4.8 Article

Enhanced corrosion and wear resistances by graphene oxide coating on the surface of Mg-Zn-Ca alloy

Journal

CARBON
Volume 109, Issue -, Pages 340-351

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2016.08.032

Keywords

-

Funding

  1. National Natural Science Foundation [51401200]
  2. Natural Science Foundation of Jilin Province [20140520099JH, 20160101288JC]
  3. Science & Technology Pillar Program of Qinghai Province [2014-GX-216A]

Ask authors/readers for more resources

The poor corrosion and wear resistances hinder the industrial applications of magnesium and its alloys. In this paper, a new graphene oxide (GO) coating is fabricated on the surface of extruded Mg-Zn-Ca alloy, via the silane coupling, agent. The GO coating has fully covered the Mg substrate through the chemical reactions, and formed an overlapped multilayer structure by interlocked effects. Electrochemical measurements indicate that the anti-corrosion performance can be remarkably improved by silane/GO coating, because the stable covalent bonds within the coating effectively restrict the penetration of electrolyte into the Mg surface, representing an excellent corrosion barrier effect. The GO coating drastically promotes the wear resistance, due to the superior bonding between the Mg substrate and GO sheets with high hardness and good lubricant effect. (C) 2016 Elsevier Ltd. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.8
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Metallurgy & Metallurgical Engineering

Improvement of strength and ductility synergy in a room-temperature stretch-formable Mg-Al-Mn alloy sheet by twin-roll casting and low-temperature annealing

T. Nakata, C. Xu, K. Kaibe, Y. Yoshida, K. Yoshida, S. Kamado

Summary: Strength and ductility of an Mg-3%Al-Mn alloy sheet were improved using twin-roll casting and low-temperature annealing, resulting in excellent tensile properties and stretch formability.

JOURNAL OF MAGNESIUM AND ALLOYS (2022)

Article Chemistry, Physical

Benchmarks of the density functional tight-binding method for redox, protonation and electronic properties of quinones

Maureen M. Kitheka, Morgan Redington, Jibo Zhang, Yan Yao, Puja Goyal

Summary: Organic materials with controllable molecular design, such as crystalline quinones, show promise as electrode materials in rechargeable batteries due to their voltage tunability and environmental friendliness. However, the detailed mechanism of proton-coupled electron transfer (PCET) in quinone crystals remains elusive. In this study, the performance of the density functional tight-binding (DFTB) method, specifically DFTB3, in describing charge transport in crystalline quinones was benchmarked. The results highlight the deficiencies of DFTB3 in accurately predicting the proton affinity, structural, and electronic properties of crystalline quinones, calling for further development of the DFTB method in this context.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2022)

Article Chemistry, Physical

A green and efficient method for preparing graphene using CO2@Mg in-situ reaction and its application in high-performance lithium-ion batteries

Shuaihu Wei, Hailong Shi, Xuejian Li, Xiaoshi Hu, Chao Xu, Xiaojun Wang

Summary: This study presents a simple and cost-effective approach to fabricate few-layer graphene through the reaction between Mg melt and CO2 gas. The graphene produced has high graphitization degree and small thickness. When used as lithium storage materials, the graphene exhibits excellent rate capability and cycling performance.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Article Materials Science, Multidisciplinary

Effect of annealing on microstructure evolution and age-hardening behavior of dilute Mg-Al-Ca-Mn alloy

J. Zuo, T. Nakata, C. Xu, Y. P. Xia, H. L. Shi, G. S. Wang, G. Z. Tang, G. H. Fan, S. Kamado, L. Geng

Summary: The microstructure evolution and mechanical properties of the as-drawn dilute Mg-0.8Al-0.1Ca-0.6Mn alloy wires during annealing and peak-aging treatment were investigated. The study revealed that the high density of nano-sized Al-Mn precipitates hindered grain boundary migration and restricted grain growth during low-temperature annealing, while partial dissolution of Al-Mn precipitates led to obvious grain growth and increased uniformity of recrystallization grain size during high-temperature annealing. Additionally, there was a growth preference in grains with a specific orientation, which was closely associated with texture changes. Furthermore, the alloy exhibited a significant age-hardening response after peak-aging treatment at 500 degrees C for 10 minutes, resulting in simultaneous improvement of tensile yield strength and elongation to failure, which was mainly attributed to the formation of monolayered Guinier-Preston (G.P.) zones and planar Al2Ca precipitates.

