Journal
ORGANIC LETTERS
Volume 22, Issue 4, Pages 1469-1474Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c00048
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Funding
- JSPS KAKENHI [JP18H04264]
- International Institute for Carbon -Neutral Energy Research (WPI-I2CNER) from MEXT, Japan
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(Aqua)ruthenium(salen) complex 1c achieved good to high chemo- and enantioselective oxidative cross-coupling of arenols. The catalytic system can be used to selectively produce C-1-symmetric bis(arenol)s from the combination of C3- and C7-substituted 2-naphthols or phenols even when there is no significant difference in oxidation potential between the cross-coupling partners. This unique cross-selectivity is dominated by steric rather than electronic effects of the arenols and can be controlled by chemoselective single-electron oxidation and oxidative carbon-carbon bond formation.
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