Journal
ORGANIC LETTERS
Volume 22, Issue 3, Pages 795-799Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b04141
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Funding
- National Key Research and Development Program of China [2016YFB0301501]
- National Science Foundation of China [21776130]
- Jiangsu Synergetic Innovation Center for Advanced Bio-Manufacture [X1821, X1802]
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Herein an exogenous oxidant- and metal-free electrochemical heteroaryl migration triggered by N radicals to construct new N-C bonds was developed. This methodology features a high atom economy and utilization rate of energy, and it is insensitive to water and air. Moreover, a user-friendly undivided cell was employed. The use of an organic catalyst makes it more efficient, green, and practical.
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