Article
Chemistry, Multidisciplinary
Qingwei Yan, Jingyao Gao, Ding Chen, Peidi Tao, Lu Chen, Junfeng Ying, Xue Tan, Le Lv, Wen Dai, Fakhr E. Alam, Jinhong Yu, Yuezhong Wang, He Li, Chen Xue, Kazuhito Nishimura, Sudong Wu, Nan Jiang, Cheng-Te Lin
Summary: The mesoplasma chemical vapor deposition (CVD) technology was used to synthesize vertically aligned graphene nanowalls (GNWs) and achieve high thermal conductivity polymer composites with low filler loadings.
Review
Chemistry, Multidisciplinary
Xiaoli Ma, Xinbo Li, Wenrui Zhang, Fanxing Meng, Xin Wang, Yanan Qin, Minwei Zhang
Summary: Carbon-based nanomaterials have unique physical and chemical properties that make them ideal for smart sensor applications, particularly in the detection of mycotoxins. Mycotoxins, with their diverse molecular structures and low molecular weights, can have significant biological effects even at low concentrations. The development of biosensor platforms based on various carbon nanocomposites is expected to have a major impact on the detection of mycotoxins in food products.
Article
Chemistry, Physical
Xigui Yang, Jiajun Dong, Mingguang Yao, Kuo Hu, Huanhuan Sun, Ran Liu, Chong-Xin Shan, Bingbing Liu
Summary: The study introduces a new method for the synthesis of diamond-graphite hybrid nanocomposite from multi-walled carbon nanotubes fibers using laser heating diamond anvil cell, with a combined theory-experiment approach confirming the formation of the hybrid structure. This approach opens up a new avenue for generating new carbon nanocomposites using high pressure techniques and other suitable carbon precursors.
Article
Chemistry, Physical
Xueyu Zhang, Yibao Wang, Zhigang Gai, Mei Zhang, Shousheng Liu, Fengxiang Guo, Nianjun Yang, Xin Jiang
Summary: This paper presents a controllable synthesis method for a diamond/graphene/diamond (DGD) sandwich structure, which effectively addresses the issues of high background current and limited electrochemical window in diamond electrodes. The DGD electrode exhibits fast heterogeneous electron transfer and holds great promise in electrochemical applications.
Article
Engineering, Chemical
Rachit Ranjan, Vivek Bajpai
Summary: This study investigates the potential of nitrogen-doped graphene nanosheets (NDG) as a reinforcing material in aluminum metal matrix composites. The NDG was synthesized through a mechanochemical process involving solid-state dry ball milling of graphite with melamine. The properties of NDG were evaluated using various characterization techniques, and it was found that adding NDG as a reinforcement significantly improved the wettability and strength of the composites.
ADVANCED POWDER TECHNOLOGY
(2023)
Article
Chemistry, Physical
Chenyan Guo, Jingui Zheng, Hongwei Deng, Penghui Shi, Guohua Zhao
Summary: Boron-doped diamond materials exhibit excellent electrochemical and photoelectrochemical properties, making them promising for various applications. Surface modification enhances their performance, while challenges and future research directions in boron-doped diamond photoelectrochemistry are also discussed for theoretical guidance.
Article
Materials Science, Multidisciplinary
Mohamed H. Mostafa, E. S. Ali, Mohamed S. A. Darwish
Summary: Polyaniline/carbon nanotube nanocomposites with outstanding physical properties can be prepared by various methods. They can be used as electrode materials for sensors and have wide applications in biosensors, gas sensors, metal ion sensors, etc.
MATERIALS CHEMISTRY AND PHYSICS
(2022)
Article
Chemistry, Multidisciplinary
Muhammad Ali, Sadullah Mir, Safeer Ahmed
Summary: This study fabricated a glucose sensing electrode using a binary composite of copper oxide and mesoporous titanium dioxide on glassy carbon (CuO/TiO2/GCE). The results showed the presence of phase pure monoclinic CuO nanoparticles and anatase TiO2. The fabricated electrode exhibited enhanced charge transfer resistance and electron transfer process, with an optimum weight ratio of CuO to TiO2 of 1:1 and an optimum potential of 0.6 V vs. saturated calomel electrode.
