Article
Thermodynamics
Abhishek Y. Deshmukh, Marco Davidovic, Temistocle Grenga, Raghavan Lakshmanan, Liming Cai, Heinz Pitsch
Summary: The study presents a reduced-order model for transient turbulent reactive sprays in compression ignition engines, termed the CARTS model. It is validated against experimental data and 3D numerical simulations, showing reasonable prediction of ignition delay time, flame lift-off length, and soot emissions. The CARTS model offers significantly lower computational cost compared to 3D simulation methods, enabling rapid screening of fuel candidates and offline model training for closed-loop control applications.
COMBUSTION AND FLAME
(2022)
Article
Energy & Fuels
Madan Mohan Avulapati, Radboud Pos, Thanos Megaritis, Lionel Ganippa
Summary: Experimental investigations were conducted to study the dynamic processes in the early development of high pressure sprays and their effects on ignition, flame stabilization, and soot formation. The analysis revealed that radial dispersion of fuel sprays at high injection pressures affects ignition and soot formation in diesel spray flames.
Article
Energy & Fuels
Dongfang Wang, Zhongjie Shi, Yikai Li, Ziming Yang, Haiyan Chen, Chenghan Sun
Summary: To investigate the effect of the wall on soot formation during spray combustion and explain the contradictory results, the vapor-phase, ignition, combustion, and soot formation of free-and impingement-spray were studied at different wall temperatures. Optical diagnostic techniques were used for comparison. The results show that compared to free spray, impingement spray has reduced vapor-phase spray tip penetration and increased vapor-phase spray volume. It also has a shorter ignition delay time when only the vapor-phase impinges on the wall. The soot formation of impingement spray is approximately one-third of free spray due to increased air entrainment. The relationship between wall temperature and soot formation is non-linear.
Article
Energy & Fuels
Q. Wan, G. Zhai, C. Wang, M. J. Evans, P. R. Medwell, A. C. Y. Yuen, S. Kook, G. H. Yeoh, Q. N. Chan
Summary: This study investigates the effects of ambient and injection parameters on the combustion characteristics of hydrogen-methane jet in direct-injection compression-ignition conditions. The results show that the ignition delay decreases with increasing ambient temperature and the lower ambient oxygen cases display a more voluminous ignition sequence. The jet flame recesses upstream and becomes increasingly lifted with lower ambient temperature and oxygen conditions, affecting the flame evolution and heat release profile.
Article
Energy & Fuels
Wenjun Zhong, Nasreldin M. Mahmoud, Qian Wang
Summary: This study utilized computational fluid dynamic simulation in a constant volume chamber to investigate the spray combustion and emission behavior of a biodiesel and gasoline blend, providing insights into combustion characteristics. A reduced kinetic mechanism for the blend and a multi-step phenomenological soot model were developed to accurately capture spray characteristics and soot formation under GCI engine conditions. The study also explored the effects of ambient oxygen level and temperature on flame structure and soot formation, offering valuable information for practical applications in GCI engines.
Article
Thermodynamics
Jaime Gimeno, Pedro Marti-Aldaravi, Marcos Carreres, Santiago Cardona
Summary: The combustion process in spray flames is a complex multi-phase phenomenon involving processes such as atomization, vaporization, and chemical kinetics. Experimental investigation on three different hydrocarbon fuels revealed that co-flow velocity and air co-flow temperature mainly control flame lift-off height, while co-flow velocity strongly influences soot formation. Differences in soot formation among fuels are likely related to fuel sooting tendency, which depends on the fuel molecular structure.
COMBUSTION AND FLAME
(2021)
Article
Energy & Fuels
Yuxuan Zhang, Xiaomin He, Jintao Wang, Fei Zhang, Yudong Kang
Summary: This study investigates a combustor based on the trapped vortex flame stabilization concept through experiments. It is found that under sub-atmospheric pressure conditions, the ignition and lean blowout performance, flame area, and flame radial penetration length decrease, while increasing inlet Mach number and temperature have both positive and negative impacts. High-speed photography methods reveal that the flame rotates with the main vortex during ignition and propagates along the cavity.
Article
Thermodynamics
Dominik Goeb, Marco Davidovic, Liming Cai, Pankaj Pancharia, Mathis Bode, Sascha Jacobs, Joachim Beeckmann, Werner Willems, Karl Alexander Heufer, Heinz Pitsch
Summary: This study investigates the ignition process and soot formation of e-fuels, finding that the fuel blend ignites similarly to n-dodecane and the oxygen content in the fuel leads to a reduction in common soot precursors in the gas phase. The ignition behavior of OME 1 is rooted in its high stoichiometric mixture fraction, while the fuel blend ignition process is dominated by its n-dodecane fraction up to 60 mol%.
