4.7 Article

Eco-friendly fabrication of porous carbon monoliths from water-soluble carboxymethyl cellulose for supercapacitor applications

Journal

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
Volume 82, Issue -, Pages 367-373

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.jiec.2019.10.036

Keywords

Porous carbon monolith; Supercapacitor; Ice-templating; Carboxymethyl cellulose; Carbonization

Funding

  1. Korea Institute of Energy Technology Evaluation and Planning (KETEP) - the Ministry of Trade, Industry & Energy (MOTIE) of the Republic of Korea [20164010201070]
  2. National Research Foundation of Korea (NRF) - Ministry of Science and ICT (MSIT) [NRF-2017R1A4A1015360]

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An eco-friendly method for the preparation of porous carbon monoliths (PCMs) with a high surface area and excellent electrochemical performance was demonstrated. Porous carboxymethyl cellulose monoliths (CMCMs) were prepared by ice-templating technique. PCMs were fabricated by the carbonization of ice-templated porous CMCMs. The prepared PCMs exhibited a high specific surface area of 724.35 m(2) g(-1) with multi-modal pore structures. The PCM-based electrode showed a high specific capacitance of 210 Fg(-1) at 1 A g(-1) in a 6.0 M KOH electrolyte, and an excellent cycle stability of almost 100% at 10 A g(-1) after 10,000 cycles. Therefore, the PCMs prepared in this study are a promising electrode material for high-performance supercapacitors. (C) 2019 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

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