Article
Materials Science, Multidisciplinary
W. D. M. C. de Toledo, R. A. Pinheiro, V. J. Trava-Airoldi, E. J. Corat
Summary: This work introduces a new Boron-Doped Diamond (BDD) anode for electrochemical degradation. The BDD deposition on carbon nanotubes (CNT) is used as the base for the electrode, which allows for efficient diamond nucleation and growth. Tests conducted in this study showed that the BDD electrodes developed with only 10 minutes of diamond growth exhibited excellent electrochemical characteristics and were able to effectively degrade brilliant green (BG) dye.
DIAMOND AND RELATED MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Ahmed E. Salih, Mohamed Elsherif, Fahad Alam, Matteo Chiesa, Haider Butt
Summary: In this study, gold nanoparticles (GNPs) were functionalized with 3-mercaptopropionic acid (GNPs-MPA) and doped into hydrogel materials using the breathing-in/breathing-out (BI-BO) method. The pH-responsive optical and colorimetric properties of the GNPs-MPA solutions and gels were investigated through UV-Vis spectroscopy and microscopy. The results showed that the color of the solutions and gels changed from red to indigo with a decrease in pH, indicating their potential as pH-triggered sensors.
Article
Chemistry, Analytical
Yuan Liao, Jie Liu, Min Liu, Lingling Lin, Xicun Wang, Zhengjun Quan
Summary: To achieve the desired goals of new biosensing systems, researchers prepared iron nanoparticles encapsulated in boron-nitrogen co-doped carbon nanotubes as a nanozyme, which exhibited excellent oxidase activity and stability. Based on this, an electrochemical sensor for the simultaneous detection of DA and UA was developed, showing enhanced selectivity and sensitivity compared to the sensor without iron nanoparticles.
MICROCHEMICAL JOURNAL
(2023)
Review
Biochemical Research Methods
Alejandro Garcia-Miranda Ferrari, Samuel J. Rowley-Neale, Craig E. Banks
Summary: This review challenges the misconception that 2D hexagonal boron nitride (2D-hBN) is non-conductive and highlights its potential as a basis for electroanalytical sensing platforms. Recent developments and trends in utilizing 2D-hBN in electrochemistry are summarized, with a focus on future developments of this often overlooked material.
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
(2021)
Review
Chemistry, Analytical
Ligia Chelmea, Mihaela Badea, Ioan Scarneciu, Marius Alexandru Moga, Lorena Dima, Patrizia Restani, Cecilia Murdaca, Daniel Ciurescu, Laura Elena Gaman
Summary: Considering the increasing incidence of hyperuricemia and oxidative stress-related diseases, quantification of uric acid has become essential. Therefore, the evolution on sensing devices being favorable, these questions are more often addressed to the field of medical researchers. As for many metabolites, (bio)sensors provide a reliable method for screening and evaluation of uric acid status.
Review
Engineering, Environmental
Shrilekha V. Sawant, Ashwin W. Patwardhan, Jyeshtharaj B. Joshi, Kinshuk Dasgupta
Summary: This review focuses on highlighting the effects of B doping on CNTs, exploring the potential applications of B-CNTs in various fields, and outlining future research directions.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Analytical
Mateusz Ficek, Mateusz Cieslik, Monika Janik, Mateusz Brodowski, Miroslaw Sawczak, Robert Bogdanowicz, Jacek Ryl
Summary: This paper focuses on the development of a novel electrode for impedimetric biosensors, based on boron-doped diamond nanosheet full-volume-enriched screen-printed carbon electrodes (BDDPE). The incorporation of diamond nanosheets leads to enhanced charge transfer and electrochemical behavior. The presented sensing system shows high specificity towards Haemophilus influenzae and has a detection limit of 1 CFU/mL, achieved in under 10 minutes.
Article
Chemistry, Physical
Daniela Mirela Lima Pinheiro, Lucas Lima Bezerra, Ana Aline Coelho Alcanfor, Filipe Xavier Feitosa, Norberto Kassio Vieira Monteiro, Adriana N. Correia, Pedro de Lima Neto, Hosiberto Batista de Sant'Ana
Summary: The thermodynamic and electrochemical properties of Ag+ ions in ChCl and G mixture were investigated, and MD and DFT methods were used for computational simulation. The specific mass, speed of sound, viscosity, and refractive index of the solution were measured at different temperatures. The electrochemical behavior of Ag+ ions was analyzed by cyclic voltammetry, and silver coatings were successfully electrodeposited on the Au surface. SEM analysis revealed the surface morphologies of the electrodeposits. The computational calculation showed that adding silver nitrate to the eutectic solvent had a predominant repulsive effect and negligible influence on sound velocity and refractive index. MD simulations demonstrated a strong interaction between Ag+ ions and Cl ions.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Environmental Sciences
Safiye Ghobakhloo, Amir Hossein Khoshakhlagh, Simone Morais, Ashraf Mazaheri Tehrani
Summary: The occupational exposure to 15 volatile organic compounds (VOCs) in Iranian paint production factories was evaluated. Benzene, toluene, ethylbenzene, xylene, styrene, n-hexane, n-heptane, n-nonane, trichloroethylene, tetrachloroethylene, n-butyl acetate, n-octane, n-decane, dichlorofluoromethane, and acetone were found to exceed the reference value, indicating potential non-carcinogenic and carcinogenic risks.
