4.6 Article

SnO2/Diatomite Composite Prepared by Solvothermal Reaction for Low-Cost Photocatalysts

Journal

CATALYSTS
Volume 9, Issue 12, Pages -

Publisher

MDPI
DOI: 10.3390/catal9121060

Keywords

SnO2; diatomite; degradation; photodegradation; organic dyes

Funding

  1. National Natural Science Foundation of China [51403094, 51774175]
  2. Program of Liaoning Education Department of China [LJ2017FBL002]

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Abundant contaminants in wastewater have a negative effect on the natural environment and ecology. Developing highly efficient photocatalysts is a practical strategy to solve the pollution issue. In order to prevent the agglomeration of SnO2 nanoparticles and improve the photocatalytic efficiency, porous diatomite is adopted as a low-cost template to load monodispersed SnO2 nanoparticles by solvothermal reaction and sintering method. Through adjusting the mass of reactants, monodispersed SnO2 nanoparticles (similar to 15 nm) generated on diatomite template achieved the maximum specific surface area of 23.53 m(2).g(-1). When served as a photocatalyst for degrading rhodamine B (Rh B) and methylene blue (MB), the composite presents an excellent photocatalytic activity close to pure SnO2, and achieves the fast degradation of Rh B and MB dye in 60 min. The degradation process is in well agreement with the first-order kinetic equation. The superior photocatalytic performance of SnO2/diatomite composite is attributed to the physical adsorption of dye molecules on the pores of diatomite, and the superior photocatalytic activity of monodispersed SnO2 nanoparticles. Due to the low-cost of diatomite and the easy preparation of SnO2 nanoparticles, the SnO2/diatomite composite has a promising application prospect, even better than pure SnO2 photocatalyst.

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