4.7 Article

Organomagnesium towards efficient synthesis of recyclable polymers

Journal

EUROPEAN POLYMER JOURNAL
Volume 130, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2020.109659

Keywords

Organomagnesium; Ring-opening polymerization; Recyclable polymers

Funding

  1. National Natural Science Foundation of China [21504039]

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Recyclable polymers, such as poly(gamma-butyrolactone) (PGBL), offer a great opportunity to address the environmental issues of plastics. Herein, we presented an alternative commercial powerful organomagnesium catalysis for ring-opening polymerizations of 3,4-trans six-membered ring-fused gamma-butyrolactone (M), enantiomer (R)-M and (S)-M with high conversions (up to 89%). Di-n-butylmagnesium and n-butylethylmagnesium exhibited effective activities for all three kinds of monomers. The polymerization process of (R)-M was systematically investigated with di-n-butylmagnesium as the catalyst. Well-defined polyesters with molecular weights ranging from 4780 to 17420 g/mol were obtained. The commercial organomagnesium catalysis would broaden the applications of recyclable polymers.

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