PROCEEDINGS OF THE COMBUSTION INSTITUTE
(2021)
Article
Energy & Fuels
Jacek Hunicz, Maciej Mikulski, Pravesh Chandra Shukla, Michal S. Geca
Summary: The study shows that in partially premixed compression ignition combustion mode, air-path optimized HVO combustion has higher thermal efficiency and lower particulate emissions compared to diesel under high EGR rates and low boost pressures, while also exhibiting lower NOX emissions.
Article
Energy & Fuels
Gabriele Di Blasio, Roberto Ianniello, Carlo Beatrice
Summary: Studies on the influence of biofuels on decarbonization of the transport system highlight the potential of using fossil fuels with a higher renewable biofuel content, such as HVO, in ultra-low emission vehicles. Research focuses on exploring the characteristics of HVO in internal combustion engines and optimizing combustion control parameters for reduced emissions and improved efficiency.
Article
Metallurgy & Metallurgical Engineering
Hamisu Adamu Dandajeh, Nicos Ladommatos, Paul Hellier
Summary: This paper investigated the effect of equalizing ignition delay in a compression ignition engine, finding that adding an ignition improver reduced soot generation. Different fuel mixtures did not significantly affect ignition delay and fuel air premixing rate.
JOURNAL OF CENTRAL SOUTH UNIVERSITY
(2022)
Article
Energy & Fuels
Jinlin Han, Yu Wang, L. M. T. Somers, Bert van de Beld
Summary: This study investigates the ignition behavior and combustion process of hydrotreated pyrolysis oil (HPO) derived from different biomass resources. The results show that HPO has a longer ignition delay compared to commercially available biofuels and fossil fuels. The biomass type and after-treatment have a small influence on the ignition delay of HPO.
Article
Energy & Fuels
Hammam Aljabri, Xinlei Liu, Moaz Al-lehaibi, Kevin Moreno Cabezas, Abdullah S. AlRamadan, Jihad Badra, Hong G. Im
Summary: This study explored the potential of using various fuels in an isobaric combustion setting in a compression ignition engine. Multiple injection events improved fuel flexibility, leading to similar combustion performance and emissions for different fuels. Blending shorter-chain alcohols with baseline fuel reduced soot emissions but may negatively impact fuel economy. Increasing nozzle number and introducing isochoric combustion improved fuel economy for pure methanol combustion.
Article
Energy & Fuels
Ashutosh Jena, Akhilendra Pratap Singh, Avinash Kumar Agarwal
Summary: The fuel properties significantly affect the combustion characteristics of the diesel engine. This study investigated the mechanisms of pilot-main injection interactions and the effects of fuel properties using optical diagnostics and computational fluid dynamics. The results showed that dieseline and diesohol resulted in lower soot formation compared to baseline diesel.
Article
Energy & Fuels
Guanxiong Zhai, Sensen Xing, Anthony C. Y. Yuen, Paul R. Medwell, Sanghoon Kook, Guan Heng Yeoh, Qing Nian Chan
Summary: This study investigates the impact of laser-induced plasma ignition on combustion behaviors of isooctane. The results show that laser ignition reduces flame lift-off lengths and increases flame stability, but also leads to increased soot formation.
Article
Thermodynamics
Fredrik Grovdal, Sigurd Sannan, Christoph Meraner, Tian Li, Terese Lovas
Summary: The study discusses a dimensional-decomposition approach for turbulent (reacting) flows by decomposing 3D into 3x1D. The research focuses on the Three-Dimensional Linear Eddy Model (LEM3D) and its recouplings, finding that the auxiliary coupling introduces large gradients leading to increased burning rates. Applications of LEM3D should be limited to areas where high-resolution treatment of scalar mixing and reaction is of particular interest.
FLOW TURBULENCE AND COMBUSTION
(2021)
Article
Acoustics
Bruno G. Pollet, Faranak Foroughi, Alaa Y. Faid, David R. Emberson, Md. H. Islam
ULTRASONICS SONOCHEMISTRY
(2020)
Article
Energy & Fuels
Anna Espekvist, Tian Li, Peter Glarborg, Terese Lovas, Peter Arendt Jensen
Summary: This study presents a simple model for devolatilization of biomass under suspension firing conditions, using a single first order reaction. Results show that particle radius and gas phase temperature have a significant influence on devolatilization rate, while aspect ratio has a smaller effect that cannot be neglected.