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T (2022)

Article Chemistry, Physical

Development of corrosion-resistant Mg-Al-Ca-Mn-Zn alloy sheet with good tensile properties and stretch formability

T. Nakata, C. Xu, Nurul Aliea Syafiqa binti Osman, L. Geng, S. Kamado

Summary: By investigating the effects of Al content on the mechanical properties, formability, and corrosion resistance of magnesium alloy sheets, it was found that moderate Al addition significantly improves these properties, resulting in good overall performance of the alloy sheets.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Article Nanoscience & Nanotechnology

Effect of grain boundary segregation on microstructure and mechanical properties of ultra-fine grained Mg-Al-Ca-Mn alloy wires

J. Zuo, T. Nakata, C. Xu, Y. P. Xia, H. L. Shi, X. J. Wang, G. Z. Tang, W. M. Gan, E. Maawad, G. H. Fan, S. Kamado, L. Geng

Summary: A high strength dilute Mg-0.8Al-0.1Ca-0.6Mn alloy wire was successfully developed by hot drawing, with the high strength attributed to the ultra-fine DRXed grains, coarse elongated unrecrystallized grains with dense dislocations, and nano sized Al2Ca and Al-Mn precipitates dispersed in the alloy wire.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2022)

Article Nanoscience & Nanotechnology

Understanding room-temperature deformation behavior in a dilute Mg-1.52Zn-0.09Ca (mass%) alloy sheet with weak basal texture

T. Nakata, T. Hama, K. Sugiya, S. Kamado

Summary: The deformation behavior of a weakly textured Mg-1.52Zn-0.09Ca alloy sheet during room-temperature tests was investigated. The sheet exhibited high elongation to failure and satisfactory stretchability, but inferior bendability. This study provides important guidance for the development of room-temperature formable Mg alloy sheets.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2022)

Article Nanoscience & Nanotechnology

Role of grain boundary segregation on microstructural development in basal-textured Mg-Al-Zn alloy sheet

T. Nakata, Z. H. Li, T. T. Sasaki, K. Hono, S. Kamado

Summary: This study reports the influence of grain boundary segregation on microstructure development during hot-rolling of AZ31 alloy. Annealing at 420 degrees C induces strong grain boundary segregation, promoting dynamic recrystallization and strong basal texture. Annealing at 500 degrees C reduces grain boundary segregation, hindering dynamic recrystallization and resulting in a weak rolling-direction-split texture, improving the stretch formability of the alloy sheet.

SCRIPTA MATERIALIA (2022)

Article Chemistry, Physical

Preparation of high-performance Mg-Gd-Y-Mn-Sc alloy by heat treatment and extrusion

Zhao Yang, Taiki Nakata, Chao Xu, Gang Wang, Lin Geng, Shigeharu Kamado

Summary: A high-performance Mg-8Gd-4Y-0.5Mn-0.2Sc alloy was fabricated using homogenization, hot extrusion, and ageing. The microstructure evolution during homogenization was studied, and an optimum time of 18 h was determined to minimize the volume fraction of second phase particles and maintain a fine grain structure. The alloy exhibited excellent age-hardening ability and strength after peak-aged treatment, with a tensile yield stress of 441 MPa and an ultimate tensile strength of 506 MPa. The high yield strength was attributed to the co-existing bimodal microstructure, fine dynamically recrystallized grains, dense precipitated particles, and nano-scale precipitates. Precipitation strengthening was revealed as the dominant strengthening mechanism.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Chemistry, Physical

Twinning-mediated texture weakening in a basal-textured Mg-6Al-1Zn (mass%) alloy sheet by a novel cold-sample rolling method

T. Nakata, C. Xu, L. Geng, S. Kamado

Summary: This paper reports the application of cold-sample rolling (CSR) processing in a Mg-6Al-1Zn alloy sheet, which resulted in a high fraction of double twins and a substantial texture-weakening effect. Compared to high-temperature rolling (HTR) processing, CSR processing induced a relatively higher texture-weakening effect. The results indicate that twinning-mediated static recrystallization is essential for texture weakening in Al-concentrated Mg-alloy sheets.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Article Materials Science, Multidisciplinary