Article
Chemistry, Analytical
Andre O. Santos, Vanessa E. E. Abrantes-Coutinho, Simone Morais, Thiago M. B. F. Oliveira
Summary: The lectin found in Agaricus bisporus mushroom biomass can be used to develop a photoelectrochemical biosensor with high sensitivity and specificity for lactose detection. Immobilizing the lectin on a poly(methylene blue)/fluorine-doped tin oxide-coated glass platform enhances the performance of the biosensor. This research has significant implications for ABL-based biosensors and the use of Agaricus bisporus extract in biotechnological applications.
Article
Engineering, Chemical
Leandro R. Prado, Renan T. Figueiredo, Ronaldo S. Silva, Cristiano T. Meneses, Flavia M. R. Mendonca, Gustavo R. Borges, Claudio Dariva, Elton Franceschi, Giancarlo R. Salazar-Banda, Silvia M. Egues
Summary: Mesoporous titanium dioxide particles (TiO2) were synthesized through reactive precipitation using the supercritical anti-solvent (SAS) technique with carbon dioxide and the ionic liquid (IL) 1-methyl-3-octylimidazolium bis[trifluoromethylsulfonyl] imide, [C(8)mim][NTf2]. The particles exhibited anatase and brookite crystalline phases, with brookite peaks more pronounced in samples synthesized with the IL. The TiO2 particles had high surface area, controlled porosity, narrow pore size distribution, high thermal stability, and spherical morphology. The particle size decreased with the use of the IL and increased with a higher precursor/alcohol ratio.
BRAZILIAN JOURNAL OF CHEMICAL ENGINEERING
(2023)
Article
Materials Science, Multidisciplinary
Ronnie A. R. Semedo, Ana Aline C. Alcanfor, Natalia G. Sousa, Paulo N. S. Casciano, Adriana N. Correia, Juliermes C. Pereira, Pedro de Lima-Neto
Summary: Znx-Mn1-x coatings were successfully electrodeposited on a rotating 1020 carbon steel electrode using a choline chloride and urea mixture without additives. The corrosion performance of the coatings was evaluated and showed better corrosion protection than the pure Zn coating. The Zn84Mn16 coating had the best performance, lasting 3 times longer than the pure Zn coating in immersion tests.
MATERIALS CHEMISTRY AND PHYSICS
(2023)
Article
Chemistry, Inorganic & Nuclear
Caique Diego de Abreu Lima, Roniel dos Santos Sousa, Antonio Werbeson Miranda, Joao Victor Barbosa Moura, Gardenia de Sousa Pinheiro, Bartolomeu Cruz Viana, Iara Souza Lima, Thiago Mielle Brito Ferreira Oliveira, Oswaldo Baffa, Jefferson Ferraz Damasceno Felix Araujo, Cleanio da Luz Lima
Summary: This study investigated the synthesis, characterization, and thermal stability of pure and Al ion-exchange titanate nanotubes (Na2Ti3O7 and NaxAlyTi3O7, respectively). The results revealed the obtainment of sodium titanate and aluminum titanate nanotubes with different average lengths and diameters. The presence of Al ions in the crystal lattice affected the energy exchange between the unpaired species and the lattice. The thermal stability of sodium titanate nanotubes was influenced by sodium ions, while the incorporation of Al3+ ions into the nanotube lamellae decreased the thermal stability of aluminum titanate nanotubes.
