering, Environmental
Gongduan Fan, Zhong Chen, Zhongsen Yan, Banghao Du, Heliang Pang, Dingsheng Tang, Jing Luo, Jiuyang Lin
Summary: The novel plasmonic Ag/AgCl@LaFeO3 (ALFO) photocatalyst showed enhanced photocatalytic activity in controlling harmful algal blooms (HABs) under visible light. ALFO-20% demonstrated higher light absorption capacity and lower electron-hole recombined rate compared to pure LaFeO3 and Ag/AgCl. Furthermore, ALFO-20% efficiently removed chlorophyll a from HABs, altered algae cell membrane permeability and morphology, disrupted photosynthesis and antioxidant systems, reducing secondary pollution and preventing HAB recurrence.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Engineering, Environmental
Xin Yu, Jielin Huang, Jingjing Zhao, Shuaifei Liu, Dandan Xiang, Yanting Tang, Juan Li, Quanhui Guo, Xinqi Ma, Junwei Zhao
Summary: Efficient visible light photocatalytic elimination of pharmaceutical factory wastewater was achieved by introducing hybrid Ag/AgCl nanoparticles into Ti3+ self-doped TiO2 mesocrystals. The Ag/AgCl@Ti3+-TiO2 mesocrystals showed superior performance in degrading tetracycline under visible light, mainly attributed to the continuous attacks of photo-generated holes and radicals on tetracycline molecules.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Physical
Jiafei Wu, Xiuxuan Fang, Haotian Dong, Leshui Lian, Na Ma, Wei Dai
Summary: The rod-like Ag/AgCl/BiOCl materials were successfully fabricated by calcination of the self-sacrificial template of silver/bismuth bimetallic-organic frameworks in order to achieve more desirable photocatalytic activity towards tetracycline. The obtained Ag/AgCl/BiOCl catalyst exhibited enhanced light absorption ability in visible light region and superior photocatalytic activity compared to BiOCl, with remarkable stability during photocatalytic reactions. This work opens up new perspectives for advanced uniform-sized photocatalytic catalyst using bimetallic MOFs as self-sacrificial templates.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Multidisciplinary
Panbing Hu, Yanmei Xin, Congfei Yao, Yuqing Miao
Summary: In2S3/BiOI composites synthesized at room temperature significantly enhance the photocatalytic degradation of tetracycline hydrochloride under visible light irradiation. The heterojunctions of the composites enhance the separation ability of photogenerated carriers, with the 7-In2S3/BiOI composite achieving the best performance. The photocatalytic mechanism of In2S3/BiOI composites involving superoxide radicals and holes is proposed based on photo-electrochemical characterization and free radical tests.
Article
Engineering, Environmental
Xinyue Xu, Yanghang Su, Yuanpeng Dong, Xiao Luo, Shihao Wang, Wenyu Zhou, Rong Li, Kevin Peter Homewood, Xiaohong Xia, Yun Gao, Xuxing Chen
Summary: The study conducted density functional theory calculations to predict the formation of an S-scheme heterojunction in the CdS quantum dots/Bi2MoO6 monolayer system. The novel S-scheme system showed high-efficiency photocatalytic degradation rate towards C2H4 under visible light, providing strong evidence for the S-scheme charge transfer path through in-situ XPS, PL, TRPL and EPR.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Chemistry, Physical
Guanghui Zhang, Jingchao Wang, Haoran Zhang, Tianyong Zhang, Shuang Jiang, Bin Li, Huoli Zhang, Jianliang Cao
Summary: This study successfully prepared hierarchical tubular micro-nano structured AgCl/Ag/TiO2 hybrids, which exhibited good catalytic activity and stability by controlling the dosage of AgNO3 and mass ratio of the components.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Environmental Sciences
Subramanian Keerthana, Balasubramanian Jansi Rani, Rathinam Yuvakkumar, Ganesan Ravi, Balasubramaniam Saravanakumar, Mehboobali Pannipara, Abdullah G. Al-Sehemi, Dhayalan Velauthapillai
Summary: Waste water remediation is a global research hotspot for reducing water scarcity. NiMoO4 nanorods showed better efficiency in degrading methylene blue dye under visible light irradiation.
ENVIRONMENTAL RESEARCH
(2021)
Article
Materials Science, Ceramics
Towseef Ahmad, Mohd Zubair Ansari
Summary: Recent developments in the field of nanomaterials have shown the importance of using doping techniques to achieve multifunctionality in materials. In this study, Sb-doped SnO2 nanoparticles were successfully prepared using a sol-gel approach. Various characterization techniques were used to investigate the effect of Sb doping on the structural and optical properties of SnO2, as well as the photocatalytic capabilities of the prepared nanoparticles. The results showed that Sb doping influenced the crystallite size and band gap energy of SnO2, leading to enhanced absorption in the visible light range and improved photocatalytic activity.
CERAMICS INTERNATIONAL
(2023)
Article
Materials Science, Multidisciplinary
Akshay Gaur, Moolchand Sharma, Vishal Singh Chauhan, Rahul Vaish
Summary: Bismuth ferrite (BiFeO3) is a potential material for removing industrial dyes from water through the photocatalysis process. Glass-ceramic with a composition of Bi2O3-Fe2O3-BaO-B2O3 was fabricated to utilize the BiFeO3 phase. The sample heat-treated at 480 degrees C for 2 hours showed the maximum degradation of Methylene Blue (MB) dye of -69% in 300 minutes. The stability of the fabricated samples was checked using XRD pattern and SEM micrographs, and MB dye degradation was calculated using RGB values obtained from a smartphone app.
MATERIALS CHEMISTRY AND PHYSICS
(2023)
Article
Chemistry, Physical
Caroline Ponraj, P. Santhosh Kumar, Sumit Sarkar, C. Krishnamoorthi, N. Manikandan, G. Vinitha, Joseph Daniel
Summary: Photocatalysis is a research hot topic due to its wide applications in environmental remediation and renewable energy. This study reports the synthesis and activity of magnetic BiFe1-xCoxO3 (x = 0, 0.025, 0.05, 0.075 & 0.10) photocatalysts under visible light irradiation. The results show that increasing dopant concentration leads to decreasing crystallite size, decreasing bandgap, increasing magnetic behavior, and enhanced photocatalytic activity.
SURFACES AND INTERFACES
(2022)