Article
Energy & Fuels
David Emberson, Judit Sandquist, Terese Lovas, Alessandro Schonborn, Inge Saanum
Summary: This study successfully validated the concept of using a photo-chemical 'smart' fuel to significantly change the ignition quality of a fuel in HCCI mode combustion and demonstrated the concept of on-board 'smart fuel' applications for ICE.
Article
Energy & Fuels
Corinna Netzer, Tian Li, Terese Lovas
Summary: The incineration of municipal solid waste is an attractive technology for generating thermal energy and reducing landfill waste volume. Numerical models are needed to optimize primary measures to ensure low emission formation during combustion. This work presents a comprehensive description of heterogeneous and homogeneous reactions in solid waste devolatilization and combustion, using surrogate species adopted from liquid fuel and biomass combustion.
Article
Energy & Fuels
David Robert Emberson, Jan Wyndorps, Ahfaz Ahmed, Karl Oskar Pires Bjorgen, Terese Lovas
Summary: The study demonstrates that using glycerol as an additive to diesel fuel has the potential to suppress the formation of soot/PM. The diesel/glycerol emulsion showed differences in ignition delay and AHRR compared to pure diesel, with no significant impact on brake thermal efficiency, and a notable reduction in particles with diameters greater than 25 nm.
Article
Thermodynamics
Corinna Netzer, Ahfaz Ahmed, Andrea Gruber, Terese Lovas
Summary: The study reveals the impact of flame curvature and preferential diffusion of H2 on local equivalence ratio, which in turn affects NO formation in NH3/H2/N2-air flames. The formation of NO is found to be influenced by local equivalence ratio and radical pools, with differences between H2-depleted and H2-enriched regions of the flame front across a wide range of equivalence ratios.
COMBUSTION AND FLAME
(2021)
Article
Energy & Fuels
Michal T. Lewandowski, Corinna Netzer, David R. Emberson, Terese Lovas
Summary: This study numerically explores the potential of glycerol as a diesel fuel additive to reduce soot emissions, showing its capability to reduce soot formation while having a moderate effect on CO emissions. Results also indicate that glycerol has a positive impact on increasing the oxidizer content in the combustion process.
Article
Thermodynamics
Jingyuan Zhang, Tian Li, Henrik Strom, Terese Lovas
Summary: In the study, a transient 3D model utilizing a new coupling approach for fixed bed biomass combustion is presented. The model, formulated as an Eulerian-Lagrangian framework with optimized sub-models, is validated through laboratory-scale experiments and sensitivity analysis, showing good agreement with experimental measurements and discussing the coupling effects.
COMBUSTION AND FLAME
(2022)
Article
Energy & Fuels
Shivang Khare, Karl Oskar Pires Bjorgen, Komeil Kohansal, Muhammad Salman Haider, Daniele Castello, Thomas Helmer Pedersen, Terese Lovas, David Robert Emberson
Summary: This study investigates the utilization of municipal solid waste (MSW) based biofuel as a diesel blendstock in a compression ignition engine. The effects of blending nonupgraded and upgraded HTL biofuel with diesel were examined in terms of combustion and emissions. The results show that the upgraded HTL biofuel outperforms the nonupgraded blend in both combustion characteristics and emissions.
Article
Energy & Fuels
Komeil Kohansal, Eliana Lozano Sanchez, Shivang Khare, Karl Oskar Pires Bjorgen, Muhammad Salman Haider, Daniele Castello, Terese Lovas, Lasse Aistrup Rosendahl, Thomas Helmer Pedersen
Summary: Hydrothermal liquefaction (HTL) bio-crude is a potential alternative to fossil fuels, but developing economically viable HTL-based value-chains is challenging due to contaminants and complexity. This study evaluates different refining scenarios for producing compliant HTL-derived road diesel blendstock. Partial hydrotreating improves distillation recovery and physicochemical properties, creating a diesel blendstock that complies with standards. With improved desulphurization, the bio-blendstock share can increase up to 10 wt%. The hydrotreated bio-crude distillate mixture shows promise as a green blendstock for meeting road transport diesel fuel demand.
Article
Thermodynamics
Miao Yang, Jingyuan Zhang, Shenghui Zhong, Tian Li, Terese Lovas, Hesammedin Fatehi, Xue-Song Bai
Summary: A three-dimensional reactive multi-phase particle-in-cell (MP-PIC) model is used to investigate biomass combustion and gasification in fluidized bed furnaces, with a distribution kernel method (DKM) proposed to solve numerical instability caused by coarse grain method (CGM) clustering. The DKM improves the accuracy and robustness of the model in capturing transient heat transfer processes and studying combustion/gasification processes under varying conditions.
