Journal
MOLECULES
Volume 25, Issue 2, Pages -Publisher
MDPI
DOI: 10.3390/molecules25020391
Keywords
carborane; heterocycle; B-H activation; polyhedral borane cluster
Funding
- Longshan academic talent research supporting program of SWUST [17LZX324, 18LZX305, 18LZXT02]
- Project of State Key Laboratory of Environment-friendly Energy Materials, SWUST [17fksy0102, 18fksy0206]
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Aromatic heterocycles are ubiquitous building blocks in bioactive natural products, pharmaceutical and agrochemical industries. Accordingly, the carborane-fused heterocycles would be potential candidates in drug discovery, nanomaterials, metallacarboranes, as well as photoluminescent materials. In recent years, the transition metal catalyzed B-H activation has been proved to be an effective protocol for selective functionalization of B-H bond of o-carboranes, which has been further extended for the synthesis of polyhedral borane cluster-fused heterocycles via cascade B-H functionalization/annulation process. This article summarizes the recent progress in construction of polyhedral borane cluster-fused heterocycles via B-H activation.
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