Dynamic microstructure evolution and mechanical properties of dilute Mg-Al-Ca-Mn alloy during hot rolling

Shiwei Xu, Congcong Zhu, Zhanhong Lin, Chen Jin, S. Kamado, K. Oh-ishi, Yun Qin

Summary: The dynamic microstructure and texture of dilute Mg-0.50Al-0.71Ca-0.33Mn alloy during hot rolling were investigated. The study revealed the important role of extension twins, double twins, and kinks in the formation of rolling texture.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2022)

Article Nanoscience & Nanotechnology

Discontinuous yielding phenomena triggered by Zn addition in low-alloyed Mg-Al-Ca-Mn alloys

Z. H. Li, S. Gao, T. T. Sasaki, T. Nakata, S. Kamado, N. Tsuji, K. Hono

Summary: Clarifying the origin of the yielding phenomenon is crucial for improving the flow stability and surface finish of magnesium alloy sheet products. This study investigates the effect of Zn addition on discontinuous yielding in low-alloyed magnesium alloy sheets and reveals the significant impact of Zn on yield-drop. Transmission electron microscopy and atom probe tomography analysis demonstrate the influence of Ca-Zn co-clusters on dislocations, and different stretching directions of the sheet result in distinct Luders deformations.

SCRIPTA MATERIALIA (2022)

Article Materials Science, Multidisciplinary

Synergistic effect of Mn thorn Sc additions on the microstructure evolution and mechanical properties of Mg-Gd-Y-Mn-Sc alloy

Zhao Yang, Gang Wang, Chao Xu, Miao Wang, Taiki Nakata, Hongyu Xu, Lin Geng, Shigeharu Kamado

Summary: In this study, Mg-Gd-Y-Mn-Sc alloys with different Mn and Sc contents were prepared. The addition of Mn and Sc refined the grain size and promoted the dynamic recrystallization and dynamic precipitation during hot extrusion, resulting in improved strength-ductility balance of the alloy.

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T (2022)

Article Chemistry, Physical

Effect of micro-texture on tensile properties and room-temperature stretch formability of Mg-Al-Zn alloy sheet

T. Nakata, T. Matsuno, R. Oki, S. Kamado

Summary: The effect of micro-texture on the tensile properties and room-temperature stretch formability of Mg-Al-Zn alloy sheet was studied. The introduction of micro-texture through solution treatment, hot-rolling, and post-annealing increased the fraction of a unique texture component, which improved the limiting dome height without compromising the strength due to the high activity of tensile twinning and minimal change in the Schmid factor for basal slips. This finding highlights the importance of micro-texture designing for the development of high strength-formability synergy in magnesium alloy sheets.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Chemistry, Physical

Dendritic growth lowers carbon electrode work function for efficient perovskite solar cells

Jie Sheng, Jingshan He, Dun Ma, Yuanbo Wang, Wu Shao, Tian Ding, Ronghao Cen, Jingwen He, Zhihao Deng, Wenjun Wu

Summary: This study presents an innovative approach to improve the photovoltaic conversion characteristics and stability of perovskite solar cells through carbon electrode interface modification. By in-situ polymerization and carbonization on the surface of nano-graphite, a dendritic structure carbon electrode is formed, reducing the work function and aligning the energy levels with perovskite. This leads to improved charge and hole collection efficiency, resulting in increased photovoltaic conversion efficiency. Furthermore, the modified carbon electrode-based perovskite solar cells exhibit exceptional stability, maintaining high efficiency even without encapsulation.

CARBON (2024)

Article Chemistry, Physical

High-performance epoxy nanocomposites via constructing a rigid-flexible interface with graphene oxide functionalized by polyetheramine and f-SiO2

Guodong Shi, Jian Song, Xiaoxiao Tian, Tongtong Liu, Zhanjun Wu

Summary: This study demonstrates the improvement of mechanical properties and reduction of coefficient of thermal expansion (CTE) in graphene oxide (GO)/epoxy (EP) nanocomposites by enhancing the interface between GO and EP through functionalization and incorporating rigid-flexible interphases. The results reveal that the SiO2-PEA-GO hybrid exhibits better strengthening and toughening effects, as well as lower CTE, compared to the PEA-GO hybrid due to the presence of rigid-flexible interfaces with higher bonding strength and better energy dissipation mechanisms. Additionally, the nanocomposites with longer polyetheramine (PEA) molecules in the rigid-flexible interphases demonstrate higher strength and toughness, while maintaining a lower CTE. This work provides a promising strategy for constructing adjustable flexible-rigid interfacial structures and offers potential in developing GO/EP nanocomposites with high mechanical properties and low CTE.