SOLID STATE SCIENCES
(2023)
Article
Chemistry, Multidisciplinary
Jaroslava Svarc-Gajic, Tanja Brezo-Borjan, Valentin Dzedik, Francisca Rodrigues, Simone Morais, Cristina Delerue-Matos
Summary: This research examines the valorization potential of cocoa hull extracts in the cosmetic industry based on Environmental, Social, and Governance (ESG) criteria. The extracts were obtained using subcritical water extraction and characterized for their chemical composition and bioactive properties. Functional cosmetic formulations were developed using cocoa hull extracts from cocoa beans sourced from different geographical locations. The extracts showed high total protein, total phenol, and total flavonoid contents, as well as significant antioxidant and antiradical activities. A functional cosmetic product, a day cream with sun protective properties, was formulated using the extract with the highest antioxidant and antiradical activity. The safety and quality parameters of the cream were analyzed, indicating the viability of using subcritical water extracts of cocoa hull in cosmetic products. The application of subcritical water extraction as a green technology can contribute to ESG development in the cosmetic industry.
SUSTAINABLE CHEMISTRY AND PHARMACY
(2023)
Article
Electrochemistry
Dara S. Santos, Caio V. S. Almeida, Katlin I. B. Eguiluz, Giancarlo R. Salazar-Banda
Summary: The catalytic activity of Pdx@Pty/C core-shell nanoparticles for methanol electrooxidation was investigated. The core-shell nanoparticles exhibited good dispersion, small particle sizes, and a Pd-Pt-rich core with a Pt shell. The core-shell catalysts displayed improved catalytic properties compared to Pt/C catalysts, and the Pd0.3@Pt0.7/C catalyst achieved the highest catalytic activity.
ELECTROCHIMICA ACTA
(2023)
Article
Biotechnology & Applied Microbiology
Joan Petrus Oliveira Lima, Aluisio Marques da Fonseca, Gabrielle Silva Marinho, Matheus Nunes da Rocha, Emanuelle Machado Marinho, Helcio Silva dos Santos, Rafael Melo Freire, Emmanuel Silva Marinho, Pedro de Lima-Neto, Pierre Basilio Almeida Fechine
Summary: This work synthesizes 12 phenol and chromone derivatives and explores their potential as therapeutic alternatives for combating SARS-CoV-2. The study identifies derivative 4 with the best energy bond to the S-glycoprotein target. Molecular simulations reveal that derivative 250 exhibits strong inhibitory activity against SARS-CoV-2. Overall, this research employs computational methods to design efficient molecular structures and aims to contribute to the development of effective therapeutic strategies against COVID-19.
Article
Chemistry, Physical
Aline R. Doria, Isabelle M. D. Gonzaga, Gessica O. S. Santos, Caio V. S. Almeida, Deyvid C. Silva, Ronaldo S. Silva, Luciane P. C. Roma, Cristina Saez, Giancarlo R. Salazar-Banda, Katlin I. B. Eguiluz
Summary: Ti/RuO2-TiO2 anodes were prepared using unconventional heating methods involving CO2 laser and microwave irradiation. These anodes exhibited improved electrochemical properties compared to conventionally-prepared anodes, with increased voltammetric charge and decreased charge transfer resistance. The laser and microwave-prepared anodes also had longer lifetimes and high efficiency in generating hypochlorite and degrading ciprofloxacin.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2023)
Article
Environmental Sciences
Amir Hossein Khoshakhlagh, Zohreh Saadati, Farideh Golbabaei, Simone Morais, Ana Margarida Paiva, Seyed Jamaleddin Shahtaheri
Summary: In this study, a metal-organic framework material called MIL-101 was synthesized and tested for the removal of low concentrations of benzene and toluene from a gas phase. Different models were used to analyze the breakthrough curves, and it was found that the Thomas model fit the benzene data best, while the Gompertz model fit the toluene data best. Nonlinear regression showed a stronger correlation with the experimental results compared to linear regression. Both liquid film and intraparticle diffusion were found to contribute to the adsorption mechanism. The Freundlich isotherm provided the best fit for the adsorption process. MIL-101 showed better reusability for benzene compared to toluene.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Chemistry, Physical
Stephanie Soares Aristides, Caio Vinicius da Silva Almeida, Katlin Ivon Barrios Eguiluz, Giancarlo R. Salazar-Banda
Summary: In this study, NixFey@Pdz/C core-shell nanoparticles with different compositions were synthesized and it was found that the addition of Ni-Fe enhanced the catalytic activity of Pd in glycerol oxidation. Among them, the Ni1.5Fe13.5@Pd85/C catalyst exhibited the best electrocatalytic performance with a specific activity 1.28 times higher than that of Pd/C. In situ FTIR spectroscopy data revealed favorable formate and CO2 production on NiFe@Pd/C catalysts. The results highlight the synergistic effect of composition and core-shell morphology on catalytic activity.
