4.7 Article

Fabrication of polypyrrole/multi-walled carbon nanotubes composites as high performance electrodes for supercapacitors

Journal

JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume 862, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2020.114006

Keywords

Polypyrrole; Multi-walled carbon nanotubes; Supercapacitors; Composite electrodes

Funding

  1. National Natural Science Foundation of China [61504080, 61704107]
  2. Shanghai Municipal Education Commission [QD2016012]
  3. Shanghai Pujiang Program [17PJ1406800]

Ask authors/readers for more resources

The development of supercapacitor electrode material with high performance and low cost is a significant part of the research work. Herein, the polypyrrole (PPy)/Multi-walled carbon nanotubes (MWNTs) composites were synthesized by oxidative polymerization, when the iron (III) chloride (FeCl3), methyl orange (MO), sodium dodecyl benzene sulfonate (SDBS) were used as the oxidant and dopant template. Various compounds of PPy and carbon nanotubes were synthesized, it shows a better capacity when the ratio of PPy andMWCNTs is up to 9:1.Under acidic conditions, the capacitance characteristics of the PPy/MWCNTs are better than other ones'when SDBS and MO are added, in other words, its ion exchange is more rapid and reversible. Electrochemical tests show that the initial discharge capacity of the PPy/MWCNTs composite electrode is 374.6 F/g. While the coulomb efficiency can remain 88% after 1000 discharge cycles, it indicates the good circulation stability of PPy/MWCNTs composite electrode material is obtained. (c) 2020 Published by Elsevier B.V.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Engineering, Manufacturing

Effect of defects and specimen size with rectangular cross-section on the tensile properties of additively manufactured components

Pan Wang, Min Hao Goh, Qiang Li, Mui Ling Sharon Nai, Jun Wei

VIRTUAL AND PHYSICAL PROTOTYPING (2020)

Article Materials Science, Multidisciplinary

Influence of Sintering Temperature on Mechanical Properties of Ti-Nb-Zr-Fe Alloys Prepared by Spark Plasma Sintering

Qiang Li, Hao Sun, Junjie Li, Xufeng Yuan, Masaaki Nakai, Mitsuo Niinomi, Takayoshi Nakano

Summary: The study shows that increasing sintering temperature enhances the strength and plasticity of the alloy, while higher Fe content can promote the formation of beta phase grains and solid-solution strengthening effect. However, excessive Fe can lead to the formation of intermetallic compounds, affecting the mechanical properties. The mechanical properties of the alloy are influenced by a combination of factors.

JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE (2021)

Article Chemistry, Physical

Impact of gelation in nickel-rich ternary lithium-ion batteries

Kyu Hwan Choi, Xuyan Liu, Xiaohong Ding, Yijie Xia, Qiang Li

Summary: The study investigates the use of polyethylenimine (PEI) polymer to synthesize NCM811 cathodes for improving particle structural stability and controlling electrode pore conditions. However, cross-linking between PEI and polyvinylidene fluoride (PVdF) accelerates gelation, leading to complete structural changes and collapse in the cathode.

IONICS (2021)

Article Materials Science, Multidisciplinary

Antibacterial Cu-Doped Calcium Phosphate Coating on Pure Titanium

Qiang Li, Jinshuai Yang, Junjie Li, Ran Zhang, Masaaki Nakai, Mitsuo Niinomi, Takayoshi Nakano

Summary: Cu-doped amorphous calcium phosphate (ACP) coatings were fabricated on pure titanium surfaces by electrochemical deposition at initial electrolyte temperatures of 35, 45, and 55 °C. The Cu concentration on the surfaces of the samples increased from 6.90 to 15.05 mass% as the initial electrolyte temperature increased. The Cu-doped ACP coatings showed strong antibacterial activity, completely inhibiting the growth of Escherichia coli.

MATERIALS TRANSACTIONS (2021)

Article Materials Science, Multidisciplinary

Microstructure, Mechanical Properties, and Cytotoxicity of β-Type Ti-Nb-Cr Alloys Designed by Electron Parameter

Qiang Li, Fei Li, Junjie Li, Zhi Gao, Ke Zhang, Mitsuo Niinomi, Takayoshi Nakano

Summary: By replacing Nb with Cr, the stability and comprehensive mechanical properties of beta-type Ti-Nb-Cr alloys can be improved without causing cytotoxicity.

JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE (2022)

Article Materials Science, Multidisciplinary

Microstructure, mechanical properties, and cytotoxicity of low Young's modulus Ti-Nb-Fe-Sn alloys

Qiang Li, Tengfei Liu, Junjie Li, Chao Cheng, Mitsuo Niinomi, Kenta Yamanaka, Akihiko Chiba, Takayoshi Nakano

Summary: The addition of Sn was found to affect the beta phase stability, plasticity, and work-hardening rate of Ti-Nb-Fe alloys, without showing a strong solid solution strengthening effect. Ti-26Nb-2Fe-4Sn alloy demonstrated good mechanical properties and cell viability, making it suitable for biomaterials.

JOURNAL OF MATERIALS SCIENCE (2022)

Article Chemistry, Physical

Boosting acidic water oxidation performance by constructing arrays-like nanoporous IrxRu1-xO2 with abundant atomic steps

Junjie Li, Zan Lian, Qiang Li, Zhongchang Wang, Lifeng Liu, Francis Leonard Deepak, Yanping Liu, Bo Li, Junyuan Xu, Zuxin Chen

Summary: In this study, a high-performance nanoporous Ir_xRu_1-xO_2 catalyst with high activity and acid stability was successfully fabricated. The catalyst exhibits excellent electrocatalytic performance under acidic conditions and can sustain long-term oxygen evolution reaction, showing great potential for large-scale practical applications.

