Journal
CATALYSIS COMMUNICATIONS
Volume 73, Issue -, Pages 63-68Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2015.10.005
Keywords
Phenol; Selective hydrogenation; Cyclohexanone; Cyclodextrin; Ionic liquid; Rhodium nanoparticles
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Funding
- Russian Foundation for Basic Research [12-08-01187]
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The effect of cyclodextrins on the activity and selectivity of a catalytic system based on rhodium nanoparticles stabilized by polyacrylic acid (PAA) in the hydrogenation of phenol in aqueous solution and ionic liquid was reported. It was found that the reaction medium and the nature of the cyclodextrin (CD) essentially affect the rate of reaction and the distribution of reaction products. The use of the system based on rhodium nanoparticles stabilized by cyclodextrins makes it possible to rapidly and efficiently prepare cyclohexanone.from phenol with yields up to 100% under relatively mild conditions (1 h; T = 80 degrees C, p(H-2) = 10-40 bars). (C) 2015 Elsevier B.V. All rights reserved.
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