COMBUSTION AND FLAME
(2022)
Article
Energy & Fuels
Yingna Du, Chen Huang, Wei Jiang, Qiangwei Yan, Yongfei Li, Gang Chen
Summary: In this study, anionic surfactants modified hydrotalcite was used as a flow improver for crude oil under low-temperature conditions. The modified hydrotalcite showed a significant viscosity reduction effect on crude oil. The mechanism of the modified hydrotalcite on viscosity and pour point of crude oil was explored through characterization and analysis of the modified hydrotalcite and oil samples.
Article
Energy & Fuels
Mohammad Saeid Rostami, Mohammad Mehdi Khodaei
Summary: In this study, a hybrid structure, MIL-53(Al)@MWCNT, was synthesized by combining MIL-53(Al) particles and -COOH functionalized multi-walled carbon nanotube (MWCNT). The hybrid structure was then embedded in a polyethersulfone (PES) polymer matrix to prepare a mixed matrix membrane (MMM) for CO2/CH4 and CO2/N2 separation. The addition of MWCNTs prevented MIL-53(Al) aggregation, improved membrane mechanical properties, and enhanced gas separation efficiency.
Article
Energy & Fuels
Yunlong Li, Desheng Huang, Xiaomeng Dong, Daoyong Yang
Summary: This study develops theoretical and experimental techniques to determine the phase behavior and physical properties of DME/flue gas/water/heavy oil systems. Eight constant composition expansion (CCE) tests are conducted to obtain new experimental data. A thermodynamic model is used to accurately predict saturation pressure and swelling factors, as well as the phase boundaries of N2/heavy oil systems and DME/CO2/heavy oil systems, with high accuracy.
Article
Energy & Fuels
Morteza Afkhamipour, Ebad Seifi, Arash Esmaeili, Mohammad Shamsi, Tohid N. Borhani
Summary: Non-conventional amines are being researched worldwide to overcome the limitations of traditional amines like MEA and MDEA. Adequate process and thermodynamic models are crucial for understanding the applicability and performance of these amines in CO2 absorption, but studies on process modeling for these amines are limited. This study used rate-based modeling and Deshmukh-Mather method to model CO2 absorption by DETA solution in a packed column, validated the model with experimental data, and conducted a sensitivity analysis of mass transfer correlations. The study also compared the CO2 absorption efficiency of DETA solution with an ionic solvent [bmim]-[PF6] and highlighted the importance of finding optimum operational parameters for maximum absorption efficiency.
Article
Energy & Fuels
Arastoo Abdi, Mohamad Awarke, M. Reza Malayeri, Masoud Riazi
Summary: The utilization of smart water in EOR operations has gained attention, but more research is needed to understand the complex mechanisms involved. This study investigated the interfacial tension between smart water and crude oil, considering factors such as salt, pH, asphaltene type, and aged smart water. The results revealed that the hydration of ions in smart water plays a key role in its efficacy, with acidic and basic asphaltene acting as intrinsic surfactants. The pH also influenced the interfacial tension, and the aged smart water's interaction with crude oil depended on asphaltene type, salt, and salinity.
Article
Energy & Fuels
Dongao Zhu, Kun Zhu, Lixian Xu, Haiyan Huang, Jing He, Wenshuai Zhu, Huaming Li, Wei Jiang
Summary: In this study, cobalt-based metal-organic frameworks (Co-based MOFs) were used as supports and co-catalysts to confine the NHPI catalyst, solving the leaching issue. The NHPI@Co-MOF with carboxyl groups exhibited stronger acidity and facilitated the generation of active oxygen radicals O2•, resulting in enhanced catalytic activity. This research provides valuable insights into the selection of suitable organic linkers and broadens the research horizon of MOF hybrids in efficient oxidative desulfurization (ODS) applications.
Article
Energy & Fuels
Edwin G. Hoyos, Gloria Amo-Duodu, U. Gulsum Kiral, Laura Vargas-Estrada, Raquel Lebrero, Rail Munoz
Summary: This study investigated the impact of carbon-coated zero-valent nanoparticle concentration on photosynthetic biogas upgrading. The addition of nanoparticles significantly increased microalgae productivity and enhanced nitrogen and phosphorus assimilation. The presence of nanoparticles also improved the quality of biomethane produced.
Article
Energy & Fuels
Yao Xiao, Asma Leghari, Linfeng Liu, Fangchao Yu, Ming Gao, Lu Ding, Yu Yang, Xueli Chen, Xiaoyu Yan, Fuchen Wang
Summary: Iron is added as a flocculant in wastewater treatment and the hydrothermal carbonization (HTC) of sludge produces wastewater containing Fe. This study investigates the effect of aqueous phase (AP) recycling on hydrochar properties, iron evolution and environmental assessment during HTC of sludge. The results show that AP recycling process improves the dewatering performance of hydrochar and facilitates the recovery of Fe from the liquid phase.
