Journal
CATALYSTS
Volume 10, Issue 1, Pages -Publisher
MDPI
DOI: 10.3390/catal10010088
Keywords
cobalt catalyst; titania; diffuse reflectance spectroscopy; sulfamethaxazole; persulfates; point of zero charge
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Two Co/TiO2 catalysts with 7% CoO/g loading were prepared using equilibrium deposition filtration and the dry impregnation method. The two catalysts were characterized with various physicochemical techniques and tested for the degradation of sulfamethaxazole (SMX) using sodium persulfate (SPS) as the oxidant. It was found that the two catalysts exhibit different physicochemical characteristics. The equilibrium deposition filtration (EDF) catalyst had a higher dispersion of cobalt phase, more easily reduced Co(III) species, and a higher ratio of Co(III)/Co(II) species. The interactions between Co-deposited species and the titania surface were monitored with diffuse reflectance spectroscopy in all the preparation steps, and it was found that they increased during drying and calcination, while EDF favored the formation of surface species with strong interactions with the support. Finally, the EDF catalyst was more active for the degradation of sulfamethaxazole due to its better physicochemical characteristics.
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