Journal
POLYMER TESTING
Volume 81, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.polymertesting.2019.106274
Keywords
Epoxy; Hybrid fillers; Synergistic effect; Mechanical properties
Funding
- Board of Research in Nuclear Sciences (BRNS), India [36(2)/14/17/2016-BRNS]
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Addition of carbon nanotubes (CNT) to Graphene (Gr) is seen to have synergistic effect as reinforcement to polymer matrix. This is possible as CNTs inhibit stacking of Gr sheets, thus providing larger surface area nanophase to get bonded with polymer matrix and providing mechanical support through load sharing and crack growth inhibition. However, tube like morphology and high aspect ratio of CNT often lead to entanglement, which restricts their effect in exfoliating Gr. The aim of the present study is to investigate the potential of ND in improving the synergistic effect of Gr-CNT hybrid as a reinforcement to epoxy matrix. This study utilizes the power of ultrasonication technique, which is very simple and scalable, for dispersing and incorporating nanofillers into epoxy matrix. Addition of ND to Gr-CNT epoxy composite improved the tensile strength from similar to 46% with 0.5 wt% (75Gr:25ND) to similar to 51% with 0.8 wt% (25Gr:25CNT:50ND) as compared to neat epoxy. While the fracture toughness improved from similar to 140% with 0.5 wt% (25Gr:75CNT) to 165% with 0.8 wt% (25Gr:50CNT:25ND). Fractured surfaces of composites revealed improved dispersion and strong interfacial interaction with addition of ND to Gr-CNT hybrid. NDs attaches to the surface of Gr inhibit the stacking of Gr sheets by restricting pi-pi stabilization. NDs also help in bridging the ends of CNTs together into long chains, thereby increasing the aspect ratio of the fiber like reinforcement. This increases the total available surface area of CNTs and Gr, to interact with epoxy matrix, improves the overall efficiency of Gr-CNT hybrid as a reinforcement, resulting into improvement in mechanical properties of the composite structure.
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