4.7 Article

Pt nanodendrites with (111) crystalline facet as an efficient, stable and pH-universal catalyst for electrochemical hydrogen production

Journal

CHINESE CHEMICAL LETTERS
Volume 31, Issue 9, Pages 2478-2482

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2020.03.032

Keywords

Platinum nanodendrites; Hydrogen evolution reaction; Electrocatalytic activity; Long-term durability; pH-universal property

Funding

  1. National Natural Science Foundation of China [51573201, 51501209, 201675165]
  2. NSFC-Zhejiang Joint Fund for the Integration of Industrialization and Informatization [U1709205]
  3. Strategic Priority Research Program of the Chinese Academy of Sciences [XDA22000000]
  4. Scientific Instrument Developing Project of the Chinese Academy of Sciences [YZ201640]
  5. Science and Technology Major Project of Ningbo [2016S1002, 2016B10038]
  6. International S&T Cooperation Program of Ningbo [2017D10016]

Ask authors/readers for more resources

High-performance nanomaterial catalysts for hydrogen evolution reaction via electrochemical water splitting are significant to the development of hydrogen energy. In this work, we report a robust and highly active catalyst fabricated through direct electrochemical deposition of Pt nanodendrites at the surface of activated carbon (Pt NDs). Owing to the large electrochemically active area and the exposed (111) facet of Pt, Pt NDs exhibits outstanding activity towards hydrogen evolution reaction with a low requiring overpotential of 0.027 V at 10 mA/cm(2) and Tafel slope of 22 mV/dec in acidic media. In addition, the hydrogen yield of Pt NDs is 30%-45% larger than that of commercial Pt/C at the same Pt loadings. Moreover, Pt NDs exhibits excellent long-term durability whose hydrogen production efficiency remains unchanged after six-hour hydrogen production, while the efficiency of commercial Pt/C catalyst decayed 9% under the same circumstance. Considering the superiority of catalytic activity and stability, this Pt NDs present great potentiality towards practical hydrogen production application. (C) 2020 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.

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