CHEMICAL PHYSICS LETTERS
(2023)
Article
Environmental Sciences
Raira Souza de Santana Castro, Aline Resende Doria, Fabio Costa, Silvana Mattedi, Katlin Ivon Barrios Eguiluz, Giancarlo Richard Salazar-Banda
Summary: The development of efficient and economically viable anode technologies is crucial for treating water contaminated with complex organic pollutants. The use of ionic liquids as solvents in the production of anodes has emerged as a promising alternative, with the calcination temperature playing a decisive role in the anodes' durability and electrochemical properties. Anodes prepared with dipropyl ammonium butyrate (DPA-Bu) at 350 degrees C exhibit higher stability and improved results in terms of organic compound degradation.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Review
Chemistry, Analytical
Claudia Campanale, Silvia Galafassi, Francesca Di Pippo, Iulian Pojar, Carmine Massarelli, Vito Felice Uricchio
Summary: Biodegradable plastic mulches (BDMs) have the potential to be an eco-friendly alternative to conventional plastic mulches in agriculture. However, their long-term impacts on soil ecosystems are still uncertain, and further research is needed. Incorporating BDMs into the soil may stimulate microbial activity, but there is also a risk of incomplete degradation and release of residual microplastics and additives.
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
(2024)
Review
Chemistry, Analytical
Xuechi Yin, Sijie Liu, Deepak Kukkar, Jianlong Wang, Daohong Zhang, Ki-Hyun Kim
Summary: The lateral flow immunoassay strip is a classic and dominant tool in point-of-care detection, known for its portability and simplicity. However, current colored nanomaterials used as signal labels in LFIA have limited sensing potential, leading to the recognition of composite nanoparticles as alternatives to enhance sensitivity, signal readout diversity, anti-matrix interference, and cost-effectiveness.
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
(2024)
Review
Chemistry, Analytical
Yaxin Cao, Longyi Shao, Timothy P. Jones, Wenjing Deng, M. Santosh, Pengju Liu, Cheng-Xue Yang, Yaowei Li, Daizhou Zhang, Kelly Berube
Summary: The toxicity of fibrous particles in ambient air can be higher than other types of particles. Microfibers can be organic or inorganic and their presence in the atmosphere as a result of human activity raises concerns for environmental and public health. Accurate collection, identification, and understanding of the health hazards associated with these fibers are crucial for mitigation strategies and protection of public health.
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
(2024)
Review
Chemistry, Analytical
Chenchen Xie, Chen Meng, Huilin Liu, Baoguo Sun
Summary: The development of food hazard factor (FHF) detection has been moving towards on-site inspection and mobile law enforcement, calling for simple, fast, and affordable analysis technology to ensure food safety and quality. This review comprehensively summarizes the progress in research on smartphone-assisted MIP optosensors, focusing on the key issues of accuracy and sensitivity.
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
(2024)
Review
Chemistry, Analytical
Guillem Peris-Pastor, Cristian Azorin, Jose Grau, Juan L. Benede, Alberto Chisvert
Summary: Green Analytical Chemistry plays an important role in every stage of method development, including sample preparation. Extraction techniques have evolved from conventional ones to a variety of miniaturized techniques in order to enhance analytical performance and ensure safety for operators and the environment. Green metric tools are used to evaluate the impact and sustainability of methods, with AGREEprep selected as the most suitable tool for evaluating published methods in various applications. The miniaturization of sample preparation strategies has led to the use of less and safer solvents, reduced waste generation and energy consumption, and improved portability and throughput.
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
(2024)
Review
Chemistry, Analytical
Helena Hruskova, Roman Reminek, Frantisek Foret
Summary: This review article summarizes the progress and recent studies in offline electromigration preparative techniques between 2018 and 2023. It covers various techniques including electrophoresis, free-flow electrophoresis, isoelectric focusing, and isotachophoresis, providing theoretical aspects, trends, and solutions to existing limitations in each technique.
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
(2024)
Review
Chemistry, Analytical
Mayank Garg, Nicole Pamme
Summary: This review focuses on the removal strategies of templates from molecularly imprinted polymers (MIPs) used in diagnostic biosensors. Chemical-based and electrochemical-based template extraction approaches are summarized and evaluated, providing guidance for researchers in the fields of analytical chemistry, diagnostics, and materials science for the design of MIP-based sensors.
