4.6 Article

Removal of Cr(VI) from Acid Wastewater by BC/ZnFe(2)O(4)Magnetic Nanocomposite via the Synergy of Absorption-Photocatalysis

Journal

CHEMCATCHEM
Volume 12, Issue 16, Pages 4121-4131

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.202000619

Keywords

BC; ZnFe2O4; magnetic; broad photoabsorption; adsorption; photocatalytic

Funding

  1. National Key Research and Development Program of China [2017YFD0601006]
  2. Major Projects for Science and Technology Development of Zhejiang Province [2020 C01017]

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Photocatalysis is a promising solar energy conversion technology due to its potential applications in water treatment, searching for highly efficient photocatalytic materials is highly desirable. Herein, we have prepared a series of biochar(BC)/ZnFe(2)O(4)magnetic nanocomposites by the calcination-hydrothermal two-step method. BC/ZnFe(2)O(4)owns improved photoabsorption from 400 to 1300 nm. PL spectra of BC/ZnFe(2)O(4)shows a weaker intensity compared with BC and ZnFe2O4, and BC/ZnFe(2)O(4)generates a stronger photocurrent density (similar to 0.08 mu A cm(-2)) than that of BC (0) or ZnFe2O4(0.03 mu A cm(-2)) under the visible light irradiation, implying efficient separation efficiency of photogeneration carriers. The investigation of pH (3, 5, 7, 9, 11) sensitivity of BC/ZnFe(2)O(4)demonstrates that removal efficiency of Cr(VI) achieves the highest rate at pH=3. Under visible light irradiation, BC/ZnFe(2)O(4)as photocatalyst can remove 80 % Cr(VI), higher than that of BC (0) or ZnFe2O4(44 %). In addition, BC/ZnFe(2)O(4)composites exhibit excellent cycling stability and can be easily separated for recycling due to its stability and unique magnetic properties. This work has presented a promising strategy in adsorption-photocatalytic treatment of acidic wastewater containing heavy metals.

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