Journal
OPTICAL MATERIALS
Volume 101, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.optmat.2020.109737
Keywords
Antimony trisulfide; Optical spectroscopy; Reflection and absorption spectra; Band structure; Frenkel excitons
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Anisotropy of optical properties of Sb2S3 single crystals was investigated at 11 and 300 K. Ground and excited states of four excitonic states (A, B, C and D) were found out. Parameters of observed excitons and bands V-1 - V-4 were determined. In Gamma point of Brillouin zone the effective masses of electrons in the bottom conduction band (m(c)* = 1.08m(0)) and of holes in four top valence bands (m(v1)*, m(v2)* = 2.91m(0) and m(v3)*, m(v4)* = 3.12m(0)) were estimated. The splitting magnitudes of valence bands V-1 - V-2 in the Brillouin zone center by crystal field (Delta(cf) = 20 meV) and by spin-orbital interaction (Delta(so) = 375 meV) were calculated. V-3 and V-4 bands have splitting of 198 meV. The observed features were interpreted on the base of existing theoretically calculated band structure and symmetries of excitons in G point of Brillouin zone for single crystals of orthorhombic symmetry (Pnma).
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