Article
Energy & Fuels
He Liang, Tao Wang, Zhenmin Luo, Jianliang Yu, Weizhai Yi, Fangming Cheng, Jingyu Zhao, Xingqing Yan, Jun Deng, Jihao Shi
Summary: This study investigated the influence of inhibitors (carbon dioxide, nitrogen, and heptafluoropropane) on the lower flammability limit of hydrogen and determined the critical inhibitory concentration needed for complete suppression. The impact of inhibitors on explosive characteristics was evaluated, and the inhibitory mechanism was analyzed with chemical kinetics. The results showed that with the increase of inhibitor quantity, the lower flammability limit of hydrogen also increased. The research findings can contribute to the safe utilization of hydrogen energy.
Article
Energy & Fuels
Zonghui Liu, Zhongze Zhang, Yali Zhou, Ziling Wang, Mingyang Du, Zhe Wen, Bing Yan, Qingxiang Ma, Na Liu, Bing Xue
Summary: In this study, high-performance solid catalysts based on phosphotungstic acid (HPW) supported on Zr-SBA-15 were synthesized and evaluated for the one-pot conversion of furfural (FUR) to γ-valerolactone (GVL). The catalysts were characterized using various techniques, and the ratio of HPW and Zr was found to significantly affect the selectivity of GVL. The HPW/Zr-SBA-15 (2-4-15) catalyst exhibited the highest GVL yield (83%) under optimized reaction conditions, and it was determined that a balance between Bronsted acid sites (BAS) and Lewis acid sites (LAS) was crucial for achieving higher catalytic performance. The reaction parameters and catalyst stability were also investigated.
Article
Energy & Fuels
Michael Stoehr, Stephan Ruoff, Bastian Rauch, Wolfgang Meier, Patrick Le Clercq
Summary: As part of the global energy transition, an experimental study was conducted to understand the effects of different fuel properties on droplet vaporization for various conventional and alternative fuels. The study utilized a flow channel to measure the evolution of droplet diameters over time and distance. The results revealed the temperature-dependent effects of physical properties, such as boiling point, liquid density, and enthalpy of vaporization, and showed the complex interactions of preferential vaporization and temperature-dependent influences of physical properties for multi-component fuels.
Article
Energy & Fuels
Yuan Zhuang, Ruikang Wu, Xinyan Wang, Rui Zhai, Changyong Gao
Summary: Through experimental validation and optimization of the chemical kinetic model, it was found that methanol can accelerate the oxidation reaction of ammonia, and methanol can be rapidly oxidized at high concentration. HO2 was found to generate a significant amount of OH radicals, facilitating the oxidation of methanol and ammonia. Rating: 7.5/10.
Article
Energy & Fuels
Radwan M. EL-Zohairy, Ahmed S. Attia, A. S. Huzayyin, Ahmed I. EL-Seesy
Summary: This paper presents a lab-scale experimental study on the impact of diethyl ether (DEE) as an additive to waste cooking oil biodiesel with Jet A-1 on combustion and emission features of a swirl-stabilized premixed flame. The addition of DEE to biodiesel significantly affects the flame temperature distribution and emissions. The W20D20 blend of DEE, biodiesel, and Jet A-1 shows similar flame temperature distribution to Jet A-1 and significantly reduces UHC, CO, and NOx emissions compared to Jet A-1.
Article
Energy & Fuels
Jiang Bian, Ziyuan Zhao, Yang Liu, Ran Cheng, Xuerui Zang, Xuewen Cao
Summary: This study presents a novel method for ammonia separation using supersonic flow and develops a mathematical model to investigate the condensation phenomenon. The results demonstrate that the L-P nucleation model accurately characterizes the nucleation process of ammonia at low temperatures. Numerical simulations also show that increasing pressure and concentration can enhance ammonia condensation efficiency.
Article
Energy & Fuels
Shiyuan Pan, Xiaodan Shi, Beibei Dong, Jan Skvaril, Haoran Zhang, Yongtu Liang, Hailong Li
Summary: Integrating CO2 capture with biomass-fired combined heat and power (bio-CHP) plants is a promising method for achieving negative emissions. This study develops a reliable data-driven model based on the Transformer architecture to predict the flowrate and CO2 concentration of flue gas in real time. The model validation shows high prediction accuracy, and the potential impact of meteorological parameters on model accuracy is assessed. The results demonstrate that the Transformer model outperforms other models and using near-infrared spectral data as input features improves the prediction accuracy.