CARBON (2024)

Article Chemistry, Physical

A facile route to the synthesis of carbon replicas cast from narrow-mesoporous matrices

Rafal Janus, Sebastian Jarczewski, Jacek Jagiello, Piotr Natkanski, Mariusz Wadrzyk, Marek Lewandowski, Marek Michalik, Piotr Kustrowski

Summary: In this study, a facile procedure for the synthesis of CMK-1 and CMK-2 carbon replicas was developed. The method utilizes basic laboratory equipment and a renewable carbon source, and operates under mild conditions. The resulting carbon mesostructures exhibit exquisite replication fidelity and structural homogeneity, making them suitable for applications in various fields.

CARBON (2024)

Article Chemistry, Physical

Microstructure and energetic characteristics of direct ink printed polymer-free rGO/nanothermite aerogel

Anqi Wang, Connor J. MacRobbie, Alex Baranovsky, Jean-Pierre Hickey, John Z. Wen

Summary: In this study, a novel polymer-free nanothermite aerogel with a wide range of nanoparticle loading was fabricated via a new additive manufacturing process. The SEM images showed a unique porous structure formed by extra thin rGO sheets, wrapping individual nanothermite clusters. The DSC-TGA results and high-speed combustion videos confirmed the enhanced energetic performance of the printed specimen.

CARBON (2024)

Article Chemistry, Physical

A solar-driven interfacial evaporator for seawater desalination based on mussel-inspired superhydrophobic composite coating

Wanze Wu, Misheng Zhao, Shiwei Miao, Xiaoyan Li, Yongzhong Wu, Xiao Gong, Hangxiang Wang

Summary: Superhydrophobic solar-driven interfacial evaporator is an energy-efficient technology for seawater desalination, which is easily fabricated using robust photothermal superhydrophobic coating and substrate. The created bifunctional coating on the melamine sponge substrate shows stable and highly efficient photothermal and superhydrophobic performance for seawater desalination. This superhydrophobic solar-driven interfacial evaporator is expected to have wide applications in seawater desalination.

CARBON (2024)

Article Chemistry, Physical

Bead-like flexible ZIF-67-derived Co@Carbon composite nanofibre mat for wideband microwave absorption in C-band

Zichen Xiang, Zhi Song, Tiansheng Wang, Menghang Feng, Yijing Zhao, Qitu Zhang, Yi Hou, Lixi Wang

Summary: This study presents a co-electrospinning synthesis strategy to fabricate lightweight and porous Co@C composite nanofibres with wideband microwave attenuation capacity. The addition of MOF-derived Co additives enhances the low-frequency absorption performance.

CARBON (2024)

Article Chemistry, Physical

A perovskite-graphene device for X-ray detection

J. Snow, C. Olson, E. Torres, K. Shirley, E. Cazalas

Summary: This study investigates the use of a perovskite-based graphene field effect transistor (P-GFET) device for X-ray detection. The sensitivity and responsivity of the device were found to be influenced by factors such as X-ray tube voltage, current, and source-drain voltage. Simulation experiments were conducted to determine the dose rate and energy incident on the device during irradiation.

CARBON (2024)

Article Chemistry, Physical

Microporous carbon prepared by microwave pyrolysis of scrap tyres and the effect of K+ in its structure on xylene adsorption

Zuzana Jankovska, Lenka Matejova, Jonas Tokarsky, Pavlina Peikertova, Milan Dopita, Karolina Gorzolkova, Dominika Habermannova, Michal Vastyl, Jakub Belik

Summary: This study provides new insights into microwave-assisted pyrolysis of scrap tyres, demonstrating that it can produce microporous carbon black with potential application in xylene adsorption. Compared to conventional pyrolysis, microwave pyrolysis requires less time and energy while maintaining similar adsorption capacity.