NANO RESEARCH (2022)

Article Metallurgy & Metallurgical Engineering

Microstructure and mechanical properties of Ti-Nb-Fe-Zr alloys with high strength and low elastic modulus

Qiang Li, Qi Huang, Jun-jie Li, Qian-feng He, Masaaki Nakai, Ke Zhang, Mitsuo Niinomi, Kenta Yamanaka, Akihiko Chiba, Takayoshi Nakano

Summary: In this study, Zr was added to develop low elastic modulus and high strength beta-Ti alloys for biomedical applications. The results showed that Zr and Fe had a significant solid-solution strengthening effect on the alloys, resulting in high yield and ultimate tensile strengths. Additionally, twinning in the deformed alloys contributed to both strength and plasticity.

TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA (2022)

Article Materials Science, Multidisciplinary

Antibacterial Properties and Biocompatibility of Hydroxyapatite Coating Doped with Various Cu Contents on Titanium

Qiang Li, Shihong Song, Junjie Li, Jinshuai Yang, Ran Zhang, Mitsuo Niinomi, Takayoshi Nakano

Summary: This study explores the effect of copper content in a copper-doped hydroxyapatite coating (CuHAp) on its antibacterial activity and biocompatibility. The results show that the coating with a copper content of 1.57% exhibits excellent biocompatibility and antibacterial properties. However, when the copper content increases to 6.85%, the coating becomes cytotoxic.

MATERIALS TRANSACTIONS (2022)

Article Engineering, Electrical & Electronic

Investigating the band gap on the performance of tin-based perovskite solar cells by device simulation

Shasha Lu, Qiang Li

Summary: This study investigated the effect of band gap on the device performance of tin-based perovskite solar cells using a simulator. The results showed that the open-circuit voltage increased with the increase of band gap, while other performance parameters tended to decrease. The internal mechanisms affecting each parameter were analyzed, and it was verified that the band gap can be tuned by doping to achieve stability.

OPTICAL AND QUANTUM ELECTRONICS (2022)

Article Chemistry, Physical

Improved electrochemical performance of LiFePO4/carbon cathode for lithium-ion batteries

Xuyan Liu, Ruipeng Zhao, Yijie Xia, Qiang Li

Summary: LFP/C composites prepared through carbothermic reduction process show enhanced electrochemical performance with increasing carbon content. LFP/C-15 exhibits the highest initial discharge specific capacity and superior capacity retention rate, close to the theoretical specific capacity.

IONICS (2022)

Article Engineering, Electrical & Electronic

Improved electrochemical performance of silicon-carbon anodes by different conductive agents

Xuyan Liu, Wenhui Chen, Yijie Xia, Qiang Li

Summary: In this study, SiO2/Si/PAN composites were prepared as active anode for LIBs using template method and liquid-phase mixing. The addition of binary conductive agents of rGO and MWCNTs at 1:1 mass ratio greatly improved the performance of LIBs.

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS (2022)

Article Materials Science, Multidisciplinary

Antibacterial Cu-Doped HA/TiO2 Bioactive Ceramic Composite Coating with Enhanced Adhesion on Pure Ti

Jiawei Yang, Qiang Li, Junjie Li, Jinshuai Yang, Ran Zhang, Mitsuo Niinomi, Takayoshi Nakano

Summary: Cu-doped hydroxyapatite/TiO2 composite coatings were prepared using an electrochemical method, resulting in improved adhesion and antibacterial properties. These coatings showed high biocompatibility and promoted cell proliferation.

JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE (2023)

Article Nanoscience & Nanotechnology

Study of a nearly Ni-free V-containing lean duplex stainless steel and the deformation mechanism

Jiaxin Pan, Pingda Xu, Wei Li, Qiang Li, Wei Li, Fengcang Ma, Ke Zhang

Summary: A novel Ni-free V-containing lean duplex stainless steel with low content of precious element Ni and good mechanical properties was developed. The effects of annealing temperature on the precipitation behavior, austenite volume fraction, and grain size of the steel were investigated. The results showed a synergistic deformation behavior of TRIP effect in austenite and rapid growth of dislocations in coarse ferrite, resulting in excellent plasticity of the steel. Annealing at 1125°C for 5 minutes yielded samples with good combination of ultimate strength and elongation.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2023)

Article Materials Science, Multidisciplinary

Effect of O addition on microstructure and mechanical properties of Ti-Nb alloys with various beta stability

Qiang Li, Yan Liu, Huanhuan Yu, Masaaki Nakai, Mitsuo Niinomi, Kenta Yamanaka, Akihiko Chiba, Takuya Ishimoto, Takayoshi Nakano

Summary: The effect of O on beta-Ti alloys with various beta phase stability was studied. Ti-xNb-0.4O (x = 30, 32, 34, 36, 38, 40, 42, mass%) alloys were prepared and their phase composition, microstructure, and mechanical properties were analyzed. O suppressed omega phase and alpha '' phase transformations, and showed a solution-strengthening effect. The Ti-xNb-0.4O alloys exhibited similar tensile strengths, with Young's moduli ranging from 60 to 69 GPa and elongations all higher than 15%. Ti-36Nb-0.4O showed desirable mechanical properties, including a Young's modulus of 61 GPa, a tensile strength of 760 MPa, and an elongation of approximately 35%.

VACUUM (2023)

No Data Available