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
(2024)
Review
Chemistry, Analytical
Ivneet Banga, Anirban Paul, Nathan Kodjo Mintah Churcher, Ruchita Mahesh Kumar, Sriram Muthukumar, Shalini Prasad
Summary: Breathomics is an emerging field that focuses on analyzing exhaled breath to diagnose and monitor respiratory diseases. Electrochemical sensors, with their high sensitivity, selectivity, and low cost, play a significant role in breathomics and can be integrated into portable devices for point-of-care diagnosis.
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
(2024)
Review
Chemistry, Analytical
Fabjola Bilo, Paola Cirelli, Laura Borgese
Summary: This review explores the application of X-ray fluorescence (XRF) spectrometry for elemental analysis of particulate matter (PM) in air quality monitoring. It discusses the fundamentals of XRF, experimental configurations, PM sampling devices and substrate, sample preparation strategies, qualitative and quantitative analysis, as well as the challenges faced by XRF in becoming a reliable analytical technique for PM analysis.
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
(2024)
Review
Chemistry, Analytical
Hakim Faraji
Summary: The dispersive liquid-liquid microextraction (DLLME) technique is widely popular in analytical chemistry due to its high efficiency, cost-effectiveness, and simplicity. Recent advancements have addressed the limitations of DLLME, incorporating greener solvents, innovative dispersion strategies, and simplified procedures. These changes have made DLLME a more sustainable and efficient technique.
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
(2024)
Review
Chemistry, Analytical
Sherin F. Hammad, Inas A. Abdallah, Alaa Bedair, Reda M. Abdelhameed, Marcello Locatelli, Fotouh R. Mansour
Summary: Carbon nanomaterials (CNMs) have excellent capabilities in terms of adsorption, enhanced oxidation, and photocatalysis, attracting widespread attention in different fields. Metal-organic frameworks (MOFs) have been widely used due to their regular network structure, porous nature, and large specific surface area. However, the instability of MOFs in aqueous solutions limits their applications in chemical sensing. Recent studies have focused on increasing the stability of MOFs in water-based matrices through chemical modifications using CNMs.
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
(2024)
Review
Chemistry, Analytical
Alexandra Pape, Oliver J. Schmitz
Summary: Low temperature plasmas based on dielectric barrier discharges have emerged as a recent development in ion source research. These ion sources are applicable to heat-sensitive analytes and can ionize a wide range of compounds. Despite intensive research on important parameters such as configuration, shape, size, and materials in the past two decades, the actual ionization mechanism for all plasma gases has not been fully elucidated. This review provides an overview of atmospheric pressure ion sources, with a focus on plasma and dielectric barrier discharge based ion sources, summarizing the reactions occurring in the plasma and discussing the applications developed by different research groups.
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
(2024)
Review
Chemistry, Analytical
Hai Xiong, Fengli Li, Linyu Zeng, Qiyu Lei
Summary: This review provides an overview of the emerging trends in the use of functional COF nanomaterials as biosensors for DNA/RNA detection. It summarizes the construction of DNA/RNA hybridized COF nanoprobes and their potential applications in bioanalyte detection, biosensing, biomarker imaging, and clinical biomedicine.
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
(2024)
Review
Chemistry, Analytical
Bing Yan
Summary: This article summarizes the recent progress in logic gate computing and operation based on multiple luminescence response and chemical sensing for lanthanide functionalized MOF hybrid systems. The article first describes multi-color luminescence and the subsequent multiple luminescence response. The basic concept of logic gate operation and the advantages of lanthanide-based hybrid materials are then introduced. Reports on logic gate operation using pure lanthanide MOFs are provided, followed by a detailed summary of logic gate operations using lanthanide functionalized MOF hybrid materials. Additionally, the article discusses the practical luminescent detection of analytes by correlating the luminescence responsive signals and the concentration of different analytes. Finally, the article concludes with a prospect for this topic.
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
(2024)
Review
Chemistry, Analytical
Brij Mohan, Gurjaspreet Singh, Rakesh Kumar Gupta, Pawan Kumar Sharma, Alexander A. Solovev, Armando J. L. Pombeiro, Peng Ren
Summary: Porous materials, particularly hydrogen-bonded organic frameworks (HOFs), have gained significant attention due to their versatile applications and unique properties such as well-defined crystalline structure and easy regeneration processes. This article provides a comprehensive overview of HOFs, including synthesis methods, hydrogen bonding motifs, recent advancements, and potential applications, offering valuable guidance for further exploration in this dynamic field.
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
(2024)