CARBON (2024)

Article Chemistry, Physical

Ambipolar charge transfer of larger fullerenes enabled by the modulated surface potential of h-BN/Rh(111)

Max Bommert, Bruno Schuler, Carlo A. Pignedoli, Roland Widmer, Oliver Groning

Summary: A detailed understanding of the interaction between molecules and two-dimensional materials is crucial for incorporating functional molecular films into next-generation 2D material-organic hybrid devices. This study compares the energy level alignment of different-sized fullerenes on a Moire superstructure and finds that C-84 fullerenes can be either neutral or negatively charged depending on slight variations of the electrostatic potential. This discovery suggests a new path to achieve ambipolar charge transfer without overcoming the electronic gap of fullerenes.

CARBON (2024)

Article Chemistry, Physical

Flexible SiO2/rGO aerogel for wide-angle broadband microwave absorption

Yuanjing Cheng, Xianxian Sun, Ye Yuan, Shuang Yang, Yuanhao Ning, Dan Wang, Weilong Yin, Yibin Li

Summary: The dual-structure aerogel (GS) consisting of flexible silica fibers and graphene honeycomb structures exhibits excellent resilience, flexibility, and reliability. It also shows remarkable wave absorbing performance, making it an ideal candidate for microwave absorption applications such as flexible electronics and aerospace.

CARBON (2024)

Article Chemistry, Physical

In situ self-adaptive growth of graphene coatings on hard substrates via competitive NiCo catalysis reaction

Shuyu Fan, Yinong Chen, Shu Xiao, Kejun Shi, Xinyu Meng, Songsheng Lin, Fenghua Su, Yifan Su, Paul K. Chu

Summary: Graphene coatings are promising solid lubrication materials due to their mechanical properties. This study presents a new method for in situ deposition of high-quality graphene coatings on hard substrates using NiCo solid solution and competitive reaction strategies. The graphene coating deposited on substrates with deep NiCo solid solution demonstrates superior low-friction and durability.

CARBON (2024)

Article Chemistry, Physical

Monodispersed semiconducting SWNTs significantly enhanced the thermoelectric performance of regioregular poly(3-dodecylthiophene) films

Mengdi Wang, Sanyin Qu, Yanling Chen, Qin Yao, Lidong Chen

Summary: The improved thermoelectric properties of conducting polymers are achieved by selectively capturing single-walled carbon nanotubes (SWNTs) in a conducting polymer film, leading to increased carrier mobility and reduced thermal conductivity. The resulting composite film exhibits significantly higher electrical conductivity and lower thermal conductivity compared to films with a mixture of SWNTs. This work provides a convenient and efficient method to enhance the thermoelectric properties of conducting polymers.

CARBON (2024)

Review Chemistry, Physical

Component optimization and microstructure design of carbon nanotube-based microwave absorbing materials: A review

Heng Wei, Weihua Li, Kareem Bachagha

Summary: This article reviews the research progress of carbon nanotube-based microwave absorbing materials (MAMs) in recent years, covering the fundamental theory, design strategies, synthesis methods, and future development directions.

CARBON (2024)

Article Chemistry, Physical

MXene-based polymer brushes decorated with small-sized Ag nanoparticles enabled high-performance lithium host for stable lithium metal battery

Chenguang Shi, Junlong Huang, Zongheng Cen, Tan Yi, Shaohong Liu, Ruowen Fu

Summary: This study developed a high-performance Li metal host material, which achieved dendrite-free Li deposition with a low nucleation overpotential and high Coulombic efficiencies through the combination of Ti3C2-g-PV4P sheets and Ag nanoparticles. The full cells assembled with the Li@host anode and LiFePO4 cathode exhibited high discharge capacity and excellent cycling stability, demonstrating a perspective design for future energy storage devices.

CARBON (2024)

Article Chemistry, Physical

A stable full cell having high energy density realized by using a three-dimensional current collector of carbon nanotubes and partial prelithiation of silicon monoxide

Tomotaro Mae, Kentaro Kaneko, Hiroki Sakurai, Suguru Noda

Summary: A new partial prelithiation method for SiO/C-CNT electrodes was developed, which showed reduced irreversible capacity and achieved high energy densities with good reversibility. The method allows for precise control of the degree of prelithiation and is applicable to various chemistries.

CARBON (2024)