Journal
MATERIALS CHEMISTRY AND PHYSICS
Volume 243, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2020.122623
Keywords
Sol-gel reaction; Phosphor; Luminescence; Energy transfer
Categories
Funding
- Innovation of Science and Technology Plan Projects of Shaanxi Province, Chain [2013KTDZ03-02-01, 2017TSCXL-GY-07-02]
- Natural Science Foundation of Shaanxi Province [2019JQ-785]
- Research Starting Foundation from Shaanxi University of Science and Technology [2016BJ-41]
- Graduate Innovation Fund of Shaanxi University of Science and Technology [SUST-A04]
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A sequence of LaAl2.03(B4O10)O-0.54: Dy3+, Eu3+ phosphors were produced by sol-gel reaction method. A number of properties such as phase composition, crystal structure, luminescence performance, lifetime decay curves and mechanism of energy transfer were discussed. Characteristic emission pertain to Dy3+ and Eu3+ ions were observed in its emission spectrum when excited under a wavelength of 349 nm. By comparing the emission spectrum and the fluorescence lifetime decay curves of LaAl2.03(B4O10)O-0.54: Dy3+, yEu(3+) phosphors, it can bear out that the energy transfer among Dy3+ ions and Eu3+ ions was existed, and the mechanism of energy transfer was proved to dipole-dipole interaction. The color of these samples can change from green to orange with the increase of concentration of Eu3+ ions concentration, and its correlated color temperature is improved. These results show that the LaAl2.03(B4O10)O-0.54: Dy3+, Eu3+ phosphors can be applied for warm WLEDs under near ultraviolet (n-UV).
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